Method for producing lanthanum hexaboride-containing composite particles and method for producing formed product

Patent metadata

Field	Value
Publication number	US-11479673-B2
Application number	US-201916572975-A
Country	US
Kind code	B2
Filing date	Sep 17, 2019
Priority date	May 1, 2017
Publication date	Oct 25, 2022
Grant date	Oct 25, 2022

Abstract

To provide a method for producing lanthanum hexaboride-containing composite particles which are capable of forming a formed product having sufficiently high transparency and which are excellent in weather resistance, by a simple operation without calcination treatment at high temperature, and a method for producing a formed product using it. Also provided is a method for producing composite particles, which involves: reacting at least one silica precursor selected from a tetraalkoxysilane, its hydrolysate and its condensate, in the presence of lanthanum hexaboride particles, a volatile base, water and an organic solvent to obtain a first reaction mixture, and reacting the first reaction mixture with at least one silicon compound selected from an amino-modified silicone, an alkylsilane and an aminosilane, or the silicon compound and the silica precursor added, to obtain a second reaction mixture containing lanthanum hexaboride-containing composite particles.

First claim

What is claimed is:

1. A method for producing lanthanum hexaboride-containing composite particles, which comprises:
reacting at least one silica precursor selected from the group consisting of a tetraalkoxysilane, its hydrolysate and its condensate, in the presence of lanthanum hexaboride particles, a base having a boiling point of at most 200° C., water and an organic solvent to obtain a first reaction mixture, and
reacting the first reaction mixture with at least one silicon compound selected from the group consisting of an amino-modified silicone, an alkylsilane and an aminosilane, or with the at least one silicon compound and the at least one silica precursor, to obtain a second reaction mixture containing lanthanum hexaboride-containing composite particles.

2. The production method according to claim 1 , wherein after the second reaction mixture is obtained, the second reaction mixture is dried to recover the lanthanum hexaboride-containing composite particles.

3. The production method according to claim 2 , wherein the second reaction mixture is a dispersion having the lanthanum hexaboride-containing composite particles dispersed in an organic solvent, and the second reaction mixture is subjected to centrifugal separation, a supernatant is removed and a sediment is recovered, and the sediment is dried.

4. The production method according to claim 1 , wherein the first reaction mixture contains the at least one silica precursor which remains unreacted.

5. The production method according to claim 1 , wherein the reaction of the at least one silica precursor to obtain the first reaction mixture is further carried out in the presence of zirconium oxide particles.

6. The production method according to claim 1 , wherein the tetraalkoxysilane is an alkoxysilane having a C 1-4 alkoxy group.

7. The production method according to claim 1 , wherein the tetraalkoxysilane is tetraethoxysilane.

8. The production method according to claim 1 , wherein the at least one silicon compound is an amino-modified silicone.

9. The production method according to claim 8 , wherein the amino-modified silicone is a side-chain amino-modified silicone, a dual-end amino-modified silicone, a single-end amino-modified silicone or a side-chain dual-end amino-modified silicone.

10. The production method according to claim 8 , wherein the amino-modified silicone is a side-chain amino-modified silicone having an amino group-containing organic group introduced to a part of the side chain of dimethylpolysiloxane.

11. The production method according to claim 1 , wherein the base having a boiling point of at most 200° C. is ammonia or a primary to tertiary alkylamine.

12. The production method according to claim 1 , wherein the base having a boiling point of at most 200° C. is present in an amount such that pH at the time of the reaction to obtain the first reaction mixture is from 8.0 to 12.0.

13. The production method according to claim 1 , wherein the average primary particle size of the lanthanum hexaboride-containing composite particles is from 10 to 1,000 nm.

14. A method for producing a formed product, which comprises producing lanthanum hexaboride-containing composite particles by the production method as defined in claim 1 , mixing the lanthanum hexaboride-containing composite particles and a thermoplastic resin to obtain a thermoplastic resin composition, and forming the thermoplastic resin composition to obtain a formed product.

15. The production method according to claim 14 , wherein the content of the lanthanum hexaboride-containing composite particles is from 0.01 to 1 part by mass per 100 parts by mass of the thermoplastic resin.

16. The production method according to claim 14 , wherein the thermoplastic resin is a fluororesin.

Assignees

• Agc Inc

Inventors

• Katayama Hajime
• Aruga Hiroshi

Classifications

• C01P2006/14

  Pore volume · CPC title

• C01P2006/17

  Pore diameter distribution · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C08G77/04

  Polysiloxanes · CPC title

• C01B35/04

  Metal borides · CPC title