Polymer blends for use in multilayer structure and multilayer structures comprising the same

Patent metadata

Field	Value
Publication number	US-11485840-B2
Application number	US-201716470695-A
Country	US
Kind code	B2
Filing date	Jan 11, 2017
Priority date	Jan 11, 2017
Publication date	Nov 1, 2022
Grant date	Nov 1, 2022

Abstract

The present invention provides polymer blends that can be used in a multilayer structure and to multilayer structures comprising one or more layers formed from such blends. In one aspect, a polymer blend comprises (a) a copolymer comprising ethylene and at least one of acrylic acid and methacrylic acid having an acid content of 2 to 21 weight percent based on the weight of the copolymer, wherein the amount of copolymer (a) comprises 20-80 weight percent of the blend based on the total weight of the blend, and (b) a copolymer comprising ethylene and at least one of methyl acrylate and ethyl acrylate having an acrylate content of 5 to 30 weight percent based on the weight of the copolymer, wherein the amount of copolymer (b) comprises 10 to 50 weight percent of the blend based on the total weight of the blend, wherein the amount of copolymer (a) and copolymer (b) is at least 70 weight percent of the blend based on the total weight of the blend.

First claim

The invention claimed is:

1. A polymer blend comprising:
(a) a copolymer consisting of ethylene and at least one of acrylic acid and methacrylic acid having an acid content of 2 to 21 weight percent based on the weight of the copolymer, wherein the amount of copolymer (a) comprises 20-80 weight percent of the blend based on the total weight of the blend; and
(b) a copolymer consisting of ethylene and at least one of methyl acrylate and ethyl acrylate having an acrylate content of 5 to 30 weight percent based on the weight of the copolymer, wherein the amount of copolymer (b) comprises 10 to 50 weight percent of the blend based on the total weight of the blend,

wherein the amount of copolymer (a) and copolymer (b) is at least 70 weight percent of the blend based on the total weight of the blend.

2. The polymer blend of claim 1 , wherein the melt index (I 2 ) ratio of copolymer (a) to copolymer (b) (I 2 of copolymer (a)/I 2 of copolymer (b)) is greater than 2.

3. A polymer blend comprising:
(a) a copolymer consisting of ethylene and at least one of acrylic acid and methacrylic acid having an acid content 2 to 21 weight percent based on the weight of the copolymer and having a melt index (I 2 ) of 1 to 40 g/10 minutes, wherein the amount of copolymer (a) comprises 1 to 90 weight percent of the blend based on the total weight of the blend; and
(b) a copolymer consisting of ethylene and at least one of methyl acrylate and ethyl acrylate having an acrylate content 5 to 30 weight percent based on the weight of the copolymer and having a melt index (I 2 ) of 0.5 to 20 g/10 minutes, wherein the amount of copolymer (b) comprises 1 to 50 weight percent of the blend based on the total weight of the blend,

wherein the melt index ratio of copolymer (a) to copolymer (b) (I 2 of copolymer (a)/I 2 of copolymer (b)) is greater than 2.

4. The polymer blend of claim 1 further comprising a polyolefin having a density of 0.930 g/cm 3 or less.

5. The polymer blend of claim 4 , wherein the blend comprises 30 weight percent or less of the polyolefin based on the total weight of the blend.

6. The polymer blend of claim 1 , wherein the blend comprises 50 to 70 weight percent of copolymer (a), 30 to 50 weight percent of copolymer (b), and 0 to 20 weight percent of the polyolefin, based on the total weight of the blend.

7. A multilayer structure comprising at least two layers, each layer having opposing facial surfaces, wherein:
Layer A comprises the polymer blend of claim 1 ; and
Layer B comprises a substrate, wherein a top facial surface of Layer B is in adhering contact with a bottom facial surface of Layer A.

8. The multilayer structure of claim 7 , wherein the substrate comprises a metal foil, a metallized film, a woven mat, a nonwoven mat, or a scrim.

9. The multilayer structure of claim 8 , wherein the substrate comprises aluminum foil.

10. The multilayer structure of claim 7 , further comprising Layer C, wherein a top facial surface of Layer A is in adhering contact with a bottom facial surface of Layer C.

11. The multilayer structure of claim 10 , wherein Layer C comprises a polyolefin, a polyamide, a metal foil, or a metallized film.

12. The multilayer structure of claim 7 , wherein the adhesion of Layer A to Layer B is at least 30 N/15 mm when measured according to ASTM D3330.

13. A multilayer structure comprising at least two layers, each layer having opposing facial surfaces, wherein:
Layer A comprises the polymer blend of claim 3 ; and
Layer B comprises a substrate, wherein a top facial surface of Layer B is in adhering contact with a bottom facial surface of Layer A.

14. The multilayer structure of claim 13 , wherein the substrate comprises a metal foil, a metallized film, a woven mat, a nonwoven mat, or a scrim.

15. The multilayer structure of claim 13 , wherein the substrate comprises aluminum foil.

16. The multilayer structure of claim 13 , further comprising Layer C, wherein a top facial surface of Layer A is in adhering contact with a bottom facial surface of Layer C.

17. The multilayer structure of claim 13 , wherein Layer C comprises a polyolefin, a polyamide, a metal foil, or a metallized film.

18. The multilayer structure of claim 13 , wherein the adhesion of Layer A to Layer B is at least 30 N/15 mm when measured according to ASTM D3330.

Assignees

• Dow Global Technologies Llc

Inventors

• Liu Andong
• Liao Guihong
• Pan Jianping
• Gao Peng
• Chen Hongyu
• Zhang Yi

Classifications

• C08L2207/066

  LDPE (radical process) · CPC title

• B32B2439/00

  Containers; Receptacles · CPC title

• B32B15/09

  comprising polyesters · CPC title

• B32B5/024

  Woven fabric · CPC title

• B32B15/06

  of {natural rubber or synthetic} rubber · CPC title