Synthetic leather

Patent metadata

Field	Value
Publication number	US-11466402-B2
Application number	US-201915734671-A
Country	US
Kind code	B2
Filing date	May 9, 2019
Priority date	Jun 7, 2018
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

The present invention provides a synthetic leather including at least a base (i), an adhesive layer (ii), and a skin layer (iii). The adhesive layer (ii) and the skin layer (iii) are both formed of a urethane resin composition including a urethane resin and water, the urethane resin being produced using an aromatic polyisocyanate as a raw material. The urethane resin composition forming the adhesive layer (ii) preferably includes a urethane resin (A) and water (B), the urethane resin (A) being produced using an aromatic polyisocyanate (a1) as a raw material. The aromatic polyisocyanate (a1) preferably includes toluene diisocyanate. It is preferable that the urethane resin (A) include an anionic group and the concentration of the anionic group in the urethane resin (A) be 0.35 mmol/g or less.

First claim

The invention claimed is:

1. A synthetic leather comprising at least a base (i), an adhesive layer (ii), and a skin layer (iii),
the adhesive layer (ii) and the skin layer (iii) being both formed of a urethane resin composition including a urethane resin and water, the urethane resin being produced using an aromatic polyisocyanate as a raw material;
wherein the urethane resin composition forming the adhesive layer (ii) includes a urethane resin (A), which is produced using an aromatic polyisocyanate (a1) including toluene diisocyanate as a raw material, and water (B);
wherein the urethane resin composition forming the skin layer (iii) includes a urethane resin (X), which is produced using an aromatic polyisocyanate (x1) including diphenylmethane diisocyanate as a raw material, a nonionic emulsifier (Y), and water (Z).

2. The synthetic leather according to claim 1 , wherein the urethane resin (A) includes an anionic group, and the concentration of the anionic group in the urethane resin (A) is 0.35 mmol/g or less.

3. The synthetic leather according to claim 2 , wherein the urethane resin (A) has an aromatic ring concentration of 0.1 to 2.5 mol/kg.

4. The synthetic leather according to claim 2 , wherein the urethane resin (A) has a weight-average molecular weight of 2,000 to 150,000.

5. The synthetic leather according to claim 1 , wherein the urethane resin (A) has an aromatic ring concentration of 0.1 to 2.5 mol/kg.

6. The synthetic leather according to claim 1 , wherein the urethane resin (A) has a weight-average molecular weight of 2,000 to 150,000.

7. The synthetic leather according to claim 1 , wherein the urethane resin (X) has a urea bond concentration of 1.2 mol/kg or less.

8. The synthetic leather according to claim 7 , wherein the urethane resin (X) has an aromatic ring concentration of 0.1 to 50 mol/kg.

9. The synthetic leather according to claim 1 , wherein the urethane resin (X) has an aromatic ring concentration of 0.1 to 50 mol/kg.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Maeda Ryo
• TETSUI Tomohiro

Classifications

• D06N3/145 Primary

  two or more layers of polyurethanes · CPC title

• C09J175/04

  Polyurethanes · CPC title

• D06N3/08

  with a finishing layer consisting of polyacrylates, polyamides or polyurethanes {or polyester} · CPC title

• C08G18/6659

  with compounds of group C08G18/34 · CPC title

• C08G18/0823

  containing carboxylate salt groups or groups forming them · CPC title