Substituted bis-2-indenyl metallocene compounds

Patent metadata

Field	Value
Publication number	US-11472895-B2
Application number	US-201917267663-A
Country	US
Kind code	B2
Filing date	Aug 29, 2019
Priority date	Aug 30, 2018
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

The present invention provides a compound according to formula (I): (I) wherein: •R2 is abridging moiety containing at least one sp2 hybridised carbon atom; •each R4, R4′, R7 and R7′ are hydrogen or moieties comprising 1-10 carbon atoms, wherein each R4, R4′, R7 and R7′ are the same; •each R5, R5′, R6 and R6′ are moieties comprising 1-10 carbon atoms, wherein each R5, R5′, R6 and R6′ are the same; and •Z is a moiety selected from ZrX 2 , HfX 2 , or TiX 2 , wherein X is selected from the group of halogens, alkyls, aryls and aralkyls. Such compound allows for the preparation of catalyst systems that provide improved olefin reactivity, such as ethylene reactivity, increased molecular weight in olefin polymerisation, such as increased M w in ethylene polymerisation, and increased comonomer incorporation in copolymerisation reactions of olefins, such as in copolymerisation reactions of ethylene with 1-hexene.

First claim

The invention claimed is:

1. Compound according to formula I:

wherein:
R2 is a bridging moiety containing at least one sp2 hybridised carbon atom; and
Z is a moiety selected from ZrX 2 , HfX 2 , or TiX 2 , wherein X is selected from halogens, alkyls, aryls, or aralkyls,
wherein condition (i) or condition (ii) applies:
(i) each of R4, R4′, R7 and R7′ is hydrogen or methyl, R4, R4′, R7 and R7′ are the same, R5 with R6 are connected to form a first fused moiety, R5′ with R6′ are connected to form a second fused moiety, the first fused moiety has the same structure as the second fused moiety, and the first fused moiety and the second fused moiety are selected from a benzene ring, a cyclohexane ring, or a cyclopentane ring, wherein the benzene ring, the cyclohexane ring, and the cyclopentane ring are optionally substituted with one or more methyl groups; or
(ii) R4 with R5, R4′ with R5′, R6 with R7, and R6′ with R7′ are connected to form fused moieties, the fused moieties of R4 with R5, R4′ with R5′, R6 with R7, and R6′ with R7′ are the same and are each a 5-carbon ring or a 6-carbon ring, wherein the 5-carbon ring and the 6-carbon ring are optionally substituted with one or more methyl groups.

2. Compound according to formula I:

wherein:
R2 is a bridging moiety containing at least one sp2 hybridised carbon atom;
R4, R4′, R7 and R7′ are hydrogen;
each of R5, R5′, R6 and R6′ is methyl; and
Z is a moiety selected from ZrX 2 , HfX 2 , or TiX 2 , wherein X is selected from halogens, alkyls, aryls or aralkyls.

3. Compound according to claim 1 , wherein each of the first fused moiety and the second fused moiety is a cyclohexane ring substituted with one or more methyl groups.

4. Compound according to claim 1 , wherein R4, R4′, R7 and R7′ are hydrogen.

5. Catalyst system comprising the compound according to claim 1 and a cocatalyst selected from aluminium- or boron-containing cocatalysts.

6. Process for preparation of olefin-based polymers, comprising a step of polymerisation of at least one olefinic compound in the presence of the catalyst system according to claim 5 .

7. Process according to claim 6 , wherein the olefinic compound(s) each are mono-olefinic compounds or di-olefinic compounds.

8. Process according to claim 6 , wherein the olefinic compound(s) each are α-olefins.

9. Process according to claim 6 , wherein the olefinic compound(s) each are selected from ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, or 1-octene.

10. Process according to claim 6 , wherein the process is a copolymerisation process of ethylene and one or more comonomer selected from propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, or 1-octene.

11. Process according to claim 10 , wherein the comonomer is selected from 1-butene, 1-hexene, or 1-octene.

12. Process according to claim 6 , wherein the process is a gas-phase polymerisation process, a slurry polymerisation process, or a solution polymerisation process.

13. Compound according to claim 1 , wherein
R2 is 2,2′-biphenylene; and
Z is a moiety selected from ZrX 2 , HfX 2 , or TiX 2 , wherein X is a halogen or an alkyl group.

14. Compound according to claim 1 , wherein the fused moieties of R4 with R5, R4′ with R5′, R6 with R7, and R6′ with R7′ are each a 5-carbon ring optionally substituted with one or two methyl groups.

15. Compound according to claim 1 , wherein the compound is [6,6′-biphenyl-2,2′-diylbis(1,2,3,5-tetrahydro-s-indacenyl)]zirconium dichloride, [2,2′-di-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-cyclopenta[b]naphthalene-2-yl)biphenyl]zirconium dichloride, [6,6′-biphenyl-2,2′-diylbis(2,2′-dimethyl-1,2,3,5-tetrahydro-s-indacenyl)]zirconium dichloride, [6,6′-biphenyl-2,2′-diylbis(η 5 -2,2,5,5-tetramethyl-2,3,4,5,6,7-hexahydro-cyclopenta[e]as-indacenyl)]zirconium dichloride, [2,2′-biphenyl-2,2′-diylbis-η5-cyclopenta[b]naphthalenyl]zirconium dimethyl, or [6,6′-biphenyl-2,2′-diylbis(η 5 -4,8-dimethyl-1,2,3,5-tetrahydro-s-indacenyl)]zirconium dichloride.

16. Compound according to claim 2 , wherein R2 is 1,2-phenylene or 2,2′-biphenylene.

17. Compound according to claim 2 , wherein the compound is [2,2′-di-(η 5 -5,6-dimethyl-inden-2-yl)biphenyl]zirconium dichloride.

Assignees

• Sabic Global Technologies Bv

Inventors

• Hendriksen Coen
• Friederichs Nicolaas Hendrika
• Sainani Jaiprakash Brijlal
• Chatterjee Anamitra
• Izmer Vyatcheslav
• Kononovich Dmitry
• Voskoboynikov Alexander
• Busico Vincenzo
• Cipullo Roberta
• Vittoria Antonio
• Samsonov Oleg V

Classifications

• C08F4/65927 Primary

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08F4/65916

  supported on a carrier, e.g. silica, MgCl2, polymer · CPC title

• C08F110/02 Primary

  Ethene · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title