Method for improving life properties and charging speed of lithium-sulfur secondary battery

Patent metadata

Field	Value
Publication number	US-11489209-B2
Application number	US-201816636538-A
Country	US
Kind code	B2
Filing date	Aug 10, 2018
Priority date	Sep 1, 2017
Publication date	Nov 1, 2022
Grant date	Nov 1, 2022

Abstract

A method for improving a lifetime property and a charging rate of a lithium-sulfur secondary battery capable of both improving a lifetime property and a charging rate of the secondary battery by inducing a homogeneous reaction of the lithium-sulfur secondary battery by applying a charging rate differently for each section in a charging process of the lithium-sulfur secondary battery.

First claim

The invention claimed is:

1. A method for charging a lithium-sulfur secondary battery, the method comprising:
charging the lithium-sulfur secondary battery in a plurality of consecutive sections including:
a first section at 0.1 C, a second section at 0.2 C and a third section at 0.1 C, with 0.2 C representing a high rate charging section and 0.1 C representing a low rate charging section,
wherein the first section, the second section and the third section represent an entire charging profile of the lithium-sulfur secondary battery.

2. The method of claim 1 , wherein the high rate charge is achieved to 70% to 80% of a maximum battery capacity.

3. The method of claim 2 , wherein the high rate charging is performed for 180 minutes to 280 minutes.

4. The method of claim 1 , wherein the secondary battery includes an electrolyte liquid including a lithium salt (1.0 M lithium bis(trifluoromethane sulfonyl)imide (LiTFSI)+1 wt % LiNO3) and a solvent (1,3-dioxolane (DOL)/methoxymethane (DME) in a volume ratio of 1:1).

5. The method of claim 4 , wherein the high rate charge is achieved to 70% to 80% of a maximum battery capacity,
wherein the high rate charging is performed for 180 minutes to 280 minutes, and
wherein, in the charging process, sulfur is converted to lithium polysulfide by a reduction reaction, and the lithium polysulfide is completely reduced to produce lithium sulfur, where the lithium polysulfide is suppressed in the high rate charging section and an equalization reaction occurs in the low rate charging section(s).

6. The method of claim 1 , wherein a first charging rate for the low rate charging section and a second charging rate for the high rate charging section are selected such that in the charging process, sulfur is converted to lithium polysulfide by a reduction reaction, and the lithium polysulfide is completely reduced to produce lithium sulfur, where the lithium polysulfide is suppressed in the high rate section and an equalization reaction occurs in the low rate section(s).

7. The method of claim 6 , wherein the secondary battery includes an electrolyte liquid including a lithium salt (1.0 M lithium bis(trifluoromethane sulfonyl)imide (LiTFSI)+1 wt % LiNO3) and a solvent (1,3-dioxolane (DOL)/methoxymethane (DME) in a volume ratio of 1:1).

8. The method of claim 7 , wherein the high rate charge is achieved to 70% to 80% of a maximum battery capacity,
wherein the high rate charging is performed for 180 minutes to 280 minutes, and
wherein, in the charging process, sulfur is converted to lithium polysulfide by a reduction reaction, and the lithium polysulfide is completely reduced to produce lithium sulfur, where the lithium polysulfide is suppressed in the high rate charging section and an equalization reaction occurs in the low rate charging section(s).

Assignees

• Lg Chemical Ltd
• Lg Energy Solution Ltd

Inventors

• Park Intae
• Yang Doo Kyung

Classifications

• H02J7/94

  in response to battery current · CPC title

• H01M10/052 Primary

  Li-accumulators · CPC title

• H01M10/44 Primary

  Methods for charging or discharging (circuits for charging H02J7/00) · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H02J7/00714

  Electricity · mapped topic