Articles including fibrous substrates and porous polymeric particles and methods of making same

Patent metadata

Field	Value
Publication number	US-11505894-B2
Application number	US-201515512862-A
Country	US
Kind code	B2
Filing date	Sep 28, 2015
Priority date	Oct 1, 2014
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

Articles are provided that include a fibrous substrate and porous polymeric particles. At least 50% of the porous polymeric particles are bound to the fibrous substrate. Methods of making the articles are provided that include providing porous polymeric particles, providing a fibrous substrate, and binding the porous polymeric particles to the fibrous substrate. The articles can be used for fluid management.

First claim

What is claimed is:

1. An article comprising: 1) a fibrous substrate and 2) porous polymeric particles, wherein at least 50% of the porous polymeric particles are bound to the fibrous substrate, wherein the fibrous substrate comprises fibers having a lower glass transition temperature than the degradation temperature of the porous polymeric particles, and wherein the porous polymeric particles comprise a polymerized product of a reaction mixture comprising:
1) a first phase having a first volume and comprising
i) a compound of Formula (II)
HO(—CH 2 CH(OH)CH 2 O) n —H   (II)

wherein n is an integer equal to at least 1; and
ii) a nonionic surfactant;

2) a second phase having a second volume and being dispersed in the first phase, wherein the first volume is greater than the second volume and wherein the second phase comprises
i) a monomer composition comprising at least 10 weight percent of a first monomer of Formula (I)
CH 2 ═C(R 1 )—(CO)—O[—CH 2 —CH 2 —O] p —(CO)—C(R 1 )═CH 2   (I)

based on a total weight of the monomer composition, wherein p is an integer equal to at least 1 and R 1 is hydrogen or alkyl;
ii) at least one second monomer comprising a monomer of Formula (III)
CH 2 ═CR 1 —(CO)—O—Y—R 2   (III)

wherein
R 1 is hydrogen or methyl;
Y is a single bond, alkylene, oxyalkylene, or poly(oxyalkylene); and
R 2 is a carbocyclic group or heterocyclic group; and

iii) a poly(propylene glycol) having a weight average molecular weight of at least 500 grams/mole,
wherein the poly(propylene glycol) is removed from the polymerized product to provide the porous polymeric particles.

2. The article of claim 1 , wherein the fibrous substrate comprises blown melt fibers.

3. The article of claim 1 , wherein the fibrous substrate comprises fibers selected from the group consisting of polyesters, polyamides, polyurethanes, rubber elastomers, or combinations thereof.

4. The article of any of claim 1 , wherein the fibrous substrate comprises fibers selected the group consisting of polyethylene terephthalate, polybutylene terephthalate, nylon 6, nylon 66, polyester elastomers, and combinations thereof.

5. The article of any of claim 1 , wherein the at least one second monomer further comprises a monomer of Formula (IV)
CH 2 ═CR 1 —(CO)—O—R 3   (IV)

wherein
R 1 is hydrogen or methyl; and
R 3 is a linear or branched alkyl.

6. The article of claim 1 , wherein the at least one second monomer further comprises a hydroxyl-containing monomer of Formula (V) or Formula (VI)
CH 2 ═CR 1 —(CO)—O—R 4   (V)

CH 2 ═CR 1 —(CO)—O—R 5 —O—Ar   (VI)

wherein
R 1 is hydrogen or methyl;
R 4 is an alkyl substituted with one or more hydroxyl groups or is a group of formula —(CH 2 CH 2 O) q CH 2 CH 2 OH where q is an integer equal to at least 1; and
R 5 is an alkylene substituted with at least one hydroxyl group and the group Ar is an aryl group.

7. The article of any of claim 1 , wherein an active agent comprising an antimicrobial agent or moisture is adsorbed within at least some of the pores of the porous polymeric particles.

8. The article of any of claim 1 , wherein at least some of the porous polymeric particles are bound to the fibrous substrate with an adhesive, a binder, or a combination thereof.

9. The article of any of claim 1 , wherein upon immersion in water for 1 hour, the article does not expand in length in any direction.

