Matt powder coatings

Patent metadata

Field	Value
Publication number	US-11479690-B2
Application number	US-202117196937-A
Country	US
Kind code	B2
Filing date	Mar 9, 2021
Priority date	Jul 25, 2014
Publication date	Oct 25, 2022
Grant date	Oct 25, 2022

Abstract

A branched carboxylic acid functional polyester resin P is described herein along with thermosetting powder coating compositions (PCC A) comprising a binder K, the binder K comprising the polyester resin P and a crosslinker X. The invention further relates to a cured PCC A. In addition, processes for making said PCC A and processes for coating an article with said PCC A are described as well as articles having coated thereon the PCC A and an articles having coated and cured thereon the PCC A.

First claim

The invention claimed is:

1. A branched carboxylic acid functional polyester resin P, having:
(a) a T g of at least 40° C. as measured by Differential Scanning calorimetry (DSC) at a heating rate of 5° C./min;
(b) an acid value (AV) of at least 65 and of at most 76.8 mg KOH/g of the polyester resin P;
(c) a hydroxyl value of at most 9 mg KOH/g of the polyester resin P; and
(d) a functionality of at least 3.5 and at most 5; wherein
the polyester resin P is a reaction product of at least the following monomers:
i) neopentyl glycol in an amount of at least 19 and at most 38 mol %;
ii) ethylene glycol in an amount of at least 8 and at most 21 mol %;
iii) a polyol in an amount of at least 0 and at most 2 mol %;
iv) isophthalic acid in an amount of at least 0 and at most 2.4 mol %;
v) terephthalic acid in an amount of at least 38 and at most 47 mol %;
vi) adipic acid in an amount of at least 0.01 and at most 10 mol %; and
vii) a polycarboxylic acid, in an amount of at least 6 and at most 10.2 mol %; and wherein
the mol % is based on a total amount of monomers i)-vii) forming the polyester resin P being 100 mol %.

2. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the polyol monomer iii) is present in an amount of at least 0 and at most 1.4 mol %.

3. The branched carboxylic acid functional polyester resin P according to claim 2 , wherein the branched carboxylic acid functional polyester resin P has an AV of at least 68 mg KOH/g of the polyester resin P.

4. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the branched carboxylic acid functional polyester resin P has an AV of at least 68 mg KOH/g of the polyester resin P.

5. The branched carboxylic acid functional polyester resin P according to claim 4 , wherein the neopentyl glycol monomer i) is present in an amount of at most 36.5 mol %.

6. The branched carboxylic acid functional polyester resin P according to claim 5 , wherein the polyol monomer iii) is present in an amount of at least 0 and at most 1.4 mol %.

7. The branched carboxylic acid functional polyester resin P according to claim 6 , wherein the hydroxyl value of the polyester resin P is at most 7 mg KOH/g of the polyester resin P.

8. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the neopentyl glycol monomer i) is present in an amount of at most 36.5 mol %.

9. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the polycarboxylic acid monomer (vii) is present in an amount of at least 6.5 mol %.

10. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the hydroxyl value of the polyester resin P is at most 8 mg KOH/g of the polyester resin P.

11. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the hydroxyl value of the polyester resin P is at most 7 mg KOH/g of the polyester resin P.

12. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the hydroxyl value of the polyester resin P is at most 6 mg KOH/g of the polyester resin P.

13. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the hydroxyl value of the polyester resin P is at most 5 mg KOH/g of the polyester resin P.

14. The branched carboxylic acid functional polyester resin P according to claim 1 , wherein the hydroxyl value of the polyester resin P is at least 0.01 and at most 5 mg KOH/g of the polyester resin P.

15. A thermosetting powder coating composition A (PCC A) comprising a binder K in an amount of at least 20 and at most 100 pph of PCC A, wherein the binder K comprises:
a crosslinker X in an amount of at least 1 and at most 55 pph of the binder K, wherein the crosslinker X is selected from the group consisting of epoxy compounds, compounds having at least two β-hydroxyalkylamide groups (BHA compounds), and mixtures thereof; and
the branched carboxylic acid functional polyester resin P according to claim 1 in an amount of at least 45 and at most 99 pph of the binder K.

16. The thermosetting powder coating composition A (PCC A) according to claim 15 , wherein the crosslinker X is a BHA compound.

17. The thermosetting powder coating composition A (PCC A) according to claim 16 , wherein the amount of the crosslinker X is at least 2 and at most 20 pph of the binder K and wherein the branched carboxylic acid functional polyester resin P is present in an amount of at least 80 and at most 98 pph of the binder K.

18. A cured thermosetting powder coating composition which is obtained upon curing the thermosetting powder coating composition A (PCC A) as defined in claim 17 .

19. The thermosetting powder coating composition A (PCC A) according to claim 16 , wherein
the amount of the crosslinker X is at least 2 and at most 20 pph of the binder K, and wherein
the branched carboxylic acid functional polyester resin P is present in an amount of at least 80 and at most 98 pph of the binder K and has an AV of at least 68 mg KOH/g of the polyester resin P, and wherein
the neopentyl glycol monomer i) of the branched carboxylic acid functional polyester resin P is present in an amount of at most 36.5 mol %; and
the polyol monomer iii) of the branched carboxylic acid functional polyester resin P is present in an amount of at least 0 and at most 1.4 mol %.

20. The thermosetting powder coating composition A (PCC A) according to claim 16 , wherein
the amount of the crosslinker X is at least 2 and at most 20 pph of the binder K, and wherein
the branched carboxylic acid functional polyester resin P is present in an amount of at least 80 and at most 98 pph of the binder K, has an AV of at least 68 mg KOH/g of the polyester resin P and a hydroxyl value which is at most 7 mg KOH/g of the polyester resin P; and wherein
the neopentyl glycol monomer i) of the branched carboxylic acid functional polyester resin P is present in an amount of at most 36.5 mol %; and
the polyol monomer iii) of the branched carboxylic acid functional polyester resin P is present in an amount of at least 0 and at most 1.4 mol %.

Assignees

• Covestro Netherlands Bv

Inventors

• Bos Matthias Johannes Cornelis
• Buijsen Paulus Franciscus Anna
• Hettinga Johannes Albertus

Classifications

• C08K5/0025

  Crosslinking or vulcanising agents; including accelerators · CPC title

• C08G63/127

  Acids containing aromatic rings · CPC title

• B05D2508/00

  Polyesters · CPC title

• C08J2367/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• C08G63/16

  Dicarboxylic acids and dihydroxy compounds · CPC title