Boron-free corrosion inhibitors for metalworking fluids
US-2017009175-A1 · Jan 12, 2017 · US
US11499118B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11499118-B2 |
| Application number | US-201816754119-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 4, 2018 |
| Priority date | Oct 6, 2017 |
| Publication date | Nov 15, 2022 |
| Grant date | Nov 15, 2022 |
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An industrial fluid additive composition comprises one or more sequestering agents one or more compounds of formula (A): (A) wherein R 1 and R 2 are independently selected from substituted hydrocarbyl moieties containing from 1 to 10 carbon atoms or unsubstituted hydrocarbyl moieties containing from 1 to 10 carbon atoms.
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The invention claimed is: 1. An industrial fluid additive composition comprising: one or more sequestering agents comprising one or more phosphonate moieties, present in an amount of at least 5% by weight of the composition, and one or more compounds of formula (A): present in amounts in the range of from 10% to 50% by weight of the composition; wherein the compound of formula (A) contains from 5 to 12 carbon atoms; wherein R 1 and R 2 are independently selected from substituted hydrocarbyl moieties containing from 1 to 5 carbon atoms or unsubstituted hydrocarbyl moieties containing from 1 to 5 carbon atoms; and wherein the composition does not comprise a biocide. 2. The industrial fluid additive composition according to claim 1 , wherein R 1 and R 2 are independently selected from substituted alkyl moieties containing from 1 to 5 carbon atoms and unsubstituted alkyl moieties containing from 1 to 5 carbon atoms. 3. The industrial fluid additive composition according to claim 1 , wherein R 1 is n-butyl and R 2 is ethyl. 4. The industrial fluid additive composition according to claim 1 , wherein the one or more sequestering agents comprise a compound of formula (B): wherein R 3 is a substituted hydrocarbyl group containing from 1 to 10 carbon atoms, or an unsubstituted hydrocarbyl group containing from 1 to 10 carbon atoms. 5. The industrial fluid additive composition according to claim 4 , wherein R 3 is a substituted alkyl group comprising one or two phosphonate moieties. 6. The additive composition according to claim 1 , wherein the one or more sequestering agents are selected from 1-hydroxethane 1,1-diphosphonic acid, aminotris(methylenephosphonic acid), or a combination thereof. 7. An industrial fluid additive composition, comprising: one or more sequestering agents comprising polyacrylates, polyacrylic acids, polylactates, or any combination thereof, present in an amount of at least 5% by weight of the composition, and one or more compounds of formula (A): present in amounts in the range of from 10% to 50% by weight of the composition; wherein the compound of formula (A) contains from 5 to 12 carbon atoms; wherein R 1 and R 2 are independently selected from substituted hydrocarbyl moieties containing from 1 to 5 carbon atoms or unsubstituted hydrocarbyl moieties containing from 1 to 5 carbon atoms; and wherein the composition does not comprise a biocide. 8. The industrial fluid additive composition according to claim 1 , wherein at least a fraction of the compound of formula (A) and at least a fraction of the one or more sequestering agents are present in the composition in the form of an ammonium phosphonate salt. 9. The industrial fluid additive composition according to claim 1 , wherein the pH of the composition is from 8 to 10.5. 10. The industrial fluid additive composition according to claim 1 , wherein the compound of formula (A) is present in the composition in an amount of from 15% to 35% by weight of the composition; and the one or more sequestering agents are present in an amount of from 5% to 20% by weight of the composition. 11. The industrial fluid additive composition according to claim 10 , wherein the composition further comprises water, present in an amount of from 30% to 60% by weight of the composition. 12. The industrial fluid additive composition according to claim 1 , further comprising one or more surfactants. 13. A metalworking fluid comprising an industrial fluid additive composition according to claim 1 . 14. The metalworking fluid according to claim 13 , wherein the one or more compounds of formula (A) are present in the metalworking fluid in an amount of from 0.1% to 0.35% by weight of the metal working fluid. 15. The metalworking fluid according to claim 13 , wherein the metalworking fluid is in the form of a water-in-oil emulsion or an oil-in-water emulsion. 16. A method of cutting, grinding or cleaning a metal, the method comprising applying a metalworking fluid according to claim 13 to said metal; and cutting, grinding or cleaning the metal while the metalworking fluid is in contact with said metal. 17. The metalworking fluid according to claim 13 , wherein the metalworking fluid comprises water and an oil. 18. A method for making a metalworking fluid, comprising providing a metalworking fluid, and adding the industrial fluid additive composition according to claim 1 to the metalworking fluid.
Polyesters · CPC title
with essential removal of material {, e.g. cutting, grinding or drilling} · CPC title
having cycloaliphatic groups · CPC title
Imides [having hydrocarbon substituents containing less than thirty carbon atoms] · CPC title
Ammonium or amine salts · CPC title
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