Apparatus and method for providing a time varying voltage

Patent metadata

Field	Value
Publication number	US-11506629-B2
Application number	US-201615575099-A
Country	US
Kind code	B2
Filing date	May 13, 2016
Priority date	May 21, 2015
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

An apparatus and method wherein the apparatus includes a channel; at least one pair of electrodes provided within sides of the channel; an electrolyte configured to move through the channel such that when the electrolyte is positioned between the at least one pair of electrodes the electrolyte provides a current path between the at least one pair of electrodes; and wherein the at least one pair of electrodes are configured such that movement of the electrolyte through the channel enables a time varying voltage to be provided.

First claim

We claim:

1. An apparatus comprising:
a channel;
at least one pair of electrodes,
each pair of the at least one pair of electrodes having a first electrode and a second electrode,
the first electrode and the second electrode being within opposite sides of the channel,
the first electrode comprising material configured to undergo oxidation with an electrolyte and the second electrode comprising material configured to undergo reduction with the electrolyte,
the first electrode being an anode and the second electrode being a cathode when the first electrode and the second electrode are in contact with an electrolyte in the channel,
at least one electrode of the at least one pair of electrodes comprising different materials at different points along the length of the channel, causing a potential difference between the at least one pair of electrodes and the electrolyte that is dependent upon the position of the electrolyte within the channel,
wherein the electrolyte, movable through the channel, is configured to be positioned between the first electrode and the second electrode, wherein the electrolyte provides a path for electric current generated by the first electrode, the second electrode, and the electrolyte, and enables via the path a potential difference between the first electrode and the second electrode to be realized,
wherein the at least one pair of electrodes, responsive at least to movement of the electrolyte through the channel, causes a time-varying voltage to be generated between the at least one pair of electrodes, at least because of the different materials and the potential differences of the at least one pair of electrodes at the different points along the length of the channel;

a first contact on the first electrode;
a second contact on the second electrode; and
sample circuitry connected across the first contact and the second contact, said sample circuitry being adapted to cause the at least one pair of electrodes to deliver the time-varying voltage to a test sample to be analyzed using the time-varying voltage.

2. The apparatus as claimed in claim 1 wherein the electrolyte comprises anionic solution configured to undergo an electrochemical reaction with the at least one pair of electrodes.

3. The apparatus as claimed in claim 1 wherein an inert liquid is provided adjacent to the electrolyte, and wherein the inert liquid is configured to not undergo an electrochemical reaction with the at least one pair of electrodes.

4. The apparatus as claimed in claim 3 wherein the electrolyte and the inert liquid are immiscible.

5. The apparatus as claimed in claim 1 wherein the sample circuitry is configured so the time-varying voltage provides a current to the test sample to enable an analyte to be detected within the test sample.

6. The apparatus as claimed in claim 1 wherein the channel and the electrolyte are configured such that the electrolyte is configured to move through the channel at a controlled rate.

7. The apparatus as claimed in claim 1 wherein the channel comprises a microfluidic channel.

8. A test device comprising an apparatus as claimed in claim 1 .

9. An apparatus comprising:
a channel;
at least one pair of electrodes,
each pair of the at least one pair of electrodes having a first electrode and a second electrode,
the first electrode and the second electrode being within opposite sides of the channel,
the first electrode comprising material configured to undergo oxidation with an electrolyte and the second electrode comprising material configured to undergo reduction with the electrolyte,
the first electrode being an anode and the second electrode being a cathode when the first electrode and the second electrode are in contact with an electrolyte in the channel,
wherein the electrolyte, movable through the channel, is configured to be positioned between the first electrode and the second electrode, wherein the electrolyte provides a path for electric current generated by the first electrode, the second electrode, and the electrolyte, and enables via the path a potential difference between the first electrode and the second electrode to be realized,
wherein the at least one pair of electrodes, responsive at least to movement of the-electrolyte through the channel, causes a time-varying voltage to be generated between the at least one pair of electrodes,

a first contact on the first electrode;
a second contact on the second electrode;
sample circuitry connected across the first contact and the second contact, said sample circuitry being adapted to cause the at least one pair of electrodes to deliver the time-varying voltage to a test sample to be analyzed using the time-varying voltage, and
at least one floating electrode provided in a wall of the channel.

10. The apparatus as claimed in claim 9 the floating electrode is configured to reduce current through the at least one pair of electrodes by collecting electrons from the electrolyte.

11. The apparatus as claimed in claim 9 wherein the at least one floating electrode comprises the same material as in the cathode of the at least one pair of electrodes.

12. The apparatus as claimed in claim 9 wherein the at least one floating electrode does not overlap another electrode.

13. A method comprising:
providing a channel; and
providing at least one pair of electrodes,
each pair of the at least one pair of electrodes having a first electrode and a second electrode,
the first electrode and the second electrode being within opposite sides of the channel,
the first electrode comprising material undergoing oxidation with an electrolyte and the second electrode comprising material configured to undergo reduction with the electrolyte,
the first electrode being an anode and the second electrode being a cathode when the first electrode and the second electrode are in contact with an electrolyte in the channel,
at least one electrode of the at least one pair of electrodes comprising different materials at different points along the length of the channel, causing a potential difference between the at least one pair of electrodes and the electrolyte that is dependent upon the position of the electrolyte within the channel,

causing the electrolyte to move through the channel, and to be positioned between the first electrode and the second electrode, wherein the electrolyte provides a path for electric current generated by the first electrode, the second electrode, and the electrolyte, and enables via the path a potential difference between the first electrode and the second electrode to be realized,
configuring the at least one pair of electrodes, responsive at least to movement of the electrolyte, to cause a time-varying voltage to be provided between the at least one pair of electrodes, at least because of the different materials and the potential difference of the at least one pair of electrodes at the different points along the length of the channel, wherein sample circuitry is connected across a first contact to the first electrode and a second contact to the second electrode,
said sample circuitry causing the at least one pair of electrodes to deliver the time-varying voltage to a test sample to be analyzed using the time-varying voltage.

Assignees

• Nokia Technologies Oy

Inventors

• Cotton Darryl
• Robinson Adam
• Wei Di

Classifications

• G01N27/49 Primary

  Systems involving the determination of the current at a single specific value, or small range of values, of applied voltage for producing selective measurement of one or more particular ionic species · CPC title

• H01H29/06

  Liquid contacts characterised by the material thereof · CPC title

• H01H2029/008

  using micromechanics, e.g. micromechanical liquid contact switches or [LIMMS] · CPC title

• G01N27/4166

  measuring a particular property of an electrolyte · CPC title

• H01H29/006 Primary

  Self interrupters, e.g. with periodic or other repetitive opening and closing of contacts · CPC title