Substituted heterocycles as harmful arthropod controlling agents

Patent metadata

Field	Value
Publication number	US-11490622-B2
Application number	US-201816954871-A
Country	US
Kind code	B2
Filing date	Dec 21, 2018
Priority date	Dec 22, 2017
Publication date	Nov 8, 2022
Grant date	Nov 8, 2022

Abstract

The present invention provides a compound substituted with an excellent control effect against a harmful arthropod, which is represented by formula (I)Het-Q  (I)wherein Q represents a group represented by Q1, etc., Het represents a group represented by Het1, etc., R2 represents a C1-C6 alkyl group, etc., G1 represents a nitrogen atom or CR3a, G2 represents a nitrogen atom or CR3b, G3 represents a nitrogen atom or CR3c, G4 represents a nitrogen atom or CR3d, R3a, R3b, R3c, and R3d are identical to or different from each other and represent a C1-C6 chain hydrocarbon group, etc., n represents 0, 1, or 2, T represents a C1-C10 chain hydrocarbon group substituted with one or more halogen atoms, etc., A2 represents a nitrogen atom or CR4a, A3 represents a nitrogen atom or CR4b, R4a and R4b are identical to or different from each other and represent a C1-C6 chain hydrocarbon group, W1 represents an oxygen atom, etc., and R6 represents a C1-C6 chain hydrocarbon group, etc.

First claim

The invention claimed is:

1. A compound represented by formula (I):
Q-Het  (I)

wherein,
Q represents Q1 or Q2:

wherein:

represents:

