Distillate hydrocracking process with an n-paraffins separation step to produce a high octane number isomerate stream and a steam pyrolysis feedstock

Patent metadata

Field	Value
Publication number	US-11473022-B2
Application number	US-202117143286-A
Country	US
Kind code	B2
Filing date	Jan 7, 2021
Priority date	Jan 7, 2021
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

In accordance with one or more embodiments of the present disclosure, process for reforming a diesel feedstock to convert diesel to a gasoline blending component includes hydrodesulfurizing and hydrodenitrogenizing the diesel feedstock to reduce a sulfur content of the diesel feedstock and a nitrogen content of the diesel feedstock; hydrocracking the hydrodesulfurized and hydrodenitrogenized diesel feedstock over a metal-containing diesel hydrocracking catalyst comprising at least one zeolite to produce an isomerate fraction; and separating the isomerate fraction into a first stream enriched in n-paraffins and a second stream enriched in iso-paraffins and naphthenes.

First claim

What is claimed is:

1. A process for reforming a diesel feedstock to convert diesel to a gasoline blending component, comprising:
hydrodesulfurizing and hydrodenitrogenizing the diesel feedstock to reduce a sulfur content of the diesel feedstock and a nitrogen content of the diesel feedstock;
hydrocracking the hydrodesulfurized and hydrodenitrogenized diesel feedstock over a metal-containing diesel hydrocracking catalyst comprising at least one zeolite to produce an isomerate fraction;
separating the isomerate fraction into a first stream enriched in n-paraffins and a second stream enriched in iso-paraffins and naphthenes; and
adding at least a portion of the second stream to a feedstock for a fluid catalytic cracking process.

2. The process of claim 1 , further comprising steam cracking at least a portion of the first stream to convert at least a portion of the n-paraffins to light olefins.

3. The process of claim 1 , further comprising adding at least a portion of the second stream to a gasoline pool.

4. The process of claim 1 , wherein the fluid catalytic cracking process converts at least a portion of the feedstock for the fluid catalytic cracking process to propylene.

5. The process of claim 1 , wherein the sulfur content of the diesel feedstock is reduced to less than or equal to 500 ppm by weight in the hydrodesulfurizing step.

6. The process of claim 1 , wherein the diesel feedstock boils at a temperature from 150° C. to 420° C.

7. The process of claim 1 , wherein the metal-containing diesel hydrocracking catalyst comprises a noble metal selected from the group consisting of platinum, palladium, ruthenium, gold, and a combination of two or more thereof.

8. The process of claim 1 , wherein the hydrocracking occurs in a hydrocracking reactor that operates at a temperature from 280° C. to 400° C., at pressure less than or equal to 60 bars, and at a liquid hourly space velocity from 0.5 per hour to 5 per hour.

9. The process of claim 1 , wherein the at least one zeolite comprises at least one of an ultra-stable Y-type (USY) zeolite, a post modified USY zeolite, a zeolite beta (BEA zeolite), an FAU zeolite, an MFI zeolite, or an MOR zeolite.

10. A process for reforming a diesel feedstock to convert diesel to a gasoline blending component, comprising:
introducing the diesel feedstock to a treater for hydrodesulfurizing and hydrodenitrogenizing the diesel feedstock to reduce a sulfur content of the diesel feedstock and a nitrogen content of the diesel feedstock;
passing the hydrodesulfurized and hydrodenitrogenized diesel feedstock to a hydrocracker comprising a metal-containing diesel hydrocracking catalyst comprising at least one zeolite to produce an isomerate fraction;
introducing the isomerate fraction to a separator to separate the isomerate fraction into a first stream enriched in n-paraffins and a second stream enriched in iso-paraffins and naphthenes; and
adding at least a portion of the second stream to a feedstock for a fluid catalytic cracking process.

11. The process of claim 10 , further comprising steam cracking at least a portion of the first stream to convert at least a portion of the n-paraffins to light olefins.

12. The process of claim 10 , further comprising adding at least a portion of the second stream to a gasoline pool.

13. The process of claim 10 , wherein the fluid catalytic cracking process converts at least a portion of the feedstock for the fluid catalytic cracking process to propylene.

14. The process of claim 10 , wherein the sulfur and nitrogen contents of the diesel feedstock are reduced to less than or equal to 10 ppm by weight in the treater.

15. The process of claim 10 , wherein the diesel feedstock boils at a temperature from 150° C. to 420° C.

16. The process of claim 10 , wherein the metal-containing diesel hydrocracking catalyst comprises a noble metal selected from the group consisting of platinum, palladium, ruthenium, gold, and a combination of two or more thereof.

17. The process of claim 10 , wherein the hydrocracking occurs in a hydrocracking reactor that operates at a temperature from 280° C. to 400° C., at pressure less than or equal to 60 bars, and at a liquid hourly space velocity from 0.5 per hour to 5 per hour.

18. The process of claim 10 , wherein the at least one zeolite comprises at least one of an ultra-stable Y-type (USY) zeolite, a post modified USY zeolite, a zeolite beta (BEA zeolite), an FAU zeolite, an MFI zeolite, or an MOR zeolite.

Assignees

• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa
• Punetha Ashok Kumar

Classifications

• C10G2400/02

  Gasoline · CPC title

• C10G2300/4006

  Temperature · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title

• C10G2300/1048

  Middle distillates · CPC title

• C10G69/06

  including at least one step of thermal cracking in the absence of hydrogen · CPC title