Composite active material

Patent metadata

Field	Value
Publication number	US-11495789-B2
Application number	US-201514660052-A
Country	US
Kind code	B2
Filing date	Mar 17, 2015
Priority date	May 13, 2014
Publication date	Nov 8, 2022
Grant date	Nov 8, 2022

Abstract

According to one embodiment, there is provided a composite. The composite includes active material particles of a titanium composite oxide or oxide of titanium, and a graphene structure including a carbon material. The carbon material has a graphene framework defining a graphene surface. The graphene structure is located in between the active material particles. The graphene structure has at least one side surface in contact with the active material particle. The side surface includes the carbon material whose graphene surface is slanted relative to the side surface.

First claim

What is claimed is:

1. A nonaqueous electrolyte battery comprising:
a negative electrode;
a positive electrode; and
a nonaqueous electrolyte,
wherein the negative electrode comprises:
a negative electrode current collector; and
a negative electrode layer formed on the negative electrode current collector, wherein the negative electrode layer comprises a nonaqueous electrolyte battery active material and a binder, wherein the nonaqueous electrolyte battery active material and the binder are comprised in the negative electrode layer in a dispersed state, and wherein the nonaqueous electrolyte battery active material comprises a composite comprising:
active material particles of a titanium composite oxide or an oxide of titanium; and
a graphene structure comprising a plurality of carbon materials each having a graphene framework defining a graphene surface, wherein the graphene structure has a form of a column or fiber, wherein the column and fiber precludes a tube, wherein the carbon materials are stacked such that 50% or more of the graphene surface is overlapped with another graphene surface, wherein the graphene structure is in a state of being dispersed among the active material particles and having at least one side surface of the column or fiber in contact with the active material particles, and wherein the carbon materials comprise exterior carbon materials constituting at least one side surface of the column or fiber and interior carbon materials separate from the exterior carbon materials, wherein the graphene surface of each of the exterior carbon materials is slanted relative to the at least one side surface of the column or fiber, and the interior carbon materials do not constitute any side surface of the column or fiber.

2. The nonaqueous electrolyte battery according to claim 1 , wherein the graphene surface is slanted relative to the at least one side surface at an angle of from 5° to 80°.

3. The nonaqueous electrolyte battery according to claim 1 , wherein the active material particles comprise the titanium composite oxide.

4. The nonaqueous electrolyte battery according to claim 3 , wherein the titanium composite oxide is represented by the following formula:
Li x Ti 1-y M1 y Nb 2-z M2 z O 7 ,
wherein indexes x, y and z are respectively within a range of 0≤x≤5, 0≤y<1, and 0≤z≤2, M1 is at least one element selected from a group consisting of Zr, Si, and Sn, and M2 is at least one element selected from a group consisting of V, Nb, Ta, and Bi.

5. The nonaqueous electrolyte battery according to claim 3 , wherein the titanium composite oxide is represented by the following formula:
Li 4+x Ti 5 O 12 ,
wherein x is within a range of 0≤x≤3.

6. The nonaqueous electrolyte battery according to claim 1 , wherein the active material particle further comprises a carbon layer on its surface.

7. The nonaqueous electrolyte battery according to claim 6 , wherein the carbon layer comprises a graphene fragment having a diameter of 200 nm or less.

8. The nonaqueous electrolyte battery according to claim 1 , wherein the carbon material further comprises at least one element selected from a group consisting of nitrogen, oxygen, and phosphorus.

9. The nonaqueous electrolyte battery according to claim 1 , comprising a lithium ion, a sodium ion, or a magnesium ion as a charge carrier.

10. The nonaqueous electrolyte battery according to claim 1 , wherein the negative electrode layer further comprises a conductive agent.

11. The nonaqueous electrolyte battery of claim 1 , wherein the graphene structure has a cavity at an end portion.

12. The nonaqueous electrolyte battery of claim 1 , wherein the graphene structure has the form of a column.

Assignees

• Toshiba Kk

Inventors

• Naito Katsuyuki
• Harada Yasuhiro
• Yoshinaga Norihiro
• Akasaka Yoshihiro

Classifications

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/485 Primary

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title