Method and facility for storing and distributing liquefied hydrogen

Patent metadata

Field	Value
Publication number	US-11499675-B2
Application number	US-201917284411-A
Country	US
Kind code	B2
Filing date	Sep 24, 2019
Priority date	Oct 9, 2018
Publication date	Nov 15, 2022
Grant date	Nov 15, 2022

Abstract

The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.

First claim

What is claimed is:

1. A method of filling a liquid hydrogen tank, comprising the steps of:
transferring a first amount of liquid hydrogen into the tank, from a first source of liquid hydrogen that comprises a hydrogen liquefier, the first amount of liquid hydrogen being provided in order to lower a temperature and a pressure in the tank;
transferring a second amount of liquid hydrogen into the tank from a second source of liquid hydrogen that comprises a liquid hydrogen storage facility, wherein the second amount of liquid hydrogen is transferred into the tank by a difference in pressure between the liquid hydrogen storage facility and the tank; and
in between said steps of transferring a first amount and transferring a second amount, reducing a pressure within the tank by withdrawal of pressurized gas from the tank to a liquid phase of the storage facility in order to at least partially condense said pressurized gas in the storage facility.

2. The method of claim 1 , wherein the reduction of tank pressure further comprises a withdrawal of pressurized gas from the tank to the atmosphere.

3. The method of claim 1 , wherein the first amount of liquid hydrogen supplied by the first source of liquid hydrogen has a temperature below the bubble point of hydrogen at the storage pressure in the tank.

4. The method of claim 1 , wherein the first amount of liquid hydrogen transferred into the tank is one of: a predefined amount of liquid hydrogen, a predefined fraction of a volume of liquid storage in the tank, an amount of liquid hydrogen corresponding to a predefined duration of transfer of liquid hydrogen from the first source of liquid hydrogen to the tank with a specific flow rate, an amount of liquid hydrogen necessary to lower a temperature and pressure in the tank by respective predetermined values, and an amount of liquid hydrogen necessary to achieve, in the tank, respective predetermined temperature and pressure values.

5. The method of claim 1 , further comprising a step of transferring liquid hydrogen from the first source of liquid hydrogen to the liquid hydrogen storage facility at a temperature that is adjusted in order to maintain a temperature in the storage facility within a specific interval.

6. The method of claim 1 , further comprising reducing a pressure within the tank via a withdrawal of pressurized gas from the tank to the atmosphere, upon completion of which, a pressure within the tank remains greater than atmospheric pressure.

7. The filling method of claim 1 , further comprising, prior to said step of transferring a first amount, measuring or estimating an initial pressure within the tank.

8. The method of claim 7 , wherein, depending on the initial pressure within the tank before said step of transferring a first amount, said method comprises a step of reducing pressure within the tank or does not comprise a reduction of pressure within the tank.

9. The filling method of claim 7 , wherein, when the initial pressure within the tank is between 1.05 and 12 bar absolute, said step of transferring a second amount is carried out directly after said step of transferring a first amount without withdrawal of fluid from the tank between said steps of transferring a first amount and transferring a second amount.

10. The filling method of claim 7 , wherein, when the initial pressure within the tank is between 4 and 8 bar abs and the initial temperature in the tank is between 80 and 120 K, said method further comprises reducing a pressure within the tank between said steps of transferring a first amount and transferring a second amount.

11. The filling method of claim 7 , wherein, when the initial pressure within the tank is between 8 and 12 bar abs and the initial temperature in the tank is between 20 and 120 K, said method further comprises reducing a pressure within the tank between said steps of transferring a first amount and transferring a second amount.

12. The filling method of claim 1 , wherein the liquid hydrogen tank is a mobile tank of a semitrailer.

13. An installation for storage and distribution of liquefied hydrogen comprising: a liquid hydrogen storage facility at a specific storage pressure; at least one mobile tank to be filled; a source of gaseous hydrogen; a boil-off gas recovery pipe, a transfer pipe, and a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen storage facility, wherein:
the storage facility comprises a liquid withdrawal pipe comprising an end connected to the liquid hydrogen storage facility and at least one other end intended to be connected to the mobile tank(s);
the liquefier is configured to produce and to feed the storage facility with hydrogen at a temperature below the bubble point of hydrogen at the storage pressure;
the boil-off gas recovery pipe comprises an end intended to be connected to the tank(s) and an end intended to be connected to the storage facility;
in order to transfer boil-off gas into the storage facility for liquefaction thereof, the transfer pipe has an end connected to the outlet of the liquefier and an end intended to be connected directly to the tank(s); and
the installation is configured to fill the at least one tank by transferring a first amount of liquid hydrogen from the liquefier into the tank via the transfer pipe and then a second amount of liquid hydrogen from the storage facility to the tank via the liquid withdrawal pipe.

14. The installation of claim 13 , wherein the installation is further configured to produce, between the transfers of the first and second amounts, a withdrawal of pressurized gas to the atmosphere via a venting pipe.

15. The installation of claim 13 , further comprising a set of sensor(s) for measurement or estimation of an initial pressure within the tank before filling and the installation is further configured to produce or not produce, between the transfers of the first and second amounts, a decrease in the pressure within the tank as a function of said initial pressure and optionally temperature conditions within the tank.

16. The installation of claim 13 , wherein the recovery pipe is connected to the lower part of the storage facility in order to send the pressurized gas from the tank into the liquid phase of the storage facility.

17. The filling method of claim 1 , further comprising, prior to said step of transferring a first amount, measuring or estimating an initial pressure within the tank and optionally temperature conditions within the tank.

18. The method of claim 17 , wherein, depending on the initial pressure and temperature conditions within the tank before said step of transferring a first amount, said method comprises a step of reducing pressure within the tank or does not comprise a reduction of pressure within the tank.

19. The installation of claim 13 , further comprising a set of sensor(s) for measurement or estimation of an initial pressure and temperature conditions within the tank before filling and the installation is further configured to produce or not produce, between the transfers of the first and second amounts, a decrease in the pressure within the tank as a function of said initial pressure and temperature conditions within the tank.

Assignees

• Air Liquide

Inventors

• Allidieres Laurent
• De Souza Silva Renan Luis

Classifications

• F25J2290/34

  Details about subcooling of liquids · CPC title

• F17C2265/034

  with condensing the gas phase · CPC title

• F17C5/007 Primary

  for individual gas tanks or containers, e.g. in vehicles (filling with liquid fuel not under pressure, B60S5/02, B67D7/00) · CPC title

• F17C2265/063

  for supply of refuelling stations · CPC title

• F17C2221/012

  Hydrogen · CPC title