Composition for 3D printing

Patent metadata

Field	Value
Publication number	US-11472971-B2
Application number	US-201615762414-A
Country	US
Kind code	B2
Filing date	Sep 26, 2016
Priority date	Sep 25, 2015
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

The present application relates to a resin composition for 3D printing, a 3D printing method using the same, and a three-dimensional shape comprising the same, and provides a resin composition which is capable of precisely forming a three-dimensional shape and implementing uniform curing properties of a three-dimensional shape.

First claim

The invention claimed is:

1. A composition for 3D printing comprising magnetic particles having at least two magnetic domains, wherein the magnetic domains are irregularly arranged when an external magnetic field is absent and are magnetized by an external magnetic field, and a thermosetting resin, wherein the magnetic particles are vibrated by magnetization reversal, and
wherein the magnetic particles satisfy Formula 1 below:
MX a O b   [Formula 1]

wherein, M is a metal oxide, X includes Fe, Mn, Co, Ni or Zn, and |a×c|=|b×d| is satisfied, where c is the cation charge of X, and d is the anion charge of oxygen, and
wherein the magnetic particles have a coercive force in a range of 1 to 200 kOe, and wherein the magnetic particles have an average particle size in a range of 20 to 50 nm.

2. The composition for 3D printing according to claim 1 , wherein the magnetic particles have a saturation magnetization value at 25° C. in a range of 20 to 150 emu/g.

3. The composition for 3D printing according to claim 1 , wherein the magnetic domains have an average size in a range of 10 to 50 nm.

4. The composition for 3D printing according to claim 1 , wherein the magnetic particles are comprised in an amount of 0.01 to 25 parts by weight, relative to 100 parts by weight of the thermosetting resin.

5. The composition for 3D printing according to claim 1 , wherein the magnetic particles form magnetic clusters.

6. The composition for 3D printing according to claim 1 , wherein the thermosetting resin comprises at least one thermosetting functional group.

7. The composition for 3D printing according to claim 1 , further comprising a thermosetting agent.

8. The composition for 3D printing according to claim 7 , wherein the filler comprises an organic filler, an inorganic filler, or a mixture thereof.

9. The composition for 3D printing according to claim 1 , further comprising a filler.

10. The composition for 3D printing according to claim 1 , further comprising a dispersing agent.

11. A 3D printing method comprising a step of applying the composition for 3D printing of claim 1 to form a three-dimensional shape.

12. The 3D printing method according to claim 11 , further comprising a step of applying a magnetic field to the applied composition.

13. The 3D printing method according to claim 12 , wherein the step of applying a magnetic field applies a magnetic field with a current of 50 A to 500 A for 20 seconds to 60 minutes at a frequency of 100 kHz to 1 GHz.

14. The 3D printing method according to claim 12 , wherein the step of applying a magnetic field comprises at least two steps of multi-profile methods.

15. The 3D printing method according to claim 14 , wherein the multi-profile method comprises a first step of applying a magnetic field with a current of 10 A to 80 A for 20 seconds to 10 minutes, a second step of applying a magnetic field with a current of 80 A to 130 A for 20 seconds to 10 minutes and a third step of applying a magnetic field with a current of 150 A to 500 A for 5 seconds to 5 minutes, at a frequency of 100 kHz to 1 GHz.

16. A three-dimensional shape comprising a cured product of the composition for 3D printing of claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Ahn Sang Bum
• Shin Jong Min
• Lee Jin Kyu

Classifications

• B29K2995/0008

  Magnetic or paramagnetic · CPC title

• B29K2463/00

  Use of {EP, i.e.} epoxy resins {or derivatives thereof} as filler · CPC title

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• C08K2003/2272

  Ferric oxide (Fe2O3) · CPC title