Start-up process for the production of glycols

Patent metadata

Field	Value
Publication number	US-11485693-B2
Application number	US-201917275570-A
Country	US
Kind code	B2
Filing date	Sep 10, 2019
Priority date	Sep 13, 2018
Publication date	Nov 1, 2022
Grant date	Nov 1, 2022

Abstract

The invention provides a start-up method for a process for the preparation of glycols from a starting material comprising one or more saccharides in the presence of hydrogen and a catalyst system comprising one or more retro-aldol catalysts comprising tungsten and one or more catalytic species suitable for hydrogenation in a reactor, said method comprising introducing the one or more retro-aldol catalysts to the reactor whilst also in the presence of one or more agents suitable to suppress tungsten precipitation.

First claim

What is claimed is:

1. A start-up method for a process for the preparation of glycols from a starting material comprising one or more saccharides in the presence of hydrogen and a catalyst system comprising one or more retro-aldol catalysts comprising tungsten and one or more catalytic species suitable for hydrogenation in a reactor, said method comprising the steps of:
a) activating a hydrogenation catalyst composition in the reactor;
b) introducing an agent suitable for suppressing tungsten precipitation to the activated hydrogenation catalyst composition in the reactor;
c) introducing a retro-aldol catalyst to the reactor containing the activated hydrogenation catalyst and the agent, wherein the one or more retro-aldol catalysts comprise at least one of silver tungstate, sodium metatungstate, ammonium metatungstate, sodium polytungstate, tungstic acid, alkali and alkaline earth metal tungstates, alkali and alkaline earth phosphotungstates, phosphotungstic acid, mixed tungstates and molybdates, and silicotungstic acid; and
d) introducing the starting material to the reactor for preparing a glycol, wherein tungsten precipitation is suppressed during reaction of the starting material.

2. The method according to claim 1 , wherein the agent comprises at least one of organic oxygenates or buffer systems comprising one or more organic acids, their corresponding conjugated bases with alkali-metal as their counterions, and mixtures thereof.

3. The method according to claim 2 , wherein the agent comprises at least one of organic oxygenate solvents, the starting material, glycols, sugar alcohols, carboxylic acids, other products formed during the process, and mixtures thereof.

4. The method according to claim 2 , wherein the buffer systems comprise at least one of acetate buffers, phosphate buffers, lactate buffers, glycolate buffers, citrate buffers or buffers of other organic acids.

5. The method according to claim 1 , wherein when the agent is selected from the group consisting of sorbitol, lactic acid, glycolic acid, and combinations thereof.

6. The method according claim 1 , further comprising raising the reactor temperature to reaction temperature after introducing the retro-aldol catalyst.

7. A startup process for the preparation of monoethylene glycol from a starting material comprising one or more saccharides in the presence of hydrogen and a catalyst system comprising one or more tungsten based retro-aldol catalysts in a reactor comprising one or more catalytic species suitable for hydrogenation, said process comprising:
a. activating a hydrogenation catalyst composition in the reactor;
b. introducing an agent suitable for suppressing catalyst deposition to the activated hydrogenation catalyst in the reactor;
c. introducing a retro-aldol catalyst to the reactor containing the activated hydrogenation catalyst and the agent; and
d. introducing the starting material to the reactor for preparing monoethylene glycol, wherein catalyst deposition is suppressed during reaction of the starting material.

8. The process according to claim 7 , wherein the agent is a portion of the starting material.

9. The process according to claim 7 , wherein the reactor temperature is less than 160° C. prior to the introducing the retro-aldol catalyst to the reactor.

10. The process according to claim 7 , wherein the agent comprises at least one of organic oxygenate solvents, glycols, sugar alcohols, or buffer systems comprising one or more organic acids, their corresponding conjugated bases with alkali-metal as their counterions, and mixtures thereof.

11. The process according to claim 10 , wherein the reactor temperature is at reaction temperature.

12. The process according to claim 7 , further comprising activating the one or more catalytic species suitable for hydrogenation prior to introducing the one or more agents.

13. The method according to claim 1 , wherein the reactor temperature in step b) is less than 160° C.

14. The process according to claim 7 , wherein the agent is selected from the group consisting of sorbitol, lactic acid, glycolic acid, and combinations thereof.

Assignees

• Shell Oil Co
• Shell Usa Inc

Inventors

• De Vlieger Dionysius Jacobus Maria
• Huizenga Pieter
• Mackay Munro
• Keyzer Lucas Petrus Simon
• Muthusamy Duraisamy

Classifications

• B01J21/18

  Carbon · CPC title

• B01J23/462

  Ruthenium · CPC title

• C07C29/132 Primary

  by reduction of an oxygen containing functional group · CPC title

• B01J23/30

  Tungsten · CPC title