Functionalized graphene and epoxy composite

Patent metadata

Field	Value
Publication number	US-11499033-B2
Application number	US-202016881485-A
Country	US
Kind code	B2
Filing date	May 22, 2020
Priority date	May 22, 2020
Publication date	Nov 15, 2022
Grant date	Nov 15, 2022

Abstract

A polymer composite formed from an epoxy based polymer and an amino-graphene. The epoxy based polymer forms a polymer matrix and the amino graphene is dispersed throughout the polymer matrix. Further, a graphene is functionalized with 3,5-dinitrophenyl groups to form functionalized graphene and one or more amine functional groups form Meisenheimer complexes with the functionalized graphene to form the amino-graphene. An associated method of making the polymer composite is also provided.

First claim

What is claimed is:

1. A polymer composite comprising
an epoxy based polymer forming a polymer matrix, and
an amino-graphene dispersed throughout the polymer matrix,
wherein a graphene is functionalized with 3,5-dinitrophenyl groups to form functionalized graphene and one or more amine functional groups form Meisenheimer complexes with the functionalized graphene to form the amino-graphene, and the graphene in the functionalized graphene has an average platelet thickness of less than 10 atomic layers.

2. The polymer composite of claim 1 , wherein the one or more amine functional groups are primary amines.

3. The polymer composite of claim 1 , wherein the one or more amine functional groups are selected from one or more of aliphatic amines, cycloaliphatic amines, aromatic amines, hydrazines, hydrazides, functionalized amines, silanized amines, and their polyamines and derivatives.

4. The polymer composite of claim 1 , wherein the polymer matrix comprises a bulk polymer matrix and interface regions, the interface regions representing domains at interfaces that are rich in the epoxy based polymer or the amino-graphene, and
wherein the amino-graphene is homogenously integrated throughout the bulk polymer matrix with less than a 10% variance in the concentration of the amino-graphene from a region of highest concentration to a region of lowest concentration within the bulk polymer matrix.

5. The polymer composite of claim 1 , wherein the amino-graphene is provided in the polymer matrix at 0.1 to 2 wt. % of the polymer composite.

6. The polymer composite of claim 1 , wherein the graphene in the functionalized graphene has an average platelet thickness of less than 5 atomic layers.

7. The polymer composite of claim 1 , wherein at least 95% of the graphene in the functionalized graphene is single atomic layer graphene.

8. The polymer composite of claim 1 , wherein the polymer composite further comprises one or more fillers functionalized with 3,5-dinitrophenyl groups in addition to the functionalized graphene.

9. The polymer composite of claim 8 , wherein the fillers are selected from one or more of SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 , graphene oxides, and carbon nanotubes.

10. The polymer composite of claim 1 , wherein the amino-graphene acts as a co-cross-linker of the polymer matrix.

11. The polymer composite of claim 1 , wherein the epoxy based polymer is formed from a bisphenol A based epoxy resin.

12. The polymer composite of claim 1 , wherein the polymer matrix is functionalized with 3,5-dinitrophenyl groups along a polymer backbone of the epoxy based polymer.

13. The polymer composite of claim 1 , wherein the polymer composite demonstrates self-healing capabilities after relaxation of an applied strain.

14. The polymer composite of claim 1 , wherein the graphene in the functionalized graphene is formed from highly oriented pyrolytic graphite.

Assignees

• Saudi Arabian Oil Co
• Massachusetts Inst Technology

Inventors

• Alamri Haleema A
• Swager Timothy Manning
• Fihri Aziz
• Altaie Ihsan
• Zhu S Sherry

Classifications

• C08K3/042

  Graphene or derivatives, e.g. graphene oxides · CPC title

• C08K9/04 Primary

  Ingredients treated with organic substances {(treated with macromolecular compounds C08K9/08)} · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• C01B2204/04

  Specific amount of layers or specific thickness · CPC title