Method for producing water-absorbent resin powder and production apparatus therefor

Patent metadata

Field	Value
Publication number	US-11465126-B2
Application number	US-201716349709-A
Country	US
Kind code	B2
Filing date	Nov 16, 2017
Priority date	Nov 16, 2016
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

The production method includes: a gel-crushing step of grinding a crosslinked hydrogel polymer to obtain a particulate crosslinked hydrogel polymer; a heating drying step of obtaining dried particles from the particulate crosslinked hydrogel polymer by using a continuous stirring drying machine; a post-crosslinking step of post-crosslinking the particulate crosslinked hydrogel polymer or the dried particles; and a sizing step of adjusting a particle size of the dried particles or the post-crosslinked dried particles to obtain water-absorbent resin powder. The particulate crosslinked hydrogel polymer contains a gel fluidizer. A gel temperature of the particulate crosslinked hydrogel polymer containing the gel fluidizer, the gel temperature being measured by a contact thermometer, is not lower than 50° C. In the production method, the dried particles or the post-crosslinked dried particles is forcedly cooled before the sizing step.

First claim

The invention claimed is:

1. A method for producing water-absorbent resin powder, the method comprising:
a gel-crushing step of grinding a crosslinked hydrogel polymer to obtain a particulate crosslinked hydrogel polymer;
a heating drying step of obtaining dried particles from the particulate crosslinked hydrogel polymer by using a continuous stirring drying machine;
a post-crosslinking step of post-crosslinking the particulate crosslinked hydrogel polymer or the dried particles; and
a sizing step of adjusting a particle size of the dried particles or the post-crosslinked dried particles to obtain water-absorbent resin powder, wherein
the particulate crosslinked hydrogel polymer in the heating drying step contains a gel fluidizer,
a gel temperature of the particulate crosslinked hydrogel polymer containing the gel fluidizer, the gel temperature being measured by a contact thermometer, is not lower than 50° C.,
the dried particles or the post-crosslinked dried particles is forcedly cooled before the sizing step,
the particulate crosslinked hydrogel polymer has a mass-average particle diameter d 1 in terms of dry weight is not greater than 800 μm before drying, and
the continuous stirring drying machine comprises a rotary drying machine having one or more heating means that are selected from a through-flow heating type, an outer wall heating type, and a tubular heating type.

2. The method according to claim 1 , wherein the gel fluidizer is a surfactant.

3. The method according to claim 1 , wherein the gel fluidizer is added to the crosslinked hydrogel polymer or the particulate crosslinked hydrogel polymer before the crosslinked hydrogel polymer or the particulate crosslinked hydrogel polymer is subjected to the post-crosslinking step.

4. The method according to claim 1 , wherein, in the heating drying step, the continuous stirring drying machine is heated in advance before the particulate crosslinked hydrogel polymer is put thereinto.

5. The method according to claim 1 , wherein a ratio (d 2 /d 1 ) of a mass-average particle diameter d 2 of the dried particles or the post-crosslinked dried particles to a mass-average particle diameter d 1 , before drying, of the particulate crosslinked hydrogel polymer is 1.05 to 100.

6. The method according to claim 1 , wherein the dried particles or the post-crosslinked dried particles is granulated material.

7. The method according to claim 1 , wherein a ratio (d 3 /d 2 ) of a mass-average particle diameter d 3 of the water-absorbent resin powder to a mass-average particle diameter d 2 of the dried particles or the post-crosslinked dried particles is 0.05 to 1.1.

8. The method according to claim 1 , wherein a mass-average particle diameter d 2 of the dried particles or the post-crosslinked dried particles is 200 to 2000 μm.

9. The method according to any one of claim 1 , wherein a mass-average particle diameter d 3 of the water-absorbent resin powder is 200 to 1000 μm.

10. The method according to claim 1 , wherein a main component of the water-absorbent resin powder is water-absorbent resin particles having a mass-average particle diameter of 150 to 850 μm.

11. The method according to claim 1 , wherein the sizing step includes:
a first crushing step of crushing the dried particles or the post-crosslinked dried particles to obtain first crushed material;
a first classification step of classifying the first crushed material to separate bulky particles contained in the first crushed material; and
a step of putting the bulky particles into the first crushing step again.

