Self-repairing cement polymer composites and processes of making and using same
US-2018044570-A1 · Feb 15, 2018 · US
US11492866B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11492866-B2 |
| Application number | US-201615262643-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 12, 2016 |
| Priority date | Sep 12, 2016 |
| Publication date | Nov 8, 2022 |
| Grant date | Nov 8, 2022 |
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A downhole tool for controlling the flow of a fluid in a wellbore includes a component that comprises: a cementitious material; an aggregate; and a ductility modifying agent comprising one or more of the following: an ionomer; a functionalized filler; the functionalized filler comprising one or more of the following: functionalized carbon; functionalized clay; functionalized silica; functionalized alumina; functionalized zirconia; functionalized titanium dioxide; functionalized silsesquioxane; functionalized halloysite; or functionalized boron nitride; a metallic fiber; or a polymeric fiber.
Opening claim text (preview).
What is claimed is: 1. A downhole tool for controlling the flow of a fluid in a wellbore, the downhole tool including a component, the component comprising: about 15 wt. % to about 50 wt. % of a cementitious material; about 20 wt. % to about 60 wt. % of an aggregate comprising sand, gravel, silica, slag, recycled concrete, glass spheres, limestone, feldspar, crushed stone, or a combination comprising at least one of the foregoing; and about 0.1 wt. % to about 10 wt. % of a ductility modifying agent, based on the total weight of the component; wherein the ductility modifying agent comprises a metal fiber and an ionomer; the ionomer comprises a polymer backbone formed from an ethylenically unsaturated carboxylic acid; and the component is a molded component made from a composition comprising the cementitious material, the aggregate; and the ductility modifying agent. 2. The downhole tool of claim 1 , wherein the metal fiber comprises steel fiber or iron fiber. 3. The downhole tool of claim 1 , wherein the cementitious material comprises one or more of the following: Portland cement; pozzolan cement; gypsum cement; high alumina content cement; silica cement; or high alkalinity cement. 4. The downhole tool of claim 1 , wherein the component further comprises one or more of the following: wollastonite; silica flour; silica fume; fly ash; calcium carbonate; barite; hematite; ilemite; siderite; hydroxyapatite; fluorapatite; or chlorapatite. 5. The downhole tool of claim 1 , wherein the component comprises: about 0.1 to about 8 wt. % of the metal fiber; about 15 to about 50 wt. % of the cementitious material; and about 20 to about 60 wt % of the aggregate, each based on the total weight of the component. 6. The downhole tool of claim 1 , wherein the downhole tool is a frac plug or a bridge plug. 7. The downhole tool of claim 1 , wherein the component comprises about 25 to about 40 wt. % of a cementitious material, about 5 wt. % to about 12 wt. % of silica fume, about 5 wt. % to about 15 wt. % of quartz powder, about 30 wt. % to about 45 wt. % of sand, about 0.5 wt. % to about 7 wt. % of a metal fiber, and about 0.1 wt. % to about 5 wt. % of a superplasticizer, each based on the total weight of the component. 8. The downhole tool of claim 1 , wherein the component is a frustoconical member; and the downhole tool further comprises: an annular body having a flow passage therethrough; a seal member carried on the annular body and configured to engage a portion of the frustoconical member; and a bottom sub disposed about the annular body, and wherein the frustoconical member is disposed about the annular body. 9. The downhole tool of claim 1 , wherein the component is a bottom sub; and the downhole tool further comprises: an annular body having a flow passage therethrough; a frustoconical member disposed about the annular body; a seal member carried on the annular body and configured to engage a portion of the frustoconical member; and the bottom sub is disposed about the annular body. 10. The downhole tool of claim 1 , wherein the component further comprises an aqueous carrier in an amount of about 0.1 to about 30 wt % based on total weight of the component. 11. The downhole tool of claim 1 , wherein all solid particles in the component have a particle size of less than about 100 microns. 12. The downhole tool of claim 1 , wherein the component has a compressive strength of about 5 ksi to about 150 ksi. 13. The downhole tool of claim 1 , wherein the component has a compressive strength of about 20 ksi to about 60 ksi. 14. The downhole tool of claim 1 , wherein the component is a frustoconical member.
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containing mixtures of the silica-lime type · CPC title
containing calcium sulfate cements {(gypsum-paper plates E04C)} · CPC title
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