Methods for electropolishing and coating aluminum on air and/or moisture sensitive substrates

Patent metadata

Field	Value
Publication number	US-11459658-B2
Application number	US-202117379395-A
Country	US
Kind code	B2
Filing date	Jul 19, 2021
Priority date	Sep 17, 2019
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

Methods for electropolishing and coating aluminum on a surface of an air and/or moisture sensitive substrate, including: in a vessel, submerging the substrate in a first molten salt bath and applying an anodizing current to the substrate at a first temperature to electropolish the surface of the substrate; wherein the first molten salt bath includes one of a first organic salt bath and first inorganic salt bath; wherein, when used, the first organic salt bath includes one of (a) aluminum halide and ionic liquid, (b) a combination of an aluminum halide and halogenatedmethylphenylsulfone (C6(H5-y,Xy)SO2CX3, where y is a number from 0-5), (c) a combination of an aluminum halide, an ionic liquid, and halogenatedmethylphenylsulfone (C6(H5-y,Xy)SO2CX3), and (d) AlF3-organofluoride-hydrofluoric acid adduct; wherein, when used, the first inorganic salt bath includes aluminum halide and alkali metal halide; and wherein the anodizing current is 10-30 mA/cm2.

First claim

What is claimed is:

1. A method for electropolishing a surface of an air and/or moisture sensitive substrate, the method comprising:
in a vessel, submerging the substrate in a first molten salt bath at a first temperature and applying an anodizing current to the substrate to electropolish the surface of the substrate;
wherein the substrate comprises one or more or more of zirconium, hafnium, thorium, uranium, plutonium, manganese, a rare earth metal (La—Lu), yttrium, magnesium, lithium, and their alloys;
wherein the first molten salt bath comprises a first inorganic salt bath;
wherein the first inorganic salt bath comprises aluminum halide and alkali metal halide;
wherein the anodizing current is 10-30 mA/cm 2 ; and
further comprising, subsequent to electropolishing the surface of the substrate, coating the electropolished surface of the substrate with aluminum,
wherein coating the electropolished surface of the substrate with aluminum comprises discontinuing the anodizing current and allowing the electropolished substrate to dwell in the first molten salt bath such that the electropolished surface of the substrate is coated with aluminum.

2. The method of claim 1 , wherein the first inorganic salt bath comprises 68-100 wt % AlCl 3 , 0-19 wt % NaCl, and 0-13 wt % KCl.

3. The method of claim 2 , wherein the first inorganic salt bath comprises 82 wt % AlCl 3 , 11 wt % NaCl, and 7 wt % KCl.

4. The method of claim 1 , wherein the first inorganic salt bath comprises 75-100 wt % AlBr 3 , 0-15.4 wt % NaBr, and 0-9.6 wt % KBr.

5. The method of claim 1 , wherein the first inorganic salt bath comprises 76-100 wt % AlI 3 , 0-15 wt % NaI, and 0-9 wt % KI at a first temperature of 110-250 degrees C.

6. The method of claim 1 , wherein the first temperature of the inorganic salt bath is 95-250 degrees C.

7. The method of claim 1 , further comprising annealing a resulting aluminum coating.

8. A method for coating aluminum on a surface of an air and/or moisture sensitive substrate, the method comprising:
in a vessel, submerging the substrate in a molten salt bath with a temperature between 95-250 degrees C.;
wherein the substrate comprises one or more or more of zirconium, hafnium, thorium, uranium, plutonium, manganese, a rare earth metal (La—Lu), yttrium, magnesium, lithium, and their alloys;
applying an anodizing current to the substrate to electropolish the surface of the substrate; and
coating the electropolished surface of the substrate with aluminum by discontinuing the anodizing current and allowing the electropolished substrate to dwell in the molten salt bath at a temperature between 95-250 degrees C. such that the electropolished surface of the substrate is electrolessly coated with aluminum;
wherein the molten salt bath comprises aluminum halide and alkali metal halide.

9. The method of claim 8 , wherein the vessel is sealed and contains an inert cover gas.

10. The method of claim 8 , wherein the substrate electrolessly coated with aluminum is submerged in a molten pool of aluminum.

Assignees

• Cons Nuclear Security Llc

Inventors

• Freiderich John W
• Boyd Tasha L

Classifications

• C25F3/20

  of aluminium · CPC title

• C25F3/28

  of actinides · CPC title

• C25F3/16 Primary

  Polishing · CPC title

• C25D3/665

  from ionic liquids · CPC title

• C25D3/44

  Aluminium · CPC title