Device and method for CO2 capture through circumscribed hollow membranes

Patent metadata

Field	Value
Publication number	US-11478745-B2
Application number	US-202017010799-A
Country	US
Kind code	B2
Filing date	Sep 2, 2020
Priority date	Sep 3, 2019
Publication date	Oct 25, 2022
Grant date	Oct 25, 2022

Abstract

A device and method for carbon dioxide capture using circumscribed hollow membranes is disclosed. The device includes a hollow membrane unit having an inner conduit composed of a vapor membrane, and an outer conduit having an inside surface circumscribing the inner conduit forming a lumen. The outer conduit includes a CO 2 pump membrane. The device also includes a mechanical pump maintaining a pressure differential between the lumen and the atmosphere, providing a product stream of CO 2 -rich gas from the lumen. The vapor membrane is sufficiently hydrophobic and porous to contain liquid water while also allowing water vapor formed by evaporation to pass through into the lumen. As water vapor passes from the lumen to the atmosphere through the CO 2 pump membrane, a carbon concentration gradient is formed and maintained across the CO 2 pump membrane. The carbon concentration gradient actively pumps CO 2 out of the atmosphere and into the lumen.

First claim

What is claimed is:

1. A device for carbon dioxide capture, comprising:
a hollow membrane unit, comprising:
an inner conduit closed at one end, the inner conduit comprising a vapor membrane;
an outer conduit having an outside surface exposed to an atmosphere and an inside surface circumscribing the inner conduit forming a lumen between the inner conduit and the inside surface of the outer conduit, the outer conduit comprising a CO 2 pump membrane, the lumen comprising a CO 2 -rich gas and a water vapor, the water vapor being substantially saturated; and
a light-absorbing material;

a water supply in fluid communication with the inside of the inner conduit;
a mechanical pump in fluid communication with the lumen, the mechanical pump maintaining a pressure differential of at least one atmosphere between the lumen and the atmosphere and providing a product stream comprising the CO 2 -rich gas; and
a cold trap coupled to the hollow membrane unit and the mechanical pump such that the mechanical pump is in fluid communication with the lumen of the hollow membrane unit through the cold trap;
wherein the vapor membrane contains liquid water provided by the water supply, the vapor membrane being sufficiently hydrophobic and porous to contain the liquid water received while also allowing water vapor to pass through the vapor membrane into the lumen, the water vapor formed by the evaporation of the liquid water;
wherein the CO 2 pump membrane is CO 2 -permeable and wherein, as water vapor passes from the lumen to the atmosphere through the CO 2 pump membrane, a carbon concentration gradient is formed and maintained across the CO 2 pump membrane with a first concentration at the outside surface that is higher than a second concentration at the inside surface, said carbon concentration gradient actively pumping CO 2 out of the atmosphere and into the lumen; and
wherein the liquid water inside the inner conduit is heated by sunlight absorbed by the light-absorbing material to a temperature that is above an ambient temperature, thereby facilitating the evaporation of the liquid water to introduce water vapor into the lumen.

2. The device of claim 1 , wherein the mechanical pump removes CO 2 -rich gas and water vapor from within the lumen at substantially the same rate as CO 2 and water vapor are introduced to the lumen through the water vapor membrane and the CO 2 pump membranes.

3. The device of claim 1 , further comprising a plurality of hollow membrane units coupled to a manifold, the inner conduit of each hollow membrane unit in fluid communication with the water supply, the lumen of each hollow membrane unit in fluid communication with the mechanical pump through the manifold.

4. A device for carbon dioxide capture, comprising:
a hollow membrane unit, comprising:
an inner conduit closed at one end, the inner conduit comprising a vapor membrane; and
an outer conduit having an outside surface exposed to an atmosphere and an inside surface circumscribing the inner conduit forming a lumen between the inner conduit and the inside surface of the outer conduit, the outer conduit comprising a CO 2 pump membrane, the lumen comprising a CO 2 -rich gas and a water vapor;

