Catalytic upcycling of polymers
US-2021061971-A1 · Mar 4, 2021 · US
US11499110B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11499110-B2 |
| Application number | US-202017018702-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 11, 2020 |
| Priority date | Sep 11, 2020 |
| Publication date | Nov 15, 2022 |
| Grant date | Nov 15, 2022 |
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A method of upcycling polymers to useful hydrocarbon materials. A catalyst with nanoparticles on a substrate selectively docks and cleaves longer hydrocarbon chains over shorter hydrocarbon chains. The nanoparticles exhibit an edge to facet ratio to provide for more interactions with the facets.
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What is claimed is: 1. A method of producing a lubricant comprising: exposing, at a temperature of 150-350° C. and a pressure of 100-200 psi for 12— 72 hours, a plurality of polymer molecules to a catalyst comprising a substrate having a plurality of catalytic nanoparticles deposited thereon; docking a first polymer molecule of the plurality of polymer molecules to the catalyst; cleaving at least one carbon-carbon bond of the first polymer molecule; forming a plurality of hydrocarbon fragments from the cleaving; selectively docking to the catalyst a second polymer molecule of the plurality of polymer molecules, preferentially over the plurality of hydrocarbon fragments; cleaving at least one carbon-carbon bond of the second polymer molecule; and forming a second plurality of hydrocarbon fragments. 2. The method of claim 1 , wherein exposing the plurality of polymer molecules is for at least 24 hours. 3. The method of claim 1 , wherein the plurality of catalytic nanoparticles comprise Pt or Ni. 4. The method of claim 1 , wherein the substrate comprises a perovskite. 5. The method of claim 4 , wherein the substrate comprises strontium titanate. 6. The method of claim 3 , wherein the substrate comprises alumina. 7. The method of claim 1 , wherein the plurality of polymer molecules are solvent-free. 8. The method of claim 1 , wherein the plurality of polymer molecules have a molecular weight ranging from 400-1000 Da (number average molecular weight). 9. The method of claim 8 , wherein the plurality of hydrocarbon fragments are C 30 to C 76 alkanes. 10. The method of claim 9 , wherein the plurality of hydrocarbon fragments have 10 branches per 1000 carbon to 400 branches per 1000 carbon. 11. The method of claim 10 , wherein the plurality of hydrocarbon fragments are saturated hydrocarbons. 12. The method of claim 1 , wherein the first polymer molecule is polyethylene. 13. The method of claim 11 , wherein the first polymer is linear low-density polyethylene. 14. The method of claim 11 , wherein the first polymer is linear high-density polyethylene.
from rubber or rubber waste · CPC title
Reduction, e.g. hydrogenation · CPC title
saturated · CPC title
used as base material · CPC title
Alumina · CPC title
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