Composite and power transmission belt

Patent metadata

Field	Value
Publication number	US-11485095-B2
Application number	US-201816651186-A
Country	US
Kind code	B2
Filing date	Sep 21, 2018
Priority date	Sep 29, 2017
Publication date	Nov 1, 2022
Grant date	Nov 1, 2022

Abstract

A composite comprises: a reinforcing element ( 10 ), an adhesive layer ( 14 ) made from an adhesive composition, and an elastomeric body made from an elastomeric matrix comprising an ethylene/alpha-olefin type elastomer and/or a polychloroprene elastomer. The adhesive composition comprises a resin based: on a polyphenol comprising an aromatic ring bearing two hydroxyl functions in the meta position relative to one another, the two positions ortho to one of the hydroxyl functions being unsubstituted; and/or on a monophenol comprising a six-membered aromatic ring bearing a single hydroxyl function, the two ortho positions being unsubstituted, or an ortho position and the para position being unsubstituted, and on a compound comprising an aromatic ring bearing two functions, one of these functions being a hydroxymethyl function and the other being an aldehyde function or a hydroxymethyl function.

First claim

The invention claimed is:

1. A process for manufacturing a composite, the process comprising:
arranging, in an uncured state, a stack comprising, in this order:
a first elastomeric layer made from a first elastomeric material;
at least one reinforcing element coated with an adhesive layer made from an adhesive composition, the adhesive composition comprising at least one resin based
on at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functions in the meta position relative to one another, the two positions ortho to at least one of the hydroxyl functions being unsubstituted, and/or
on at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl function,
the two positions ortho to the single hydroxyl function being unsubstituted, or
at least one position ortho to and the position para to the single hydroxyl function being unsubstituted, and

on at least one aromatic compound comprising at least one aromatic ring bearing at least two functions, one function being a hydroxymethyl function and another function being an aldehyde function or a hydroxymethyl function; and

a second elastomeric layer made from a second elastomeric material, at least one of the first and second elastomeric materials comprising at least one elastomer selected from the group consisting of an ethylene/alpha-olefin elastomer, a polychloroprene elastomer (CR) and mixtures thereof; and

moulding and crosslinking the stack.

2. A process for manufacturing a power transmission belt, the process comprising:
arranging, in an uncured state, a stack comprising, in this order:
a first elastomeric layer made from a first elastomeric material;
at least one reinforcing element coated with an adhesive layer made from an adhesive composition, the adhesive composition comprising at least one resin based
on at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functions in the meta position relative to one another, the two positions ortho to at least one of the hydroxyl functions being unsubstituted, and/or
on at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl function,
the two positions ortho to the single hydroxyl function being unsubstituted, or
at least one position ortho to and the position para to the single hydroxyl function being unsubstituted, and

on at least one aromatic compound comprising at least another aromatic ring bearing at least two functions, one function being a hydroxymethyl function and one function being an aldehyde function or a hydroxymethyl function;

a second elastomeric layer made from a second elastomeric material, at least one of the first and second elastomeric materials comprising at least one elastomer selected from the group consisting of an ethylene/alpha-olefin elastomer, a polychloroprene elastomer (CR) and mixtures thereof; and
a third elastomeric mechanical drive layer arranged in contact with the second elastomeric layer and made from a third elastomeric material; and

moulding and crosslinking the stack.

3. A composite comprising:
at least one reinforcing element;
an adhesive layer made from an adhesive composition and coating the at least one reinforcing element;
an elastomeric body made from an elastomeric matrix comprising at least one elastomer selected from the group consisting of an ethylene/alpha-olefin elastomer, a polychloroprene elastomer and mixtures thereof, the at least one reinforcing element coated with the adhesive layer being embedded in the elastomeric body,
wherein the adhesive composition comprises at least one resin based:
on at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functions in the meta position relative to one another, the two positions ortho to at least one of the hydroxyl functions being unsubstituted, and/or
on at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl function,
the two positions ortho to the single hydroxyl function being unsubstituted, or
at least one position ortho to and the position para to the single hydroxyl function being unsubstituted, and

on at least one aromatic compound comprising at least one aromatic ring bearing at least two functions, one function being a hydroxymethyl function and another function being an aldehyde function or a hydroxymethyl function.

4. The composite according to claim 3 , wherein the at least one aromatic polyphenol is selected from the group consisting of resorcinol, phloroglucinol, 2,2′,4,4′-tetrahydroxydiphenyl sulfide, 2,2′,4,4′-tetrahydroxybenzophenone, resins pre-condensed from at least one of these aromatic polyphenols and mixtures thereof.

5. The composite according to claim 3 , wherein the at least one aromatic compound corresponds to general formula (VII′a1) or (VII′2a):

6. The composite according to claim 3 , wherein the ethylene/alpha-olefin elastomer is selected from the group consisting of ethylene-propylene copolymers (EPM), ethylene-propylene-diene copolymers (EPDM), and mixtures thereof.

7. The composite according to claim 3 , wherein the adhesive composition comprises at least one unsaturated elastomer latex.

8. The composite according to claim 7 , wherein the at least one unsaturated elastomer latex is a diene elastomer selected from the group consisting of polybutadienes, butadiene copolymers, polyisoprenes, isoprene copolymers, vinylpyridine-styrene-butadiene terpolymers, ethylene/alpha-olefin elastomers, polychloroprene elastomers (CR) and mixtures thereof.

9. The composite according to claim 8 , wherein the ethylene/alpha-olefin type elastomer of the at least one unsaturated elastomer latex is selected from the group consisting of ethylene-propylene copolymers (EPM), ethylene-propylene-diene copolymers (EPDM), and mixtures thereof.

10. The composite according to claim 3 , wherein the at least one reinforcing element is nonmetallic.

11. The composite according to claim 3 , wherein the elastomeric body directly coats the adhesive layer.

12. The composite according to claim 3 further comprising an elastomeric bonding layer made from an elastomeric bonding composition and directly coating the adhesive layer, the elastomeric bonding composition comprising at least one elastomer selected from the group consisting of an ethylene/alpha-olefin elastomer, a polychloroprene elastomer (CR) and mixtures thereof.

13. The composite according to claim 12 , wherein the ethylene/alpha-olefin elastomer of the elastomeric bonding layer is selected from the group consisting of ethylene-propylene copolymers (EPM), ethylene-propylene-diene copolymers (EPDM) and mixtures thereof.

14. The composite according to claim 12 , wherein the at least one elastomer of the elastomeric bonding composition is identical to the at least one elastomer of the elastomer matrix.

15. The composite according to claim 3 , the composite forming a power transmission belt.

Assignees

• Michelin & Cie

Inventors

• Doisneau David

Classifications

• B29K2023/16

  EPM, i.e. ethylene-propylene copolymers; EPDM, i.e. ethylene-propylene-diene copolymers; EPT, i.e. ethylene-propylene terpolymers · CPC title

• B29L2031/7094

  Driving belts · CPC title

• C09J171/10

  from phenols · CPC title

• F16G5/08

  with textile reinforcement · CPC title

• F16G1/10

  with textile reinforcement · CPC title