Method and a system for removing hydrogen sulphide ions (HS−) from a liquor of a pulp mill process

Patent metadata

Field	Value
Publication number	US-11473243-B2
Application number	US-201816756781-A
Country	US
Kind code	B2
Filing date	Oct 15, 2018
Priority date	Oct 20, 2017
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

A method for removing hydrogen sulphide ions (HS−) from a liquor (300) of a pulp mill process, the method comprising pumping the liquor (300) to an injector arrangement (710) using a pump arrangement (720) such that the pumping of the liquor (300) through a jet nozzle (115) generates suction at a gas inlet (130), whereby reagent gas (310) is mixed with the liquor (300), and letting out the treated liquor (300) from the injector arrangement (710) to a vessel (200). In this way, the liquor (300) is treated to form at least partly treated liquor (300). A corresponding use of an injector arrangement. A system for performing the method.

First claim

The invention claimed is:

1. A method for removing hydrogen sulphide ions (HS − ) from a liquor of a pulp mill process, the method comprising:
pumping the liquor to an injector arrangement using a pump arrangement, the injector arrangement comprising at least one injector, the at least one injector comprising: a first chamber configured to receive the liquor from the pump arrangement, a jet nozzle for forming a jet of the liquor, and a gas inlet passage configured to convey reagent gas to be mixed with the jet,
letting out the liquor from the injector arrangement to a vessel, whereby some of the hydrogen sulphide ions (HS − ) are removed from the liquor and at least partly treated liquor is formed, and
conveying a part of the liquor from a first outlet of the vessel to a circulation of the liquor to a point upstream from the injector arrangement,
wherein the pumping of the liquor through the jet nozzle generates the jet and suction at the gas inlet passage such that an absolute pressure of the reagent gas in the gas inlet passage is from 0.1 atm to 1.0 atm, whereby reagent gas is mixed with the liquor.

2. The method of claim 1 , wherein the first outlet of the vessel is arranged at a lower part of the vessel.

3. The method of claim 1 , wherein the first outlet of the vessel is arranged at a bottom of the vessel.

4. The method of claim 2 , wherein:
a first mass flow of the liquor is conveyed using the pump arrangement via the injector arrangement to the vessel,
a second mass flow of the liquor is conveyed from the vessel for use and/or for further treatment by gas, and
a third mass flow of the liquor is recycled from the first outlet of the vessel to the circulation of the liquor,
wherein a ratio of the second mass flow to the third mass flow is from 10% to 90%.

5. The method of claim 1 , further comprising:
measuring a content of a compound or compounds of the liquor from the vessel or from another vessel, and
controlling a flow of the liquor from the vessel or the other vessel, respectively, by using the measured content of the compound or compounds of the liquor.

6. The method of claim 5 , wherein either:
the compound or compounds is/are such a compound or compounds of the liquor of which content is affected by reaction of the liquor with the reagent gas, or
the compound or at least one of the compounds is either sodium sulphide (Na 2 S) or sodium thiosulphate (Na 2 S 2 O 3 ).

7. The method of claim 1 , further comprising:
conveying at least partly treated liquor from the vessel into a second vessel,
pumping the at least partly treated liquor to a second injector arrangement using a second pump arrangement, thereby: generating suction at a gas inlet of the second injector arrangement, and mixing second gas with the at least partly treated liquor,
letting out the at least partly treated liquor from the second injector arrangement to the second vessel, whereby the at least partly liquor is further reacted with the second gas, and
an oxygen content of the second gas is greater than an oxygen content of the reagent gas.

8. The method of claim 1 , comprising a pre-treatment stage upstream from the vessel, wherein:
the pre-treatment stage comprises:
pumping the liquor to a pre-treatment injector arrangement using a pre-treatment pump arrangement, thereby: generating suction at a gas inlet of the pre-treatment injector arrangement, and mixing pre-treatment gas with the liquor, and
letting out the liquor from the pre-treatment injector arrangement to a pre-treatment vessel, whereby the liquor is reacted with the pre-treatment gas, and

the method further comprises conveying the pre-treated liquor from the pre-treatment vessel to the vessel.

9. The method of claim 1 , wherein at least one of:
[A] the injector comprises a collision element, wherein the jet nozzle is arranged relative to the collision element in such a way that the jet formed by the jet nozzle is directed towards the collision element;
[B] the liquor is pumped to the vessel via the injector arrangement in such a way that the mixing of the reagent gas with the liquor forms bubbles of which an average diameter is at most 5 mm; or
[C] the liquor is pumped to the vessel via the injector arrangement in such a way that a velocity of the liquor in the jet is at least 5 m/s.

