Positive electrode active material, preparation method thereof, positive electrode including same and secondary battery

Patent metadata

Field	Value
Publication number	US-11482702-B2
Application number	US-201916638321-A
Country	US
Kind code	B2
Filing date	Feb 26, 2019
Priority date	Mar 9, 2018
Publication date	Oct 25, 2022
Grant date	Oct 25, 2022

Abstract

A method for preparing a positive electrode active material and a positive electrode active material prepared by the method are provided. The method includes preparing a lithium composite transition metal oxide represented by Formula 1, and washing the lithium composite transition metal oxide with a cleaning liquid containing cleaning water and a surfactant. The cleaning liquid contains cleaning water in an amount of no less than 50 parts by weight and less than 400 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.

First claim

The invention claimed is:

1. A method for preparing a positive electrode active material comprising:
preparing a lithium composite transition metal oxide represented by Formula 1 below; and
washing the lithium composite transition metal oxide with a cleaning liquid comprising cleaning water and a surfactant,
Li a [Ni b Co c M 1 d M 2 e ]O 2   [Formula 1]

(wherein, M 1 is one or more selected from the group consisting of Mn and Al, M 2 is one or more selected from the group consisting of Zr, B, W, Mg, Ce, Hf, Ta, Ti, Sr, Ba, F, P, S, and La, and 0.9≤a≤1.1, 0.6≤b<1, 0<c≤0.3, 0<d≤0.3, 0≤e≤0.1; and
wherein the cleaning liquid contains the cleaning water in an amount of no less than 50 parts by weight and less than 400 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.

2. The method of claim 1 , wherein the cleaning liquid contains the surfactant in an amount of 0.01-10 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.

3. The method of claim 1 , wherein the surfactant is one or more selected from the group consisting of an anionic surfactant, a cationic surfactant, and an amphoteric surfactant.

4. The method of claim 1 , wherein the washing is performed for 5-30 minutes.

5. The method of claim 1 , further comprising forming a coating layer on a surface of the lithium composite transition metal oxide after the washing.

6. The method of claim 5 , wherein the forming of a coating layer comprises mixing the lithium composite transition metal oxide and a coating raw material and then performing heat treatment.

7. A positive electrode active material comprising a lithium composite transition metal oxide represented by Formula 1 below, wherein
the lithium composite transition metal oxide has a powder electrical conductivity of 0.0216 S/cm to 0.05 S/cm, where the powder electrical conductivity is measured after pressing the lithium composite transition metal oxide with a force of 20 kN:
Li a [Ni b Co c M 1 d M 2 e ]O 2   [Formula 1]

wherein, M 1 is one or more selected from the group consisting of Mn and Al, M 2 is one or more selected from the group consisting of Zr, B, W, Mg, Ce, Hf, Ta, Ti, Sr, Ba, F, P, S, and La, and 0.9≤a≤1.1, 0.6≤b<1, 0<c≤0.3, 0<d≤0.3, 0≤e≤0.1.

8. The positive electrode active material of claim 7 , wherein the powder electrical conductivity is 0.02S/cm or less when measured after pressing the lithium composite transition metal oxide with a force of 4 kN.

9. The positive electrode active material of claim 7 , wherein the positive electrode active material contains 0.6 wt % or less of lithium by-products.

10. The positive electrode active material of claim 7 , wherein the positive electrode active material comprises a coating layer including one or more elements selected from the group consisting of Al, Ti, W, B, F, P, Mg, Ni, Co, Fe, Cr, V, Cu, Ca, Zn, Zr, Nb, Mo, Sr, Sb, Bi, Si, and S.

11. A positive electrode comprising the positive electrode active material of claim 7 .

12. A secondary battery comprising the positive electrode of claim 11 , a negative electrode positioned opposite to the positive electrode, a separator interposed between the positive electrode and the negative electrode, and an electrolyte.

13. The positive electrode active material of claim 7 , wherein the positive electrode active material contains 0.1 to 0.6 wt % of lithium by-products.

14. The positive electrode active material of claim 7 , wherein the lithium composite transition metal oxide represented by Formula 1 has a modified surface, and
wherein the modified surface is obtained by the following method comprising:
washing the lithium composite transition metal oxide represented by Formula 1 with a cleaning liquid comprising cleaning water and a surfactant, wherein the cleaning liquid contains the cleaning water in an amount of no less than 50 parts by weight and less than 400 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.

15. The positive electrode active material of claim 14 , wherein the cleaning liquid contains the surfactant in an amount of 0.01-10 parts by weight based on 100 parts by weight of the lithium composite transition metal oxide.

16. The positive electrode active material of claim 14 , wherein the surfactant is one or more selected from the group consisting of an anionic surfactant, a cationic surfactant, and an amphoteric surfactant.

17. The positive electrode active material of claim 14 , wherein the washing is performed for 5-30 minutes.

18. The positive electrode active material of claim 14 , further comprising a coating layer disposed on the modified surface.

Assignees

• Lg Chemical Ltd

Inventors

• Eom Jun Ho
• Ban Sung Ho
• Baek Hyeon Hui
• Park Na Ri

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C01P2006/80

  Compositional purity · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• H01M4/364

  as mixtures · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title