12. The method according to claim 11 , wherein the sizing step includes:
a second classification step of classifying the dried particles or the post-crosslinked dried particles to separate bulky particles contained in the dried particles or the post-crosslinked dried particles;
a second crushing step of crushing the bulky particles to obtain second crushed material; and
a step of putting the second crushed material into the second classification step again.

13. The method according to claim 11 , wherein, in the sizing step, fine powder is removed from the dried particles or the first crushed material.

14. The method according to claim 13 , further comprising a fine powder recycling step of putting the fine powder into a step before the heating drying step and reusing the fine powder.

15. The method according to claim 1 , wherein a gas is introduced into the continuous stirring drying machine used in the heating drying step.

16. The method according to claim 1 , wherein the continuous stirring drying machine is inclined from one end thereof toward another end thereof.

17. The method according to claim 1 , wherein the rotary drying machine has a rotary container that contains the particulate crosslinked hydrogel polymer therein and rotates, and at least one obstructive wall is provided within the rotary container.

18. The method according to claim 1 , wherein
a temperature of the dried particles after the heating drying step and the post-crosslinking step is 150 to 250° C., and
the dried particles or the post-crosslinked dried particles are forcedly cooled to 50 to 130° C. before the sizing step.

19. The method according to claim 1 , wherein a moisture content of the particulate crosslinked hydrogel polymer to be subjected to the heating drying step is 25 to 75% by mass.

20. The method according to claim 1 , wherein moisture contents of the dried particles and the post-crosslinked dried particles are each 1 to 20% by mass.

21. The method according to claim 1 , wherein a post-crosslinking agent is added to the particulate crosslinked hydrogel polymer before the heating drying step.

22. The method according to claim 1 , wherein a post-crosslinking agent is added to the particulate crosslinked hydrogel polymer or the dried particles during the heating drying step.

23. The method according to claim 22 , wherein a moisture content of the particulate crosslinked hydrogel polymer at a time when the post-crosslinking agent is added is not greater than 50% by mass.

24. The method according to claim 1 , further comprising a swelling step of re-swelling the dried particles, the post-crosslinked dried particles, or the water-absorbent resin powder.

25. The method according to claim 24 , wherein 1 to 10% by mass of water is added to the dried particles, the post-crosslinked dried particles, or the water-absorbent resin powder in the swelling step.

26. The method according to claim 1 , wherein the dried particles or the post-crosslinked dried particles is re-swollen and forcedly cooled simultaneously after the heating drying step and before the sizing step.

27. The method according to claim 1 , wherein the dried particles or the post-crosslinked dried particles is forcedly cooled by using a continuous cooling machine having a through-flow heat transfer type or conductive heat transfer type cooling means, after the heating drying step before the sizing step.

28. The method according to claim 27 , wherein the continuous cooling machine is a material stirring type cooling machine.

29. The method according to claim 1 , wherein a water-soluble content, before drying, of the particulate crosslinked hydrogel polymer in terms of dry weight is not greater than 20% by mass.

30. The method according to claim 1 , wherein a w

Assignees

• Nippon Catalytic Chem Ind

Inventors

• Watabe Hiroyasu
• Sato Mai
• Wakabayashi Ryota
• Shobo Yoshihiro
• Katsube Shin-Ya
• Imura Motohiro
• Honda Koji
• Adachi Yoshifumi
• Yorino Tsuyoshi
• Inoue Masafumi
• Arake Tomoyuki
• Hayashi Hiroki
• Katakura Naoki
• Fujino Shin-Ichi
• Ishizaki Kunihiko
• SHUTO Tokio

Classifications

• B01J20/3078

  Thermal treatment, e.g. calcining or pyrolizing · CPC title

• B01J13/0065

  containing an organic phase · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• F26B3/22

  the heat source and the materials or objects to be dried being in relative motion, e.g. of vibration · CPC title

• F26B11/0445

  having conductive heating arrangements, e.g. heated drum wall · CPC title