Resin composition, resin-coating material, vehicle wire harness and method of producing vehicle wire harness

Patent metadata

Field	Value
Publication number	US-11499067-B2
Application number	US-201916683744-A
Country	US
Kind code	B2
Filing date	Nov 14, 2019
Priority date	Jul 5, 2017
Publication date	Nov 15, 2022
Grant date	Nov 15, 2022

Abstract

A resin composition, containing an ethylene-vinyl acetate copolymer (A); and 15 to 30 mass parts of a bromine-based flame retardant (B), 5 to 15 mass parts of antimony trioxide (C), 6 to 12 mass parts of a benzimidazole-based aging retardant (D), 2 to 4 mass parts of a phenol-based aging retardant (E), 2 to 4 mass parts of a thioether-based aging retardant (F), 0.5 to 2 mass parts of a copper inhibitor (G), and 3 to 6 mass parts of a crosslinking aid (H), with respect to 90 to 100 mass parts of the ethylene-vinyl acetate copolymer (A);
a vehicle wire harness; and, a method of producing a vehicle wire harness.

First claim

The invention claimed is:

1. A resin composition, comprising:
an ethylene-vinyl acetate copolymer (A); and
15 to 30 mass parts of a bromine-based flame retardant (B), 5 to 15 mass parts of antimony trioxide (C), 6 to 12 mass parts of a benzimidazole-based aging retardant (D), 2 to 4 mass parts of a phenol-based aging retardant (E), 2 to 4 mass parts of a thioether-based aging retardant (F), 0.5 to 2 mass parts of a copper inhibitor (G), and 3 to 6 mass parts of a crosslinking aid (H), with respect to 90 to 100 mass parts of the ethylene-vinyl acetate copolymer (A).

2. The resin composition according to claim 1 , comprising 1 to 10 mass parts of a maleic acid-modified polyethylene (I).

3. The resin composition according to claim 1 , which is the resin composition is a resin composition for a resin-coating material layer of an insulated wire.

4. The resin composition according to claim 1 , wherein the ethylene-vinyl acetate copolymer (A) is any one of (1) an ethylene-vinyl acetate copolymer, (2) a combination of an ethylene-vinyl acetate copolymer and a maleic acid-modified polyethylene, and (3) a combination of an ethylene-vinyl acetate copolymer, a maleic acid-modified polyethylene and a low-density polyethylene.

5. The resin composition according to claim 4 , the content of the ethylene-vinyl acetate copolymer (A) is 90 to 100 mass parts when the total amount of the resin of the resin composition is taken as 100 mass parts, and in the case of containing the maleic acid-modified polyethylene, the content of the maleic acid-modified polyethylene is 1 to 10 mass parts.

6. The resin composition according to claim 1 , which is used for a vehicle wire harness.

7. A resin-coating material obtained by crosslinking the resin composition according to claim 1 .

8. A vehicle wire harness, comprising a layer composed of the resin-coating material according to claim 7 .

9. A method of producing of a vehicle wire harness, which comprises a step of irradiating electron beams of 80 to 250 kGy to a resin composition;
wherein the resin composition comprises from 90 to 100 mass parts of an ethylene-vinyl acetate (A), from 15 to 30 mass parts of a bromine-based flame retardant (B), from 5 to 15 mass parts of antimony trioxide (C), from 6 to 12 mass parts of a benzimidazole-based aging retardant (D), from 2 to 4 mass parts of a phenol-based aging retardant (E), from 2 to 4 mass parts of a thioether-based aging retardant (F), from 0.5 to 2 mass parts of a copper inhibitor (G), and from 3 to 6 mass parts of a crosslinking aid (H).

10. The method of producing of a vehicle wire harness according to claim 9 , comprising a step of irradiating electron beams of 80 to 250 kGy to a resin composition after extrusion-coating of the resin composition on the periphery of a conductor to provide a coating material layer.

11. The method of producing of a vehicle wire harness according to claim 9 , wherein the ethylene-vinyl acetate copolymer (A) is any one of (1) an ethylene-vinyl acetate copolymer, (2) a combination of an ethylene-vinyl acetate copolymer and a maleic acid-modified polyethylene, and (3) a combination of an ethylene-vinyl acetate copolymer, a maleic acid-modified polyethylene and a low-density polyethylene.

12. The method of producing of a vehicle wire harness according to claim 9 , the content of the ethylene-vinyl acetate copolymer (A) is 90 to 100 mass parts when the total amount of the resin of the resin composition is taken as 100 mass parts, and in the case of containing the maleic acid-modified polyethylene, the content of the maleic acid-modified polyethylene is 1 to 10 mass parts.

Assignees

• Furukawa Electric Co Ltd
• Furukawa Automotive Systems Inc

Inventors

• Takahashi Kenji
• Sawada Yuka
• Oshino Takashi
• Suzuki Yutaka
• Uchiyama Yasuharu
• Osuga Hideyuki

Classifications

• H01B3/44

  vinyl resins; acrylic resins (silicones H01B3/46) · CPC title

• H01B7/295

  using material resistant to flame · CPC title

• B29K2105/0085

  Copolymers · CPC title

• H01B3/00

  Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties · CPC title

• B29K2105/0044

  Stabilisers, e.g. against oxydation, light or heat · CPC title