represents

R 2 represents C 1 -C 6 alkyl, wherein the C 1 -C 6 alkyl is optionally substituted with one or more substituents independently selected from the group consisting of halogen, CH 2 -cyclopropyl, and cyclopropyl;
R 3a represents H, halogen, CN, NO 2 , a C 1 -C 6 hydrocarbon chain, C(NOR 17 )R 30 , C(O)R 13 , C(O)NR 31 R 32 , C(O)NR 11 S(O) 2 R 23 , C(O)OR 17 , NR 11 R 12 , NR 11a R 12a , NR 11 C(O)R 13 , NR 11 C(O)NR 31 R 32 , NR 11 C(O)OR 14 , N═CHNR 31 R 32 , NR 24 NR 11 R 12 , NR 24 NR 11 C(O)R 13 , NR 24 NR 11 C(O)NR 31 R 32 , NR 24 NR 11 C(O)OR 14 , NR 24 OR 11 , N═S(O) p R 15 R 16 , OR 12 , C 3 -C 7 cycloalkyl, phenyl, or 5- or 6-membered heteroaryl, wherein the C 1 -C 6 hydrocarbon chain is optionally substituted with one or more independently selected Group B substituents, and further wherein the C 3 -C 7 cycloalkyl is optionally substituted with one or more independently selected Group E substituents, and the phenyl or 5- or 6-membered heteroaryl is optionally substituted with one or more independently selected Group H substituents;
R 3b represents H, halogen, CN, NO 2 , a C 1 -C 6 hydrocarbon chain, C(NOR 17 )R 30 , C(O)R 13 , C(O)NR 31 R 32 , C(O)NR 11 S(O) 2 R 23 , C(O)OR 17 , NR 11 R 12 , NR 11a R 12a , NR 11 C(O)R 13 , NR 11 C(O)NR 31 R 32 , NR 11 C(O)OR 14 , N═CHNR 31 R 32 , NR 24 NR 11 R 12 , NR 24 NR 11 C(O)R 13 , NR 24 NR 11 C(O)NR 31 R 32 , NR 24 NR 11 C(O)OR 14 , NR 24 OR 11 , N═S(O) p R 15 R 16 , OR 12 , C 3 -C 7 cycloalkyl, phenyl, or 5- or 6-membered heteroaryl, wherein the C 1 -C 6 hydrocarbon chain is optionally substituted with one or more independently selected Group B substituents, and further wherein the C 3 -C 7 cycloalkyl is optionally substituted with one or more independently selected Group E substituents, and the phenyl or 5- or 6-membered heteroaryl is optionally substituted with one or more independently selected Group H substituents;
R 3c represents H, halogen, CN, NO 2 , a C 1 -C 6 hydrocarbon chain, C(NOR 17 )R 30 , C(O)R 13 , C(O)NR 31 R 32 , C(O)NR 11 S(O) 2 R 23 , C(O)OR 17 , NR 11 R 12 , NR 11a R 12a , NR 11 C(O)R 13 , NR 11 C(O)NR 31 R 32 , NR 11 C(O)OR 14 , N═CHNR 31 R 32 , NR 24 NR 11 R 12 , NR 24 NR 11 C(O)R 13 , NR 24 NR 11 C(O)NR 31 R 32 , NR 24 NR 11 C(O)OR 14 , NR 24 OR 11 , N═S(O) p R 15 R 16 , OR 12 , C 3 -C 7 cycloalkyl, phenyl, or 5- or 6-membered heteroaryl, wherein the C 1 -C 6 hydrocarbon chain is optionally substituted with one or more independently selected Group B substituents, and further wherein the C 3 -C 7 cycloalkyl is optionally substituted with one or more independently selected Group E substituents, and the phenyl or 5- or 6-membered heteroaryl is optionally substituted with one or more independently selected Group H substituents;
R 3d represents H, halogen, CN, NO 2 , a C 1 -C 6 hydrocarbon chain, C(NOR 17 )R 30 , C(O)R 13 , C(O)NR 31 R 32 , C(O)NR 11 S(O) 2 R 23 , C(O)OR 17 , NR 11 R 12 , NR 11a R 12a , NR 11 C(O)R 13 , NR 11 C(O)NR 31 R 32 , NR 11 C(O)OR 14 , N═CHNR 31 R 32 , NR 24 R 11 R 12 , NR 24 NR 11 C(O)R 13 , NR 24 NR 11 C(O)NR 13 R 32 , NR 24 NR 11 C(O)OR 14 , NR 24 OR 11 , N═S(O) p R 15 R 16 , OR 12 , C 3 -C 7 cycloalkyl, phenyl, or 5- or 6-membered heteroaryl, wherein the C 1 -C 6 hydrocarbon chain is optionally substituted with one or more independently selected Group B substituents, and further wherein the C 3 -C 7 cycloalkyl is optionally substituted with one or more independently selected Group E substituents, and the phenyl or 5- or 6-membered heteroaryl is optionally substituted with one or more independently selected Group H substituents;
each R 11 independently represents H or a C 1 -C 6 hydrocarbon chain, wherein each C 1 -C 6 hydrocarbon chain is optionally and independently substituted with one or more independently selected halogen substituents;
each R 12 independently represents H, a C 1 -C 6 hydrocarbon chain, S(O) 2 R 23 , C 3 -C 7 cycloalkyl, C 3 -C 7 cycloalkenyl, phenyl, or 6-membered heteroaryl, wherein each C 1 -C 6 hydrocarbon chain is optionally and independently substituted with one or more independently selected Group F substituents, and further wherein each C 3 -C 7 cycloalkyl and C 3 -C 7 cycloalkenyl is optionally and independently substituted with one or more independently selected Group J substituents, and each phenyl and 6-membered heteroaryl is optionally and independently substituted with one or more independently selected Group D substituents;
each R 11a and R 12a taken together with the N atom to which they are attached, independently represents a non-aromatic 3- to 7-membered heterocyclyl, wherein each non-aromatic 3- to 7-membered heterocyclyl is optionally and independently substituted with one or more independently selected Group E substituents;
each R 13 independently represents H, a C 1 -C 6 hydrocarbon chain, C 1 -C 3 alkylene-C 3 -C 6 cycloalkyl, C 3 -C 7 cycloalkyl, phenyl, or 5- or 6-membered heteroaryl, wherein each C 1 -C 6 hydrocarbon chain, C 1 -C 3 alkylene-C 3 -C 6 cycloalkyl, and C 3 -C 7 cycloalkyl is optionally and independently substituted with one or more independently selected halogen substituents, and further wherein each phenyl and 5- or 6-membered heteroaryl is optionally and independently substituted with one or more independently selected Group D substituents;
each R 14 independently represents a C 1 -C 6 hydrocarbon chain, C 1 -C 3 alkylene-C 3 -C 6 cycloalkyl, C 1 -C 3 alkylene-phenyl, or C 3 -C 7 cycloalkyl, wherein each C 1 -C 6 hydrocarbon chain, C 1 -C 3 alkylene-C 3 -C 6 cycloalkyl, and C 3 -C 7 cycloalkyl is optionally and independently substituted with one or more independently selected halogen substituents, and further wherein each phenyl of each C 1 -C 3 alkylene-phenyl is optionally and independently substituted with one or more independently selected Group D substituents;
each R 15 independently represents C 1 -C 6 alkyl, wherein each C 1 -C 6 alkyl is optionally and independently substituted with one or more independently selected halogen substituents;
each R 16 independently represents C 1 -C 6 alkyl, wherein each C 1 -C 6 alkyl is optionally and independently substituted with one or more independently selected halogen substituents;
each R 17 independently represents H, a C 1 -C 6 hydrocarbon chain, or phenyl, wherein each C 1 -C 6 hydrocarbon chain is optionally and independently substituted with one or more independently selected halogen substituents, and further wherein each phenyl is optionally and independently substituted with one or more independently selected Group D substituents;
each R 23 independently represents a C 1 -C 6 hydrocarbon chain or phenyl, wherein each C 1 -C 6 hydrocarbon chain is optionally and independently substituted with one or more independently selected halogen substituents, and wherein each phenyl is optionally and independently substituted with one or more independently selected Group D substituents;
each R 24 independently represents H or a C 1 -C 6 hydrocarbon chain, wherein each C 1 -C 6 hydrocarbon chain is optionally and independently substituted w

Assignees

• Sumitomo Chemical Co

Inventors

• Orimoto Kohei
• Nakajima Yuji
• Kono Risa
• Maehata Ryota
• Tashiro Masayuki

Classifications

• A01N25/12

  Powders or granules (A01N25/26 takes precedence) · CPC title

• A01N25/04

  Dispersions, {emulsions, suspoemulsions, suspension concentrates} or gels (foams A01N25/16) · CPC title

• A01N43/90 Primary

  having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system · CPC title

• C07D487/04 Primary

  Ortho-condensed systems · CPC title

• C07D471/04 Primary

  Ortho-condensed systems · CPC title