Zeolite-like metal-organic frameworks with ana topology

Patent metadata

Field	Value
Publication number	US-11491459-B2
Application number	US-202017008419-A
Country	US
Kind code	B2
Filing date	Aug 31, 2020
Priority date	Sep 11, 2014
Publication date	Nov 8, 2022
Grant date	Nov 8, 2022

Abstract

Embodiments of the present disclosure provide a metal-organic framework composition including a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers. Embodiments of the present disclosure further provide a method of separating chemical species including contacting a metal-organic framework having an ana topology with a flow of paraffins and separating the paraffins.

First claim

What is claimed is:

1. A metal-organic framework composition comprising:
a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers, wherein the metal-organic framework has pores that are tunable to within a range of about 0.5 Å or less.

2. The metal-organic framework composition of claim 1 , wherein the metal-organic framework includes a three-dimensional channel system.

3. The metal-organic framework composition of claim 1 , wherein the ana topology includes a metal connected to four organic linkers in a tetrahedral arrangement.

4. The metal-organic framework composition of claim 1 , wherein the one or more metals are selected from the group consisting of zinc, copper, nickel, cobalt, and iron.

5. The metal-organic framework composition of claim 1 , wherein the one or more metals are selected from the group consisting of yttrium, cadmium, and indium.

6. The metal-organic framework composition of claim 1 , wherein the one or more metals are selected from the group consisting of La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu.

7. The metal-organic framework composition of claim 1 , wherein the one or more metals are selected from the group consisting of zinc, copper, nickel, cobalt, iron, yttrium, cadmium, indium, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu.

8. The metal-organic framework composition of claim 1 , wherein the one or more metals are selected from the group consisting of Be, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ac, Th, Pa, U, Np, Pu, Am, Cm, Bk, Cf, Es, Fm, Md, No, and Lr.

9. The metal-organic framework composition of claim 1 , wherein the one or more organic linkers are selected from the group consisting of 1H-Imidazole-4, 5-dicarboxylic acid; 1H-Imidazole-2-carboxylic acid; pyrimidine-4,6-dicarboxcylic acid; and pyridine-2,5-dicarboxylic acid.

10. The metal-organic framework composition of claim 1 , wherein the one or more organic linkers are selected from the group consisting of 2,7-diaza-anthracene-1,8-dicarboxylic acid and 2,7-diaza-anthracene-3,6-dicarboxylic acid.

11. The metal-organic framework composition of claim 1 , further comprising one or more of lithium, sodium, potassium, rubidium, cesium, francium, beryllium, magnesium, calcium, strontium, barium, and radium.

12. A metal-organic framework composition comprising:
a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers, wherein the one or more organic linkers are selected from the group consisting of 1H-Imidazole-4, 5-dicarboxylic acid; 1H-Imidazole-2-carboxylic acid; pyrimidine-4,6-dicarboxcylic acid; and pyridine-2,5-dicarboxylic acid.

13. A metal-organic framework composition comprising:
a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers, wherein the one or more organic linkers are selected from the group consisting of 2,7-diaza-anthracene-1,8-dicarboxylic acid and 2,7-diaza-anthracene-3,6-dicarboxylic acid.

Assignees

• Univ King Abdullah Sci & Tech

Inventors

• Eddaoudi Mohamed
• Belmabkhout Youssef
• Mohideen Mohamed Infas Haja
• Adil Karim
• Bhatt Prashant M
• Shekhah Osama
• Chernikova Valeriya

Classifications

• F02B1/14

  Methods of operating · CPC title

• C01B2203/1247

  Higher hydrocarbons · CPC title

• B01J20/28033

  Membrane, sheet, cloth, pad, lamellar or mat · CPC title

• C10L1/06

  for spark ignition · CPC title

• F02M25/12

  the apparatus having means for generating such gases (using rays and simultaneously generating ozone F02M27/06) · CPC title