Acrylic polymer particles, production process therefor, ink composition, and coating composition

Patent metadata

Field	Value
Publication number	US-11472893-B2
Application number	US-201916582558-A
Country	US
Kind code	B2
Filing date	Sep 25, 2019
Priority date	Jan 4, 2016
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

Particles of an acrylic polymer comprising a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from a (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms, wherein the particles having electrostatic buildup inhibition rate of 90 to 99.9° as obtained by a specific method.

First claim

The invention claimed is:

1. Particles of an acrylic polymer, comprising
a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from a (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms,
wherein the particles are formed of one type of acrylic copolymer obtained by a single polymerization step, and
wherein the particles having electrostatic buildup inhibition rate of 90 to 99.9% as obtained by the following method:
(Method for obtaining electrostatic buildup inhibition rate):
According to JIS K 7365:1999 “Plastics Method for determination of apparent density of material that can be poured from a specified funnel”, volume density (A) of the particles of an acrylic polymer is measured, In addition, an anti-static agent is added in an amount of 0.1 g per 100 mL of the particles of an acrylic polymer, volume density (B) of a mixture obtained by sufficiently mixing them is measured, and the electrostatic buildup inhibition rate is calculated based on the following mathematical equation (1).
Electrostatic buildup inhibition rate (%)=Volume density( A )/Volume density ( B )×100  (1)

2. The particles of an acrylic polymer according to claim 1 , wherein a sodium element amount in the particles of an acrylic polymer is 3.5 to 50 ppm.

3. The particles of an acrylic polymer according to claim 2 , wherein the sodium element amount in the particles of an acrylic polymer is 3.5 to 30 ppm.

4. The particles of an acrylic polymer according to claim 1 , wherein the particles have a mass average particle diameter of 100 to 1000 μm.

5. The particles of an acrylic polymer according to claim 1 , further comprising a constituent unit (C) derived from α,β-unsaturated carboxylic acid.

6. Particles of an acrylic polymer, comprising a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms, the particles having a sodium element amount of 3.5 to 50 ppm,
wherein the particles are formed of one type of acrylic copolymer obtained by a single polymerization step.

7. The particles of an acrylic polymer according to claim 6 , wherein the sodium element amount in the particles of an acrylic polymer is 3.5 to 30 ppm.

8. The particles of an acrylic polymer according to claim 6 , wherein the particles have a mass average particle diameter of 100 to 1000 μm.

9. The particles of an acrylic polymer according to claim 6 , further comprising a constituent unit (C) derived from α,β-unsaturated carboxylic acid.

10. A process for producing particles of an acrylic polymer according to claim 1 , the process comprising a step of washing the acrylic polymer obtained by suspension polymerization so as to have a sodium element amount of 3.5 to 50 ppm.

11. The process for producing particles of an acrylic polymer according to claim 10 , wherein a dispersion agent containing sodium element is used for the suspension polymerization.

12. The process for producing particles of an acrylic polymer according to claim 11 , wherein a use amount of the dispersion agent is an amount allowing that the sodium element amount contained in the dispersion agent is 0.0009 to 0.004 part by mass relative to 100 parts by mass of a raw material monomer of the particles of an acrylic polymer.

13. The process for producing particles of an acrylic polymer according to claim 10 , wherein a dispersion aid containing sodium element is used for the suspension polymerization.

14. The process for producing particles of an acrylic polymer according to claim 13 , wherein a use amount of the dispersion aid is an amount allowing that the sodium element amount contained in the dispersion aid is 0.06 to 0.35 part by mass relative to 100 parts by mass of a raw material monomer of the particles of an acrylic polymer.

15. The process for producing particles of an acrylic polymer according to claim 10 , wherein the washing is carried out by using an aqueous solution of a sodium element-containing compound.

16. The process for producing particles of an acrylic polymer according to claim 15 , wherein a use amount of the aqueous solution of a sodium element-containing compound is an amount allowing that the sodium element amount contained in the aqueous solution of a sodium element-containing compound is 0.03 to 0.1 part by mass relative to 100 parts by mass of the acrylic polymer.

17. The process for producing particles of an acrylic polymer according to claim 15 , wherein mass of the aqueous solution of a sodium element-containing compound to be used for the washing is 1 to 3 times the acrylic polymer.

18. An ink composition, comprising the particles of an acrylic polymer according to claim 1 .

19. A coating composition, comprising the particles of an acrylic polymer according to claim 1 .

20. An article, comprising the coating composition of claim 19 , wherein the article is a container, marine article, or a road marking.

Assignees

• Mitsubishi Chem Corp

Inventors

• Saito Yoshikazu
• Mukuda Takahiro
• Fukuoka Hiroyuki
• Moriya Makoto
• Kiura Masaaki
• Serizawa Masashi

Classifications

• C08F2500/24

  Polymer with special particle form or size · CPC title

• C09D11/107

  from unsaturated acids or derivatives thereof · CPC title

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title

• C09D133/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08J3/12

  Powdering or granulating · CPC title