MXene-based voice coils and active acoustic devices

Patent metadata

Field	Value
Publication number	US-11470424-B2
Application number	US-201917054291-A
Country	US
Kind code	B2
Filing date	Jun 4, 2019
Priority date	Jun 6, 2018
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

The present disclosure is directed to electroacoustical devices comprising patterned MXene compositions on biaxially oriented polymer substrates and methods of making and using the same.

First claim

What is claimed:

1. A voice coil comprising a patterned MXene composition attached to a biaxially oriented polyaromatic polymer film that has undergone oxygen plasma treatment to effect increased hydrophilicity.

2. The voice coil of claim 1 , wherein the MXene composition comprises at least one layer having first and second surfaces, each layer described by a formula M n+1 X n T x and comprising:
a substantially two-dimensional army of crystal cells,
each crystal cell having an empirical formula of M n+1 X n , such that each X is positioned within an octahedral array of M,
wherein M is at least one Group IIIB, IVB, VB, or VIB metal,
wherein each X is C, N, or a combination thereof;
n=1, 2, or 3; and wherein
T x represents surface termination groups.

3. The voice coil of claim 1 , wherein the MXene composition at least one layer having first and second surfaces, each layer comprising:
a substantially two-dimensional army of crystal cells,
each crystal cell having an empirical formula of M′ 2 M″ n X n+1 , such that each X is positioned within an octahedral array of M′ and M″, and where M″ n are present as individual two-dimensional array of atoms intercalated (sandwiched) between a pair of two-dimensional arrays of M′ atoms,
wherein M′ and M″ are different Group IIIB, IVB, VB, or VIB metals (especially where M′ and M″ are Ti, V, Nb, Ta, Cr, Mo, or a combination thereof),
wherein each X is C, N, or a combination thereof; and
n=1 or 2.

4. The voice coil of claim 1 , wherein the biaxially oriented polyaromatic polymer film comprises a polyester, a polyphenylene oxide, a polyamide, or a polyphenylene sulfide.

5. The voice coil of claim 1 , wherein the biaxially oriented polyaromatic polymer film comprises polyethylene terephthalate, polyethylenenaphthalate, or a polyphthalamide.

6. The voice coil of claim 1 , wherein the voice coil is patterned in a spiral or serpentine pattern.

7. The voice coil of claim 1 , wherein the voice coil is patterned in double Archimedean coil.

8. A planar electrical device comprising the voice coil of claim 1 , positioned within a frame.

9. An active acoustic device for receiving or transmitting acoustic waves, the active acoustic device comprising the voice coil of claim 1 , optionally comprising two or more magnets positioned proximate to the voice coil.

10. The active acoustic device of claim 9 further comprising two or more magnets positioned proximate to the voice coil.

11. The active acoustic device of claim 9 that is a microphone or a speaker.

12. The active acoustic device of claim 9 that is an electrostatic speaker, an electroacoustic transducer, a thermoacoustic transducer, or a planar speaker.

13. A method of making the voice coil of claim 1 , the method comprising spray-coating, spin coating, or roller coating a layer of MXene onto the biaxially oriented polyaromatic polymer film.

14. The method of claim 13 , wherein the voice coil is patterned by masking techniques.

15. A method of making the voice coil of claim 1 , the method comprising applying at least one layer of MXene composition onto the biaxially oriented polyaromatic polymer film and removing at least a portion of the applied MXene composition by wet or plasma or laser etching techniques to form a MXene pattern on the biaxially oriented polyaromatic polymer film.

16. A method of operating a voice coil of claim 1 , the method comprising passing an alternating current through the patterned MXene composition.

17. An active acoustic device for receiving or transmitting acoustic waves, the active acoustic device comprising the planar electrical device of claim 8 , optionally comprising two or more magnets positioned proximate to the voice coil.

18. A method of operating the planar electric device of claim 8 , the method comprising passing an alternating current through the patterned MXene composition.

19. A method of operating the active acoustic device of claim 9 , the method comprising passing an alternating current through the patterned MXene composition.

Assignees

• Univ Drexel

Inventors

• Spinelli Devon J
• Heng Thomas
• Sarycheva Asia
• Lelyukh Pavel S
• Gogotsi Yury

Classifications

• H04R9/025

  Magnetic circuit · CPC title

• H04R9/08

  Microphones · CPC title

• H04R9/06

  Loudspeakers · CPC title

• C01B32/90

  Carbides · CPC title

• H01F2007/068

  using printed circuit coils · CPC title