10. The method of claim 1 , wherein:
the liquor comprises sodium sulphide (Na 2 S),
the reagent gas comprises oxygen (O 2 ), and
the method further comprises oxidizing sodium sulphide (Na 2 S) to at least sodium thiosulphate (Na 2 S 2 O 3 ) by chemical reaction of the liquor with the reagent gas, thereby removing hydrogen sulphide ions (HS − ) from the liquor.

11. The method of claim 1 , wherein:
the liquor comprises sodium sulphide (Na 2 S),
the reagent gas comprises oxygen (O 2 ), and
the method further comprises:
receiving liquor having a sodium sulphide (Na 2 S) content of from 25 g/l to 60 g/l, and
oxidizing the received liquor in such a way that the sodium sulphide (Na 2 S) content of the at least partly oxidized liquor in the vessel is less than 3 g/l.

12. The method of claim 11 , wherein the sodium sulphide (Na 2 S) content is at most 1.5 g/l.

13. The method of claim 1 , wherein:
the liquor comprises sodium sulphide (Na 2 S),
the reagent gas comprises acid gas,
the method further comprises acidifying the liquor to remove hydrogen sulphide ions (HS − ) from the liquor, and
the reagent gas comprises an acid gas selected from a group consisting of carbon dioxide (CO 2 ), sulphur dioxide (SO 2 ), sulphur trioxide (SO 3 ), a nitrogen oxide (NOx), hydrogen fluoride (HF), hydrogen chloride (HCl), hydrogen bromide (HBr), hydrogen iodide (HI), and formic acid (HCOOH).

14. The method of claim 13 , wherein the reagent gas is carbon dioxide (CO 2 ) or sulphur dioxide (SO 2 ).

15. The method of claim 1 , further comprising heating the liquor or the at least partly treated liquor by injecting steam into the vessel.

16. The method of claim 1 , wherein the temperature of the liquor in the vessel is from 80° C. to 98° C.

17. The method of claim 1 , further comprising one of [A], [B], [C], or [D], each defined as:
[A]:
forming the liquor in a causticizer, whereby the liquor is white liquor of a Kraft process,
using such a reagent gas that comprises oxygen (O 2 ), and
oxidizing white liquor; and/or
using the oxidized white liquor in delignification plant or bleaching process for pulp;

[B]:
forming the liquor in a digester, and optionally concentrating the liquor, whereby the liquor is black liquor of a Kraft process,
using such a reagent gas or gases that comprise oxygen (O 2 ) and an acid gas, and acidifying and oxidizing the black liquor;

[C]:
forming the liquor in a chemical recovery boiler, whereby the liquor is green liquor of a Kraft process,
using such a reagent gas or gases that comprise acid gas, and
acidifying the green liquor;

[D]:
forming the liquor in a digester, and optionally concentrating the liquor, whereby the liquor is black liquor of a Kraft process,
using such a reagent gas or gases that comprise acid gas, and
acidifying the black liquor.

18. A method for removing hydrogen sulphide ions (HS − ) from a liquor of a pulp mill process, the method comprising:
pumping the liquor to an injector arrangement using a pump arrangement, the injector arrangement comprising at least one injector, the at least one injector comprising: a first chamber configured to receive the liquor from the pump arrangement, a jet nozzle for forming a jet of the liquor

Assignees

• Valmet Technologies Oy

Inventors

• Lampinen Rami
• Välimäki Erkki
• Hilli Tuomo

Classifications

• D21C11/0057 Primary

  Oxidation of liquors, e.g. in order to reduce the losses of sulfur compounds, followed by evaporation or combustion if the liquor in question is a black liquor (deodorisation of gases D21C11/08; combustion D21C11/12, D21C11/14) · CPC title

• F04F5/42

  characterised by the input flow of inducing fluid medium being radial or tangential to output flow (cyclones B04C) · CPC title

• D21C11/04 Primary

  of alkali lye · CPC title

• B01J10/00

  Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor (B01J19/08 takes precedence; separation, e.g. distillation, also combined with chemical reactions B01D, {e.g. B01D3/009}) · CPC title

• D21C11/00

  Regeneration of pulp liquors {or effluent waste waters} · CPC title