Extrados structural element made from an aluminium copper lithium alloy

Patent metadata

Field	Value
Publication number	US-11472532-B2
Application number	US-201414899743-A
Country	US
Kind code	B2
Filing date	Jun 18, 2014
Priority date	Jun 21, 2013
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

Extrados structural element made from an aluminum, copper and lithium alloy and method for manufacturing same. An alloy with composition (in wt %) 4.2-5.2 Cu, 0.9-1.2 Li, 0.1-0.3 Ag, 0.1-0.25 Mg, 0.08-0.18 Zr, 0.01-0.15 Ti, an Fe and Si content level less than or equal to 0.1% each, and other element with content level less than or equal to 0.05% each and 0.15% in total, is poured, homogenized, deformed hot, placed in a solution at a temperature of at least 515° C., pulled from 0.5 to 5% and annealed. The combination of magnesium, copper and manganese content with the temperature in solution can reach an advantageous elasticity under compression limit. Products having a thickness of at least 12 mm have, in the longitudinal direction, an elasticity under compression limit of at least 645 MPa and an elongation of at least 7%.

First claim

The invention claimed is:

1. A method for manufacturing an extruded, rolled and/or forged product made of an alloy containing aluminium, said method comprising
a) preparing a molten metal bath comprising 4.3 to 5.2% Cu by weight, 0.9 to 1.2% Li by weight, 0.2 to 0.25% Ag by weight, 0.1 to 0.25% Mg by weight, 0.08 to 0.18% Zr by weight, 0.01 to 0.15% Ti by weight, up to 0.2% Zn by weight, up to 0.6% Mn by weight, a Fe and Si content less than or equal to 0.1% by weight each, other elements with a content less than or equal to 0.05% by weight each and 0.15% by weight total, and the rest of aluminium;
b) casting a raw form from said molten metal bath;
c) homogenizing said raw form by a heat treatment in which the temperature at mid-thickness of the raw form reaches at least 510° C. for at least 10 hours,
d) hot working said raw form that has been homogenized from (c) into an extruded, rolled and/or forged product;
e) solution heat treating said product at a temperature of at least 515° C. and quenching;
f) controlled stretching said product that has been solution heat treated and quenched from (e) with a permanent set of 0.5 to 5%;
g) aging said product stretched with a permanent set from (f) by heating to a temperature of 150 to 160° C. for 5 to 70 hours.

2. The method according to claim 1 , wherein the copper content of said molten metal bath lies between 4.3 and 5.0% by weight.

3. The method according to claim 1 , wherein the lithium content of said molten metal bath lies between 1.0 and 1.15% by weight.

4. The method according to claim 1 , wherein the magnesium content of said molten metal bath lies between 0.15 and 0.24% by weight.

5. The method according to claim 1 , wherein the manganese content of said molten metal bath lies between 0.2 and 0.5% by weight.

6. The method according to claim 1 , wherein the zirconium content of said molten metal bath lies between 0.11 and 0.18% by weight.

7. The method according to claim 1 wherein the solution heat-treatment temperature is at least 520° C.

8. The method according to claim 1 , wherein the copper content of said molten metal bath lies between 4.4 and 4.8% by weight.

9. The method according to claim 1 , wherein the zirconium content of said molten metal bath lies between 0.13 and 0.17% by weight.

10. The method according to claim 1 wherein stress relieving by controlled stretching is performed with a permanent set from 0.5 to 1.5%.

11. The method according to claim 1 , wherein d) further comprises cold working the raw form after hot working and before homogenizing.

12. The method according to claim 1 , wherein the extruded, rolled and/or forged product made of an alloy containing aluminium consists essentially of 4.3 to 5.2% Cu by weight, 0.9 to 1.2% Li by weight, 0.2 to 0.25% Ag by weight, 0.1 to 0.25% Mg by weight, 0.08 to 0.18% Zr by weight, 0.01 to 0.15% Ti by weight, up to 0.2% Zn by weight, up to 0.6% Mn by weight, a Fe and Si content less than or equal to 0.1% by weight each, other elements with a content less than or equal to 0.05% by weight each and 0.15% by weight total, and the rest of aluminium.

13. The method according to claim 1 , wherein the extruded, rolled and/or forged product made of an alloy containing aluminium consists of 4.3 to 5.2% Cu by weight, 0.9 to 1.2% Li by weight, 0.2 to 0.25% Ag by weight, 0.1 to 0.25% Mg by weight, 0.08 to 0.18% Zr by weight, 0.01 to 0.15% Ti by weight, up to 0.2% Zn by weight, up to 0.6% Mn by weight, a Fe and Si content less than or equal to 0.1% by weight each, other elements with a content less than or equal to 0.05% by weight each and 0.15% by weight total, and the rest of aluminium.

14. The method according to claim 1 , wherein the product is a rolled product comprising a manganese content between 0.2 and 0.5% by weight and comprising a compressive yield stress in L direction of at least 653 MPa and a fracture toughness K Q (L-T) of at least 20 MPa√m.

15. The method according to claim 1 , wherein the solution heat treatment is performed in two steps, with a first step performed at a temperature between 515 and 520° C. and a second step performed at a temperature of at least 530° C.

Assignees

• Constellium Issoire

Inventors

• Danielou Armelle
• Pouget Gaelle
• Sigli Christophe

Classifications

• C21D1/30

  Stress-relieving · CPC title

• C22F1/057

  of alloys with copper as the next major constituent · CPC title

• C22C21/14

  with silicon · CPC title

• C22C21/16

  with magnesium · CPC title

• B22D21/007

  with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C · CPC title