Ion guide device and ion guide method

Patent metadata

Field	Value
Publication number	US-11508565-B2
Application number	US-202117393507-A
Country	US
Kind code	B2
Filing date	Aug 4, 2021
Priority date	Sep 29, 2020
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

An ion guide device includes a plurality of ring electrodes disposed in parallel, wherein each ring electrode includes at least 4 electrode units separated from each other, a channel for ion transmission is formed inside the plurality of ring electrodes, and an arrangement direction of the plurality of ring electrodes defines an axial direction of ion transmission; an radio-frequency voltage source, for applying out-of-phase radio-frequency voltages on the neighboring electrode units belonging to the same ring electrode, and applying in-phase radio frequency voltages on a neighboring electrode units along the axial direction, thereby forming an radio-frequency multipole field that confine ions in the ion guide device; and a direct-current voltage source, wherein the ions are transmitted off-axis and focused to a position closer to an inner surface of the ring electrode under a combined action of the radio-frequency voltage and the direct-current voltage.

First claim

What is claimed is:

1. An ion guide device, comprising:
a plurality of ring electrodes disposed in parallel, each of the ring electrodes includes at least 4 electrode units separated from each other, a channel for ion transmission is formed inside the plurality of ring electrodes, and an arrangement direction of the plurality of ring electrodes defines an axial direction of ion transmission;
a radio-frequency voltage source, for applying out-of-phase radio-frequency voltages on the neighboring electrode units belonging to the same ring electrode, and applying in-phase radio frequency voltages on the neighboring electrode units along the axial direction, thereby forming an radio-frequency multipole field that confine ions in the ion guide device; and
a direct-current voltage source, for applying a direct-current voltage on the plurality of ring electrodes, a direct-current voltage has a first direct-current component whose amplitude changing along the axial direction and a second direct-current component whose amplitude changing along a predetermined direction on a plane where a ring electrode is located,
wherein the ions are transmitted off-axis and focused to a position closer to an inner surface of the ring electrode under a combined action of the radio-frequency voltages and the direct-current voltages.

2. The ion guide device according to claim 1 , wherein a shape of the ring electrode has at least one interior angle and the predetermined direction is pointed to the interior angle.

3. The ion guide device according to claim 2 , wherein the interior angle is an inferior angle of 30° to 150°.

4. The ion guide device according to claim 1 , wherein the radio-frequency multipole field extends in the axial direction inside the plurality of ring electrodes.

5. The ion guide device according to claim 1 , wherein the ring electrode has a plurality of electrode units with the same length.

6. The ion guide device according to claim 1 , wherein a length of each of the electrode units of each of the ring electrodes gradually decreases in the predetermined direction.

7. The ion guide device according to claim 1 , wherein the plurality of ring electrodes have the same shape and size.

8. The ion guide device according to claim 1 , wherein the ring electrode is a metal portion manufactured on a circuit board.

9. The ion guide device according to claim 8 , wherein each of the ring electrodes is manufactured on one or more circuit boards.

10. The ion guide device according to claim 8 , wherein the circuit board includes at least one gap and the gap is used for gas circulation.

11. An ion guide method, comprising the steps of:
providing a plurality of ring electrodes disposed in parallel, each of the ring electrodes includes at least 4 electrode units separated from each other, a channel for ion transmission is formed inside the plurality of ring electrodes, and an arrangement direction of the plurality of ring electrodes defines an axial direction of ion transmission;
applying out-of-phase radio-frequency voltages on the neighboring electrode units belonging to the same ring electrode, and applying in-phase radio frequency voltages on the neighboring electrode units along the axial direction, thereby forming an radio-frequency multipole field distributed along the axial direction in a device;
applying direct-current voltages to the plurality of ring electrodes, a direct-current voltage has a first direct-current component whose amplitude changing along the axial direction and a second direct-current component whose amplitude changing along a predetermined direction on a plane where a ring electrode is located; and
transmitting ions off-axis and focusing the ions to a position closer to an inner surface of the ring electrode under a combined action of the radio-frequency voltages and the direct-current voltages.

12. An ion guide device, comprising:
a plurality of ring electrodes disposed in parallel, each of the ring electrodes includes at least 4 electrode units separated from each other, a channel for ion transmission is formed inside the plurality of ring electrodes, and an arrangement direction of the plurality of ring electrodes defines an axial direction of ion transmission;
an radio-frequency voltage source, for applying out-of-phase radio-frequency voltages on the neighboring electrode units belonging to the same ring electrode, and applying in-phase radio frequency voltages on the neighboring electrode units along the axial direction, thereby forming an radio-frequency multipole field that confine ions in the ion guide device; and
a direct-current voltage source, which is used to apply direct-current voltages on the plurality of ring electrodes, a direct-current voltage has a second direct-current component whose amplitude changing along a predetermined direction on a plane where a ring electrode is located, so that the ions are deflected toward the electrode units directed in the predetermined direction,
wherein central angles between the electrode units directed in the predetermined direction and the adjacent electrode units are both less than or equal to π/8.

13. The ion guide device according to claim 12 , wherein the central angles of the electrode units directed in the predetermined direction and the adjacent electrode units are both less than or equal to π/16.

Assignees

• Shimadzu Corp

Inventors

• Wang Keke
• Zhang Xiaoqiang
• Sun Wenjian

Classifications

• H01J49/065 Primary

  having stacked electrodes, e.g. ring stack, plate stack · CPC title

• H01J49/022

  Circuit arrangements, e.g. for generating deviation currents or voltages (regulating electric or magnetic variables in general, e.g. current, magnetic field G05F); Components associated with high voltage supply (high voltage supply per se H02M) · CPC title

• H01J49/063

  Multipole ion guides, e.g. quadrupoles, hexapoles · CPC title