R-T-B based sintered magnet

Patent metadata

Field	Value
Publication number	US-11469016-B2
Application number	US-202016909351-A
Country	US
Kind code	B2
Filing date	Jun 23, 2020
Priority date	Jul 25, 2016
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

An R-T-B based sintered magnet containing a first heavy rare earth element, in which R includes Nd, T includes Co and Fe, the first heavy rare earth element includes Tb or Dy, the R-T-B based sintered magnet has a region in which a concentration of the first heavy rare earth element decreases from the surface toward the inside, a first grain boundary phase which contains the first heavy rare earth element and Nd but does not contain Co is present in one cross section including the region, and an area occupied by the first grain boundary phase in one cross section including the region is 1.8% or less.

First claim

What is claimed is:

1. An R-T-B based sintered magnet comprising a first heavy rare earth element, wherein
R includes Nd,
T includes Co and Fe,
the first heavy rare earth element includes Tb or Dy,
the R-T-B based sintered magnet comprises a region having a concentration of the first heavy rare earth element decreasing from a surface toward an inside,
a first grain boundary phase which contains the first heavy rare earth element and Nd but does not contain Co is present in one cross section including the region, and
an area occupied by the first grain boundary phase in the cross section is 1.35% or less.

2. The R-T-B based sintered magnet according to claim 1 , wherein a second grain boundary phase which contains Nd and Co but does not contain the first heavy rare earth element is further present in the region and
a ratio of an area of the first grain boundary phase to an area of the second grain boundary phase is 2.0 or less.

3. The R-T-B based sintered magnet according to claim 1 , further comprising a second heavy rare earth element, wherein
the second heavy rare earth element is substantially uniformly contained over the entire grain boundary phase of the R-T-B based sintered magnet and is a different kind of element from the first heavy rare earth element.

4. The R-T-B based sintered magnet according to claim 1 , wherein a second grain boundary phase of a multiparticle grain boundary phase which contains Nd and Co and has a substantially uniform concentration of the first heavy rare earth element is further present in the region and
a ratio of an area of the first grain boundary phase to an area of the second grain boundary phase is 2.0 or less.

5. The R-T-B based sintered magnet according to claim 2 , further comprising a second heavy rare earth element, wherein
the second heavy rare earth element is substantially uniformly contained over the entire grain boundary phase of the R-T-B based sintered magnet and is a different kind of element from the first heavy rare earth element.

6. The R-T-B based sintered magnet according to claim 1 , wherein the area occupied by the first grain boundary phase in the cross section is 0.69% or less.

7. A sintered magnet, wherein
a first heavy rare earth element contained in a heavy rare earth compound is diffused from a surface toward an inside of an R-T-B based sintered magnet by attaching the heavy rare earth compound to at least a part of the surface of the R-T-B based sintered magnet and heating the heavy rare earth compound, wherein
R includes Nd,
T includes Co and Fe,
the first heavy rare earth element includes Tb or Dy,
a first grain boundary phase which contains the first heavy rare earth element and Nd but does not contain Co is present in one cross section including a region having the first heavy rare earth element diffused,
an area occupied by the first grain boundary phase in the cross section is 1.35% or less,
a second grain boundary phase which contains Nd and Co but does not contain the first heavy rare earth element is further present in the region, and
a ratio of an area of the first grain boundary phase to an area of the second grain boundary phase is 2.0 or less.

8. The sintered magnet according to claim 7 , wherein the R-T-B based sintered magnet contains a second heavy rare earth element.

9. The R-T-B based sintered magnet according to claim 7 , wherein the area occupied by the first grain boundary phase in the cross section is 0.69% or less.

Assignees

• Tdk Corp

Inventors

• Kakoki Ayato
• Iwasaki Makoto
• Hidaka Tetsuya
• Hayakawa Takuma

Classifications

• C22C38/005

  containing rare earths, i.e. Sc, Y, Lanthanides · CPC title

• H01F1/0577 Primary

  sintered · CPC title

• C22C2202/02

  Magnetic · CPC title

• B22F2201/11

  Argon · CPC title

• B22F9/04

  starting from solid material, e.g. by crushing, grinding or milling ({C22C1/1084 takes precedence}; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C) · CPC title