Rare-earth doped metal oxide ceramic waveguide quantum memories and methods of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11465941-B2
Application number	US-201917276856-A
Country	US
Kind code	B2
Filing date	Sep 12, 2019
Priority date	Sep 24, 2018
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

A ceramic waveguide includes: a doped metal oxide ceramic core layer; and at least one cladding layer comprising the metal oxide surrounding the core layer, such that the core layer includes an erbium dopant and at least one rare earth metal dopant being: lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, thulium, ytterbium, lutetium, scandium, or oxides thereof, or at least one non-rare earth metal dopant comprising zirconium or oxides thereof. Also included is a quantum memory including: at least one doped polycrystalline ceramic optical device with the ceramic waveguide and a method of fabricating the ceramic waveguide.

First claim

What is claimed is:

1. A ceramic waveguide, comprising:
a doped metal oxide ceramic core layer; and
at least one cladding layer comprising the metal oxide surrounding the core layer,
wherein the core layer includes an erbium dopant and
at least one rare earth metal dopant, comprising: lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, thulium, ytterbium, lutetium, scandium, or oxides thereof, or
at least one non-rare earth metal dopant comprising zirconium or oxides thereof, wherein the core layer has an average grain size in a range of 1 μm 2 to 500 μm 2 .

2. The ceramic waveguide of claim 1 , wherein,
(i) the core layer comprises an erbium dopant and a lanthanum dopant, the erbium dopant is Er 3+ and the lanthanum dopant is La 3+ ; or
(ii) the core layer comprises an erbium dopant and a gadolinium dopant,
the erbium dopant is Er 3+ and the gadolinium dopant is Gd 3+ .

3. A ceramic waveguide, comprising:
a doped metal oxide ceramic core layer; and
at least one cladding layer comprising the metal oxide surrounding the core layer,
wherein:
the core layer comprises an erbium dopant and a lutetium dopant, the erbium dopant is Er 3+ and the lutetium dopant is Lu 3+ ; or
(ii) the core layer comprises an erbium dopant and a scandium dopant, the erbium dopant is Er 3+ and the scandium dopant is Sc 3+ .

4. The ceramic waveguide of claim 3 wherein, the metal oxide is selected from yttrium oxide (Y 2 O 3 ), hafnium oxide (HfO 2 ), zirconium oxide (ZrO 2 ), or combinations thereof.

5. The ceramic waveguide of claim 3 , wherein: wherein the core layer has an average grain size in a range of 1 μm 2 to 500 μm 2 .

6. The ceramic waveguide of claim 3 wherein the at least one cladding layer has a refractive index that is lower than a refractive index of the core layer.

7. The ceramic waveguide of claim 6 , wherein photons traversing the core layer are configured to undergo total internal reflection at a boundary between the core layer and the at least one cladding layer.

8. The ceramic waveguide of claim 1 , wherein the metal oxide is selected from yttrium oxide (Y 2 O 3 ), hafnium oxide (HfO 2 ), zirconium oxide (ZrO 2 ), or combinations thereof.

9. The ceramic waveguide of claim 1 , wherein
the metal oxide is yttrium oxide (Y 2 O 3 ); and
the core layer is configured to have a refractive index (n 1 ) greater than a refractive index of Y 2 O 3 (n 2 ) such that n 1 −n 2 is in a range of 0.001/molar % to 0.009/molar %.

10. A quantum memory, comprising the ceramic waveguide of claim 1 .

11. A method of fabricating a ceramic waveguide, the method comprising:
reacting an organic precursor, at least one transition metal complex, and a plurality of rare-earth metal complexes to form a plurality of rare-earth doped crystalline nanoparticles;
sintering the plurality of rare-earth doped nanoparticles to form a doped polycrystalline ceramic substrate;
disposing a transition metal ceramic slurry over the doped polycrystalline ceramic substrate; and
sintering the slurry to bond the transition metal ceramic to the doped polycrystalline ceramic substrate.

12. The method of claim 11 , wherein the plurality of rare-earth doped crystalline nanoparticles each comprise a diameter of 40 nm or less.

13. The method of claim 11 , wherein the step of reacting comprises:
providing an organic precursor solution;
providing a metal salt solution comprising at least one transition metal complex and a plurality of rare-earth metal complexes; and
mixing the organic precursor solution with the metal salt solution at a boiling point of a solvent in the metal salt solution to form a mixture.

14. The method of claim 13 , wherein the step of reacting further comprises:
filtering the mixture to form a plurality of amorphous nanoparticle precursors;
annealing the plurality of amorphous nanoparticle precursors to form the plurality of rare-earth doped crystalline nanoparticles.

15. The method of claim 14 , wherein:
the organic precursor is urea,
the at least one transition metal complex comprises yttrium.

16. The method of claim 11 , wherein the step of sintering the plurality of rare-earth doped nanoparticles comprises:
a first cold isostatic pressing of the plurality of rare-earth doped crystalline nanoparticles into a pellet;
sintering the pellet at a temperature of at least 1450° C.; and
a second hot isostatic pressing of the pellet under inert atmosphere to form the doped polycrystalline ceramic substrate.

17. The method of claim 11 , wherein the step of disposing comprises:
spin coating or tape casting the transition metal ceramic slurry over the doped polycrystalline ceramic substrate to a thickness in a range of 100 μm to 1 cm.

18. The method of claim 11 , wherein the step of sintering the slurry comprises:
removing volatile material from the slurry to bond the transition metal ceramic to the doped polycrystalline ceramic substrate,
wherein sintering decreases a thickness of the transition metal ceramic by at least 30%, as compared with a thickness of the disposed transition metal ceramic slurry.

19. The method of claim 18 , wherein the volatile material includes at least one of solvent, binder, and plasticizer.

Assignees

• Corning Inc

Inventors

• Aitken Bruce Gardiner
• Garner Sean Matthew
• Ketcham Thomas Dale
• Nolan Daniel Aloysius
• Yang Jun
• Zhang Haitao

Classifications

• C04B2235/3224

  Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide · CPC title

• C04B2235/3227

  Lanthanum oxide or oxide-forming salts thereof · CPC title

• C04B35/486 Primary

  Fine ceramics · CPC title

• C04B2235/6025

  Tape casting, e.g. with a doctor blade · CPC title

• C04B35/6455

  Hot isostatic pressing · CPC title