a water supply in fluid communication with the inside of the inner conduit; and
a mechanical pump in fluid communication with the lumen, the mechanical pump maintaining a pressure differential between the lumen and the atmosphere and providing a product stream comprising the CO 2 -rich gas;
wherein the vapor membrane contains liquid water provided by the water supply, the vapor membrane being sufficiently hydrophobic and porous to contain the liquid water received while also allowing water vapor to pass through the vapor membrane into the lumen, the water vapor formed by the evaporation of the liquid water; and
wherein the CO 2 pump membrane is CO 2 -permeable and wherein, as water vapor passes from the lumen to the atmosphere through the CO 2 pump membrane, a carbon concentration gradient is formed and maintained across the CO 2 pump membrane with a first concentration at the outside surface that is higher than a second concentration at the inside surface, said carbon concentration gradient actively pumping CO 2 out of the atmosphere and into the lumen.

5. The device of claim 4 , further comprising a cold trap coupled to the hollow membrane unit and the mechanical pump such that the mechanical pump is in fluid communication with the lumen of the hollow membrane unit through the cold trap.

6. The device of claim 4 , wherein the liquid water inside the inner conduit is heated to a temperature that is above an ambient temperature, thereby facilitating the evaporation of the liquid water to introduce water vapor into the lumen.

7. The device of claim 6 , wherein the hollow membrane unit comprises a light-absorbing material and wherein the liquid water inside the inner conduit is heated by sunlight absorbed by the light-absorbing material.

8. The device of claim 4 , wherein the mechanical pump removes CO 2 -rich gas and water vapor from within the lumen at substantially the same rate as CO 2 and water vapor are introduced to the lumen through the vapor membrane and the CO 2 pump membranes.

9. The device of claim 4 , wherein the water vapor within the lumen is substantially saturated.

10. The device of claim 4 , further comprising a plurality of hollow membrane units coupled to a manifold, the inner conduit of each hollow membrane unit in fluid communication with the water supply, the lumen of each hollow membrane unit in fluid communication with the mechanical pump through the manifold.

11. A method for carbon dioxide capture, comprising:
filling an inner conduit with liquid water from a water supply in fluid communication with the inside of the inner conduit, the inner conduit comprising a vapor membrane and circumscribed within an outer conduit having an outside surface exposed to an atmosphere and an inside surface facing the inner conduit forming a lumen between the inner conduit and the inside surface of the outer conduit, the lumen running the length of the outer conduit, the outer conduit comprising a CO 2 pump membrane that is CO 2 -permeable;
introducing a water vapor into the lumen by allowing the liquid water inside the inner conduit to evaporate and pass through the vapor membrane, the vapor membrane being sufficiently hydrophobic and porous to contain the liquid water while also allowing water vapor to pass through the vapor membrane into the lumen;
forming and maintaining a carbon concentration gradient across the CO 2 pump membrane by allowing water vapor to pass from the lumen to the atmosphere through the CO 2 pump membrane, the carbon concentration gradient having a first concentration at the outside surface that is higher than a second concentration at the inside surface, said carbon concentration gradient actively pumping CO 2 out of the atmosphere and into the lumen as a CO 2 -rich gas; and
removing CO 2 -rich gas and water vapor from the lumen with a mechanical pump that is in fluid communication with the lumen, the mechanical pump maintaining a pressure differential between the lumen and the atmosphere and providing a product stream comprising the CO 2 -rich gas.

12. The method of claim 11 , further comprising substantially evacuating the lumen before introducing the water vapor into the lumen.

13. The method of claim 11 , further comprising condensing the water vapor at it is removed from the lumen with the CO 2 -rich gas, the water vapor condensed with a cold trap coupled to the lumen and the mechanical pump such that the mechanical pump is in fluid communicat

Assignees

• Univ Arizona State

Inventors

• Lackner Klaus

Classifications

• B01D53/229 Primary

  Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption) · CPC title

• B01D53/22

  by diffusion (manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00) · CPC title

• F17C11/00

  Use of gas-solvents or gas-sorbents in vessels {(absorbing compositions for acetylene C10L3/04; absorbing compositions for hydrogen C01B3/0005)} · CPC title

• B01D53/265

  by refrigeration (condensation) · CPC title

• B01D8/00

  Cold traps; Cold baffles (pumps for evacuating by condensing or freezing F04B37/08) · CPC title