Fuel cell staging for molten carbonate fuel cells

Patent metadata

Field	Value
Publication number	US-11476486-B2
Application number	US-201916695286-A
Country	US
Kind code	B2
Filing date	Nov 26, 2019
Priority date	Nov 30, 2018
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

Systems and methods are provided for using fuel cell staging to reduce or minimize variations in current density when operating molten carbonate fuel cells with elevated CO2 utilization. The fuel cell staging can mitigate the amount of alternative ion transport that occurs when operating molten carbonate fuel cells under conditions for elevated CO2 utilization.

First claim

The invention claimed is:

1. A method for producing electricity, the method comprising:
introducing an anode input stream comprising H 2 , a reformable fuel, or a combination thereof into a first anode stage of a plurality of molten carbonate fuel cell stages;
introducing a cathode input stream comprising O 2 and CO 2 into a first cathode stage of the plurality of molten carbonate fuel cell stages;
passing a second anode input stream into a second anode stage of the plurality of molten carbonate fuel cell stages;
passing an intermediate cathode output into a second cathode stage of the plurality of molten carbonate fuel cell stages; and
operating the plurality of molten carbonate fuel cell stages to generate i) electricity at an average current density of 60 mA/cm 2 or more with respect to one or more fuel cell stages of the plurality of molten carbonate fuel cell stages, ii) an anode exhaust from the plurality of molten carbonate fuel cell stages comprising H 2 , CO, and CO 2 , and iii) a cathode exhaust from the plurality of molten carbonate fuel cell stages comprising a CO 2 content of 2.0 vol % or less, a H 2 O content of 1.0 vol % or more, and an O 2 content of 1.0 vol % or more, at least one of the first cathode stage and the second cathode stage being operated at a transference of 0.97 or less.

2. The method of claim 1 , wherein the at least one of the first cathode stage and the second cathode stage is operated at a transference of 0.95 or less.

3. The method of claim 1 , wherein the plurality of molten carbonate fuel cell stages are operated at a combined transference of 0.97 or less.

4. The method of claim 1 , wherein the second anode input stream comprises at least a portion of an intermediate anode output stream.

5. The method of claim 4 , wherein the intermediate anode output comprises an output from the first anode stage.

6. The method of claim 5 , further comprising:
passing a second anode intermediate output into a third anode stage, the anode exhaust comprising an output from the third anode stage; and
passing a second cathode intermediate output into a third cathode stage, the cathode exhaust comprising an output from the third cathode stage,
wherein the first anode stage, the second anode stage, and the third anode stage are arranged in a co-current manner or a counter-current manner relative to the first cathode stage, the second cathode stage, and the third cathode stage.

7. The method of claim 1 , wherein a transference in the first cathode stage is different from a transference in the second cathode stage.

8. The method of claim 1 , wherein at least the first anode stage, the second anode stage, the first cathode stage, and the second cathode stage are operated in a co-current, cross-flow manner.

9. The method of claim 1 , wherein at least the first anode stage, the second anode stage, the first cathode stage, and the second cathode stage are operated in a counter-current, cross-flow manner.

10. The method of claim 1 , wherein the anode exhaust comprises an anode output from the second anode stage, or wherein the cathode exhaust comprises a cathode output from the second cathode stage, or a combination thereof.

11. The method of claim 1 , wherein the intermediate cathode output comprises an output from the first cathode stage.

12. The method of claim 1 , wherein a combined measured CO 2 utilization in the first cathode stage and the second cathode stage during the operating of the plurality of molten carbonate fuel cells is 75% or more.

13. The method of claim 1 , wherein the electricity is generated at a current density of 120 mA/cm 2 or more with respect to one or more fuel cell stages of the plurality of molten carbonate fuel cell stages.

14. The method of claim 1 , wherein the voltage drop across the first cathode stage, the second cathode stage, or both is 0.4 V or less, or wherein the electricity is generated at a voltage of 0.55 V or more, or a combination thereof.

15. The method of claim 1 , wherein a fuel utilization in the first anode stage, the second anode stage, or both is 60% or more, or wherein a fuel utilization in the first anode stage, the second anode stage, or both is 55% or less.

16. The method of claim 1 , wherein a H 2 concentration in the anode exhaust is 5.0 vol % or more, or wherein a combined concentration of H 2 and CO in the anode is exhaust is 6.0 vol % or more, or a combination thereof.

17. The method of claim 1 , wherein the plurality of molten carbonate fuel cell stages is operated at a thermal ratio of 0.25 to 1.0.

18. The method of claim 1 , wherein an amount of the reformable fuel introduced into the first anode stage, an internal reforming element associated with the first anode stage, or a combination thereof, is at least about 75% greater than the amount of hydrogen reacted in the first anode stage to generate electricity.

19. The method of claim 1 , wherein the cathode input stream comprises 5.0 vol % or less of CO 2 , or wherein the cathode exhaust comprises 1.0 vol % or less of CO 2 , or a combination thereof.

Assignees

• Exxonmobil Technology & Engineering Company
• Fuelcell Energy Inc

Inventors

• Blanco Gutierrez Rodrigo F
• Shen Eric B
• Pereira Carla S
• Davis Keith E
• Ghezel-Ayagh Hossein

Classifications

• H01M8/145 Primary

  comprising carbonates · CPC title

• H01M8/04589

  of fuel cell stacks · CPC title

• H01M2008/147

  Fuel cells with molten carbonates · CPC title

• H01M8/04951

  of the individual fuel cell · CPC title

• H01M8/04843

  of fuel cell exhausts · CPC title