10. The article of claim 1 , wherein at least 25% of the porous polymeric particles are fused to the fibrous substrate.

11. The article of claim 1 , wherein the article comprises 15 to 55 weight percent porous polymeric particles, based on a total dry weight of the article.

12. The article of claim 1 , wherein the article consists of the fibrous substrate and the porous polymeric particles.

13. The article of claim 1 , wherein the fibers comprise hydrophilic fibers.

14. The article of claim 1 , wherein the porous polymeric particles include particles in the form of hollow beads.

15. A method of making an article, the method comprising:
a) providing porous polymeric particles comprising a polymerized product of a reaction mixture comprising:
1) a first phase having a first volume and comprising
i) a compound of Formula (II)
HO(—CH 2 CH(OH)CH 2 O) n —H   (II)

wherein n is an integer equal to at least 1; and
ii) a nonionic surfactant;

2) a second phase having a second volume and being dispersed in the first phase, wherein the first volume is greater than the second volume and wherein the second phase comprises
i) a monomer composition comprising at least 10 weight percent of a first monomer of Formula (I)
CH 2 ═C(R 1 )—(CO)—O[—CH 2 —CH 2 -O] p —(CO)—C(R 1 )═CH 2   (I)

based on a total weight of the monomer composition, wherein p is an integer equal to at least 1 and R 1 is hydrogen or alkyl;
ii) at least one second monomer comprising a monomer of Formula (III)
CH 2 ═CR 1 —(CO)—O—Y—R 2   (III)

wherein
R 1 is hydrogen or methyl;
Y is a single bond, alkylene, oxyalkylene, or poly(oxyalkylene);
R 2 is a carbocyclic group or heterocyclic group; and

iii) a poly(propylene glycol) having a weight average molecular weight of at least 500 grams/mole,
wherein the poly(propylene glycol) is removed from the polymerized product to provide the porous polymeric particles;
wherein the poly(propylene glycol) is removed from the polymerized product to provide the porous polymeric particles;
b) providing a fibrous substrate comprising fibers, wherein the fibrous substrate comprises fibers having a lower glass transition temperature than the degradation temperature of the porous polymeric particles; and
c) binding the porous polymeric particles to the fibrous substrate, wherein at least 50% of the porous polymeric particles are bound to the fibrous substrate.

16. The method of claim 15 , wherein the binding comprises:
i) heating the fibrous substrate to a temperature above the glass transition temperature of the fibers;
ii) contacting the porous polymeric particles with the heated fibrous substrate; and
iii) cooling the porous polymeric particles and fibrous substrate to fuse porous polymeric particles to the fibrous substrate.

17. The method of claim 15 , wherein the binding the porous polymeric particles to the fibrous substrate is performed simultaneously with the providing a fibrous substrate.

18. The method of claim 17 , wherein the binding the porous polymeric particles to the fibrous substrate and the providing a fibrous substrate comprises:
i) extruding meltblown fibers comprising a polymeric material;
ii) metering porous polymeric particles into the meltblown fibers; and
iii) collecting the meltblown fibers and the porous polymeric particles as a nonwoven fibrous substrate comprising porous polymeric particles bound to the fibrous substrate.

19. The method of claim 18 , wherein the porous polymeric particles are metered using a particle dropper comprising a feed roll.

20. The method of claim 15 , wherein at least 25% of the porous polymeric particles are fused to the fibrous substrate.

Assignees

• 3M Innovative Properties Company

Inventors

• El Hedok Ibrahim A
• Sahouani Hassan
• Hanson Jennifer N
• Eaton Bradley W

Classifications

• D06M15/263 Primary

  of unsaturated carboxylic acids; Salts or esters thereof · CPC title

• D06M2200/11

  Oleophobic properties · CPC title

• D06M23/08

  Processes in which the treating agent is applied in powder or granular form (adhesives for multi-layer textile fabrics D06M17/00) · CPC title

• D06M15/53

  Polyethers (polyacetals D06M15/39) · CPC title

• D06M15/267

  of unsaturated carboxylic esters having amino or quaternary ammonium groups · CPC title