Storable liquid suspension of hollow particles

Patent metadata

Field	Value
Publication number	US-11466202-B2
Application number	US-201616336825-A
Country	US
Kind code	B2
Filing date	Nov 11, 2016
Priority date	Nov 10, 2016
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

Provided are compositions and methods of using a liquid suspension of hollow particles comprising a plurality of hollow particles, water, a suspending aid, and a stabilizer selected from the group consisting of a non-ionic surfactant, a latex, an oleaginous fluid, porous silica, and combinations thereof. The liquid suspension is homogenous. An example method includes statically storing the liquid suspension in a container for at least one week; wherein the liquid suspension maintains a difference in density from the top of the container to the bottom of the container of less than one pound per gallon while stored. The method further includes adding the liquid suspension to a treatment fluid; wherein the liquid suspension reduces the density of the treatment fluid; and introducing the treatment fluid into a wellbore penetrating a subterranean formation.

First claim

What is claimed is:

1. A method of using a liquid suspension of hollow particles, the method comprising:
providing a liquid suspension of hollow particles comprising:
a plurality of hollow particles,
water,
a suspending aid,
a styrene-butadiene latex stabilizer; and
a non-ionic surfactant stabilizer selected from the group consisting of polyethylene oxide, polypropylene oxide, polyethylene glycol/polypropylene glycol block copolymers, derivatives thereof, and mixture thereof; wherein the non-ionic surfactant is present in the liquid suspension at a concentration of about 3% to about 30% by weight of the liquid suspension;

statically storing the liquid suspension in a container for at least one week; wherein the liquid suspension maintains a difference in density from the top of the container to the bottom of the container of less than one pound per gallon while stored;
adding the liquid suspension to a treatment fluid; wherein the liquid suspension reduces the density of the treatment fluid; and
introducing the treatment fluid into a wellbore penetrating a subterranean formation.

2. The method of claim 1 , wherein the liquid suspension is not agitated prior to adding the liquid suspension to the treatment fluid.

3. The method of claim 1 , wherein the liquid suspension is statically stored for at least one month.

4. The method of claim 1 , wherein the treatment fluid comprises a water-based drilling fluid, a cement slurry, a completion fluid, a displacement fluid, or a conformance fluid.

5. The method of claim 1 , wherein the plurality of hollow particles are selected from the group consisting of glass spheres, glass microspheres, ceramic spheres, cenospheres, and combinations thereof.

6. The method of claim 1 , wherein the suspending aid is selected from the group consisting of diutan gums, scleroglucan, guar gums, carragenans, xanthan gums, welan, celluloses, hydroxyethyl celluloses, bentonite, attapulgite, sepiolite, vermiculite, illite, muscovite, biotite, kaolinite, cookeite, halloysite, flint clay, montmorillonite, hectorite, and combinations thereof.

7. The method of claim 1 , wherein the stabilizer comprises the latex and the latex comprises a rubber selected from the group consisting of cis-1,4-polyisoprene rubber, styrene-butadiene rubber, cis-1,4-polybutadiene rubber, high styrene resin, butyl rubber, ethylene-propylene rubbers, neoprene rubber, nitrile rubber, cis-/trans-1,4-polyisoprene rubber, silicone rubber, chlorosulfonated polyethylene rubber, crosslinked polyethylene rubber, epichlorohydrin rubber, fluorocarbon rubber, fluorosilicone rubber, polyurethane rubber, polyacrylic rubber, polysulfide rubber, blends thereof, derivatives thereof, and combinations thereof.

8. A system for treating a subterranean formation comprising:
a liquid suspension of hollow particles comprising:
a plurality of hollow particles,
water,
a suspending aid,
a styrene-butadiene latex stabilizer, and
a non-ionic surfactant stabilizer selected from the group consisting of polyethylene oxide, polypropylene oxide, polyethylene glycol/polypropylene glycol block copolymers, derivatives thereof, and mixtures thereof; wherein the non-ionic surfactant is present in the liquid suspension at a concentration of about 3 % to about 30 % by weight of the liquid suspension; wherein the liquid suspension is capable of being statically stored in a container for one week; wherein the liquid suspension maintains a difference in density from the top of the container to the bottom of the container of less than one pound per gallon while stored;

a container capable of storing the liquid suspension of hollow particles for at least one week;
a treatment fluid;
mixing equipment capable of mixing the treatment fluid and the liquid suspension of hollow particles;
pumping equipment capable of pumping the treatment fluid into a wellbore penetrating a subterranean formation.

9. The system of claim 8 , wherein the suspending aid is selected from the group consisting of diutan gums, scleroglucan, guar gums, carragenans, xanthan gums, welan, celluloses, hydroxyethyl celluloses, bentonite, attapulgite, sepiolite, vermiculite, illite, muscovite, biotite, kaolinite, cookeite, halloysite, flint clay, montmorillonite, hectorite, and combinations thereof.

10. The system of claim 8 , wherein the stabilizer comprises the latex and the latex comprises a rubber selected from the group consisting of cis-1,4-polyisoprene rubber, styrene-butadiene rubber, cis-1,4-polybutadiene rubber, high styrene resin, butyl rubber, ethylene-propylene rubbers, neoprene rubber, nitrile rubber, cis-/trans-1,4-polyisoprene rubber, silicone rubber, chlorosulfonated polyethylene rubber, crosslinked polyethylene rubber, epichlorohydrin rubber, fluorocarbon rubber, fluorosilicone rubber, polyurethane rubber, polyacrylic rubber, polysulfide rubber, blends thereof, derivatives thereof, and combinations thereof.

Assignees

• Halliburton Energy Services Inc

Inventors

• Pang Xueyu
• Hundt Gregory
• Lewis Samuel
• Sodhi Thomas Singh
• Singh John P
• Tan Brendon

Classifications

• C04B2103/50

  Defoamers, air detrainers · CPC title

• C09K8/12 Primary

  containing synthetic organic macromolecular compounds or their precursors · CPC title

• C09K8/032

  Inorganic additives · CPC title

• C04B18/082

  Cenospheres · CPC title

• C04B24/34

  Natural resins, e.g. rosin {(C04B24/243 takes precedence)} · CPC title