Adhesive composition, cured product, and bonded body

Patent metadata

Field	Value
Publication number	US-11466183-B2
Application number	US-201916442981-A
Country	US
Kind code	B2
Filing date	Jun 17, 2019
Priority date	Jul 18, 2018
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

An adhesive composition which is excellent in adhesion to various hardly adhesive materials such as polyethylene terephthalate, polyethylene, polypropylene, modified polyphenylene ether, polyphenylene sulfide, and a cycloolefin polymer. Further, an adhesive composition containing the following components (A) to (C) may be described Component (A): (Meth) acrylic triblock elastomer having a weight average molecular weight of 80,000 or more, Component (B): (Meth) acrylate monomer having no hydroxyl group and having a phenoxy group, and Component (C): Radical initiator.

First claim

What is claimed is:

1. An adhesive composition comprising the following components (A) to (C):
component (A): (Meth) acrylic triblock elastomer having a melt flow index (190° C., 2.16 kg) of 0.01 or more and 20 or less and having a weight average molecular weight of 80,000 or more,
component (B): (Meth) acrylate monomer having no hydroxyl group and having a phenoxy group, and
component (C): Radical initiator,
wherein the component (A) is an X—Y—X type (meth) acrylic triblock elastomer formed of a segment X which is a polymer of a (meth)acrylate compound and a segment Y which is a polymer of a (meth)acrylate compound,
wherein the component (B) consists of phenoxyethyl acrylate.

2. The adhesive composition according to claim 1 , wherein component (A) is an X—Y—X type (meth) acrylic triblock elastomer formed of a segment X having a glass transition temperature of 70° C. or higher and a segment Y having a glass transition temperature of 0° C. or lower.

3. The adhesive composition according to claim 2 , wherein segment X of component (A) is a polymer of a methacrylate compound having an alkyl group of 1 to 3 carbon atoms, and the segment Y is a polymer of an acrylate compound having an alkyl group of 4 to 20 carbon atoms.

4. The adhesive composition according to claim 2 , wherein a content ratio of segment X is 5 to 50% by mass when a total of the (meth) acrylic triblock elastomer of the component (A) is 100% by mass, and in the component (A), a content ratio of the segment Y is 50 to 95% by mass when a total of the (meth) acrylic triblock elastomer of the component (A) is 100% by mass.

5. The adhesive composition according to claim 1 , wherein 3 to 200 parts by mass of component (A) is included with respect to 100 parts by mass of component (B).

6. The adhesive composition according to claim 1 , wherein component (C) is a photo radical initiator or an organic peroxide.

7. The adhesive composition according to claim 1 , wherein the adhesive composition is used for bonding a material being selected from the group consisting of polyethylene terephthalate, polyethylene, polypropylene, modified polyphenylene ether, polyphenylene sulfide, and a cycloolefin polymer.

8. The adhesive composition according to claim 1 , wherein the adhesive composition is in a liquid state at 25° C.

9. The adhesive composition according to claim 1 , wherein the component (C) is consisting of an organic peroxide.

10. The adhesive composition according to claim 1 , wherein 3 to 7 parts by mass of the component (A) is included with respect to 100 parts by mass of the component (B), and 0.01 to 3 parts by mass of the component (C) is included with respect to 100 parts by mass of the component (B).

11. An adhesive composition comprising the following components (A) to (C):
component (A): (Meth) acrylic triblock elastomer having a melt flow index (190° C., 2.16 kg) of 0.01 or more and 20 or less and having a weight average molecular weight of 80,000 or more,
component (B): (Meth) acrylate monomer having no hydroxyl group and having a phenoxy group, and
component (C): Radical initiator,
wherein the component (A) is an X—Y—X type (meth) acrylic triblock elastomer formed of a segment X which is a polymer of a (meth)acrylate compound and a segment Y which is a polymer of a (meth)acrylate compound;
wherein the adhesive composition has a PPE peel adhesion strength of 15.0 N/m or more, and
wherein the adhesive composition has a PPS peel adhesion strength of 14.0 N/m or more.

12. A cured product obtained by curing the adhesive composition according to claim 1 .

13. A bonded body bonded by the adhesive composition according to claim 1 .

Assignees

• Three Bond Co Ltd
• Threebond Co Lid

Inventors

• Kuwahara Yusuke

Classifications

• B32B2457/202

  LCD, i.e. liquid crystal displays · CPC title

• C08K5/14

  Peroxides · CPC title

• C09J153/005

  Modified block copolymers · CPC title

• C09J153/00

  Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers · CPC title

• C09K2323/05

  Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer · CPC title