Method for producing hard metal powder, and hard metal powder

Patent metadata

Field	Value
Publication number	US-11504768-B2
Application number	US-201816486581-A
Country	US
Kind code	B2
Filing date	Feb 16, 2018
Priority date	Feb 17, 2017
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

A method for producing hard metal powder suitable for manufacturing hard metal products including metal carbides and a binder is provided. An easy to carry out method that provides high quality hard metal powder includes: a) dissolving in water, water soluble raw materials and a binder source to form an aqueous solution, b) drying the aqueous solution to form a precursor powder having the raw materials homogenously distributed throughout the precursor powder, c) decomposing the precursor powder by heating the powder in an inert atmosphere to remove gas evolved in the decomposition of the raw materials, d) grinding the precursor powder and mixing it with a liquid media to produce a suspension, e) spray drying the suspension to agglomerate the precursor powder, and f) heat treating the agglomerated precursor powder to form a hard metal powder containing agglomerates of carbides evenly distributed and bonded to a metallic matrix.

First claim

The invention claimed is:

1. A method for producing hard metal powder suitable for manufacturing hard metal products comprising metal carbides and a metallic binder, the method comprising:
a) dissolving water soluble raw materials in water comprising a hard particle source, comprising a carbon source, and a metallic binder source to form an aqueous solution,
b) drying in a drying process the aqueous solution to form a precursor powder having the water soluble raw materials homogenously distributed throughout the precursor powder,
c) decomposing the precursor powder in a first heat treatment by heating it in a temperature of 370° C. to 430° C. in an inert atmosphere to remove gas evolved in the decomposition of the water soluble raw materials,
d) grinding the precursor powder and mixing it with a liquid media to produce a suspension,
e) spray drying the suspension to agglomerate the precursor powder, and
f) heat treating the agglomerated precursor powder in a second heat treatment at 900° C. to 1150° C. in an inert atmosphere to form a hard metal powder containing agglomerates of carbides evenly distributed and bonded to a metallic matrix, wherein (f) is carried out immediately after (e).

2. The method according to claim 1 , wherein the hard particle source in (a) comprises, in addition to C, one or more of the chemical elements W, Cr, V, Ti, Zr, Mo, Ta, and Nb.

3. The method of claim 1 , wherein the hard particle source in (a) comprises ammonium meta tungstate forming a W (wolfram) source.

4. The method of claim 1 , wherein the metallic binder source in (a) comprises one or more of chemical elements Co, Cr, Ni, and Fe.

5. The method of claim 1 , wherein the hard particle source in (a) comprises glycine forming a C (carbon) source.

6. The method of claim 1 , wherein the metallic binder source in (a) comprises cobalt acetate forming a Co (cobalt) source.

7. The method of claim 1 , wherein the drying process in (b) is a spray drying process carried out in a hot gas.

8. The method of claim 1 , wherein the gas removed in (c) comprises NH 3 and H 2 O.

9. The method of claim 1 , wherein the precursor powder is grinded in (d) in a ball mill.

10. The method of claim 9 , wherein the liquid media in (d) is water.

11. The method of claim 9 , wherein the liquid media in (d) is ethanol.

12. The method of claim 1 , wherein the liquid media in (d) is water.

13. The method of claim 1 , wherein the liquid media in (d) is ethanol.

14. The method of claim 1 , wherein the spray drying in (e) is carried out in hot gas without a reducing agent.

15. The method of claim 14 , wherein the hot gas in (e) is air.

16. The method of claim 1 , wherein the inert atmosphere in (f) is argon.

17. The method of claim 1 , wherein the agglomerates of carbides in (f) have a size of 5 μm to 50 μm.

Assignees

• Teknologian Tutkimuskeskus Vtt Oy

Inventors

• Lagerbom Juha
• Karhu Marjaana
• Sinilehto Hanna-Mari
• Kanerva Ulla

Classifications

• B22F2301/00

  Metallic composition of the powder or its coating · CPC title

• B22F2301/20

  Refractory metals · CPC title

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• C22C29/10

  based on titanium carbide · CPC title

• B22F1/148

  Agglomerating · CPC title