Method of making an ash-based mortar composition

Patent metadata

Field	Value
Publication number	US-11492293-B2
Application number	US-202117397390-A
Country	US
Kind code	B2
Filing date	Aug 9, 2021
Priority date	Jul 25, 2019
Publication date	Nov 8, 2022
Grant date	Nov 8, 2022

Abstract

A mortar composition, which includes (i) a treated palm oil fuel ash, wherein the treated palm oil fuel ash is the only binder present, (ii) a fine aggregate, (iii) an alkali activator containing an aqueous solution of sodium hydroxide and sodium silicate, and (iv) aluminum hydroxide as a strength enhancer. A cured mortar made from the mortar composition is also disclosed with advantageous compressive strength properties.

First claim

The invention claimed is:

1. A method of making a mortar composition, wherein the mortar composition comprises:
a treated palm oil fuel ash as a binder, wherein the treated palm oil fuel ash is the only binder present;
a fine aggregate;
an alkali activator comprising an aqueous solution of sodium hydroxide and sodium silicate; and
aluminum hydroxide as a strength enhancer which is the only strength enhancer present in the mortar composition,
wherein the treated palm oil fuel ash is present in the mortar composition in an amount of 20 to 30 wt. %, based on a total weight of the mortar composition,
wherein the treated palm oil fuel ash comprises, as constituent oxides, 60 to 72 wt. % SiO 2 , 4 to 8 wt. % Al 2 O 3 , 3 to 7 wt. % Fe 2 O 3 , 3 to 8 wt. % CaO, 1 to 5 wt. % MgO, 3 to 7 wt. % K 2 O, 0.2 to 0.5 wt. % SO 3 , 0.1 to 0.25 wt. % Na 2 O, and 1 to 5 wt. % of P 2 O 3 , each based on a total weight of the treated palm oil fuel ash, and
wherein the treated palm oil fuel ash has a median particle size (d 50 ) of 0.5 to 2.0 μm;
the method comprising:
first forming the treated palm oil fuel ash by combusting palm shells and fibers to form a raw palm oil fuel ash; drying the raw palm oil fuel ash to form dried palm oil fuel ash; grinding the dried palm oil fuel ash by a mechanical ball mill to form ground palm oil fuel ash; heating the ground palm oil fuel ash to form a calcined palm oil fuel ash; then grinding the calcined palm oil fuel ash to form the treated palm oil fuel ash; then
mixing the treated palm oil fuel ash with the fine aggregate, the alkali activator, the aluminum hydroxide and water to form the mortar composition.

2. The method of claim 1 , wherein the treated palm oil fuel ash has a loss on ignition (LOI) of less 3 wt. %, based on a total weight of the treated palm oil fuel ash, and a specific surface area of 1.4 to 1.6 m 2 /g.

3. The method of claim 1 , wherein a weight ratio of the fine aggregate to the treated palm oil fuel ash in the mortar composition is 1:1 to 2:1.

4. The method of claim 1 , wherein the fine aggregate has a fineness modulus of 1.8 to 2.1 and a saturated surface dry (SSD) specific gravity of 2.5 to 2.7.

5. The method of claim 1 , wherein a weight ratio of the alkali activator to the treated palm oil fuel ash in the mortar composition is 0.3:1 to 0.7:1.

6. The method of claim 1 , wherein a weight ratio of sodium silicate to sodium hydroxide in the mortar composition is 1:1 to 3:1.

7. The method of claim 1 , wherein a weight ratio of the aluminum hydroxide to the treated palm oil fuel ash in the mortar composition is 0.01:1 to 0.05:1.

8. The method of claim 1 , wherein the mortar composition has weight ratio of water to the treated palm oil fuel ash of 0 .2 to 0.98.

9. The method of claim 1 , wherein the mortar composition consists of the treated palm oil fuel ash, the fine aggregate, sodium hydroxide, sodium silicate, aluminum hydroxide, and water.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Salami Babatunde Abiodun
• Johari Megat Azmi Megat
• Maslehuddin Mohammed
• Ahmad Zainal Arifin

Classifications

• C04B26/003 Primary

  Oil-based binders, e.g. containing linseed oil · CPC title

• C04B18/087

  from liquid fuels, e.g. oil · CPC title

• C04B18/02

  Agglomerated materials {, e.g. artificial aggregates} · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B28/021 Primary

  Ash cements, e.g. fly ash cements (fly ash as filler C04B18/08); Cements based on incineration residues, e.g. alkali-activated slags from waste incineration (alkali-activated combustion residues as such C04B7/243; mixtures of the lime-pozzuolane type C04B28/18); Kiln dust cements · CPC title