Reinforced separator for alkaline hydrolysis

Patent metadata

Field	Value
Publication number	US-11499240-B2
Application number	US-201816628695-A
Country	US
Kind code	B2
Filing date	Jul 9, 2018
Priority date	Jul 10, 2017
Publication date	Nov 15, 2022
Grant date	Nov 15, 2022

Abstract

A reinforced separator for alkaline hydrolysis includes a porous support, a first porous polymer layer contiguous with one side of the support and a second porous polymer layer contiguous with the other side of the support, characterized in that the maximum pore diameter at the outer surface of the first porous polymer layer PDmax(1) and of the second porous polymer layer PDmax(2) are different from each other and wherein a ratio between PDmax(2) and PDmax(1) is between 1.25 and 10.

First claim

The invention claimed is:

1. A method of preparing a reinforced separator for alkaline hydrolysis comprising:
a porous support;
a first porous polymer layer contiguous with a first side of the porous support; and
a second porous polymer layer contiguous with a second side of the porous support; wherein
a maximum pore diameter PD max (1) at an outer surface of the first porous polymer layer and a maximum pore diameter PD max (2) at an outer surface of the second porous polymer layer are different from each other; and
a ratio PD max (2)/PD max (1) is between 1.25 and 10, the method comprising:
applying a dope solution including a membrane polymer, a hydrophilic inorganic material, and a solvent on the first side and on the second side of a porous support; and
performing phase inversion on the dope solution applied to the first side of the porous support and the dope solution applied to the second side of the porous support to obtain a first porous polymer layer on the first side of the porous support and a second porous polymer layer on the second side of the porous support,
wherein the step of performing phase inversion on the dope solution applied to the first side of the porous support is different from the step of performing phase inversion on the dope solution applied to the second side of the porous support.

2. The method according to claim 1 , wherein the solvent in the dope solution is selected from the group consisting of N-methyl-2-pyrrolidone, N-ethyl-pyrrolidone, N,N-dimethyl-formamide, formamide, dimethylsulfoxide, N,N-dimethylacetamide, acetonitrile, and mixtures thereof.

3. The method according to claim 1 , wherein the dope solution further includes polyvinylpyrrolidone or glycerol.

4. The method according to claim 1 , wherein the dope solution applied to the first side of the porous support is different form the dope solution applied to the second side of the porous support.

5. The method according to claim 1 , wherein the step of performing phase inversion includes performing Vapour Induced Phase Separation and Liquid Induced Phase Inversion.

6. The method according to claim 5 , wherein the step of performing Vapour Induced Phase Separation on the dope solution applied to the first side of the porous support is different from the step of performing Vapour Induced Phase Separation on the dope solution applied to the second side of the porous support.

7. The method according to claim 5 , wherein the step of performing Liquid Induced Phase Inversion is performed in a coagulation bath including water.

8. The method according to claim 1 , further comprising:
transporting the porous support in a vertical position during the step of applying the dope solution and the step of performing phase inversion.

9. The method according to claim 1 , wherein PD max (1) is between 0.05 μm and 0.3 μm, and PD max (2) is between 0.2 μm and 6.5 μm.

10. The method according to claim 1 , wherein the ratio PD max (2)/PD max (1) is between 2 and 7.5.

11. The method according to claim 1 , wherein each of the first porous polymer layer and the second porous polymer layer includes a membrane polymer and a hydrophilic inorganic material.

12. The method according to claim 11 , wherein the membrane polymer includes polysulfone or polyethersulfone.

13. The method according to claim 11 , wherein the hydrophilic inorganic material is selected from the group consisting of TiO 2 , BaSO 4 , and ZrO 2 .

14. The method according to claim 12 , wherein the hydrophilic inorganic material is selected from the group consisting of TiO 2 , BaSO 4 , and ZrO 2 .

Assignees

• Agfa Gevaert Nv

Inventors

• Mues Willem

Classifications

• C25B1/04

  by electrolysis of water · CPC title

• C25B13/08

  based on organic materials · CPC title

• C25B13/02 Primary

  characterised by shape or form · CPC title

• C25B9/73

  of the filter-press type · CPC title

• B01D69/10

  Supported membranes; Membrane supports · CPC title