Thermoplastic resin, thermoplastic resin composition, and heat conductive sheet
US-2020148815-A1 · May 14, 2020 · US
US11459443B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11459443-B2 |
| Application number | US-201816623261-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 21, 2018 |
| Priority date | Jun 23, 2017 |
| Publication date | Oct 4, 2022 |
| Grant date | Oct 4, 2022 |
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Provided is a resin material capable of effectively enhancing insulation properties, adhesiveness and long-term insulation reliability. The resin material according to the present invention contains first inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.90 or less, second inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.95 or more, third inorganic particles having an average aspect ratio of more than 2, and a binder resin.
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The invention claimed is: 1. A resin material comprising: first inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.90 or less; second inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.95 or more; third inorganic particles having an average aspect ratio of more than 2; and a binder resin, the content of the first inorganic particles in 100% by volume of the resin material being 0.5% by volume or more and 55% by volume or less, the content of the second inorganic particles in 100% by volume of the resin material being 0.5% by volume or more and 55% by volume or less, and the content of the third inorganic particles in 100% by volume of the resin material being 25% by volume or more and 65% by volume or less. 2. The resin material according to claim 1 , wherein the content of the first inorganic particles is 5% by volume or more and 95% by volume or less relative to 100% by volume of sum of the first inorganic particles and the second inorganic particles. 3. The resin material according to claim 1 , wherein the content of the third inorganic particles is 30% by volume or more and 90% by volume or less relative to 100% by volume of sum of the first inorganic particles, the second inorganic particles, and the third inorganic particles. 4. The resin material according to claim 1 , wherein materials of the first and second inorganic particles comprise an aluminum element or a carbon element. 5. The resin material according to claim 1 , wherein the third inorganic particles are primary particles constituting agglomerated particles. 6. The resin material according to claim 1 , wherein the average aspect ratio of the third inorganic particles is 15 or less. 7. The resin material according to claim 1 , wherein a material of the third inorganic particles is boron nitride. 8. The resin material according to claim 1 , wherein when the resin material is heated at a temperature of 200° C. for 80 minutes and pressed at a pressure of 12 MPa to obtain a cured product of the resin material, an average particle diameter of the first inorganic particles and an average particle diameter of the second inorganic particles are 40% or less of the thickness of the cured product. 9. The resin material according to claim 1 , wherein the average particle diameter of the first inorganic particles and the average particle diameter of the second inorganic particles are 30 μm or less. 10. The resin material according to claim 1 , wherein thermal conductivity of the first inorganic particles, thermal conductivity of the second inorganic particles, or thermal conductivity of the third inorganic particles is 10 W/m·K or more. 11. The resin material according to claim 1 , wherein the binder resin contains a thermosetting compound and a thermosetting agent. 12. The resin material according to claim 1 , wherein the resin material is a resin sheet. 13. A method for producing the resin material according to claim 1 , the method comprising a step of blending the first inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.90 or less, the second inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.95 or more, the third inorganic particles having an average aspect ratio of more than 2, and the binder resin. 14. A laminate comprising: a thermal conductor; an insulating layer laminated on one surface of the thermal conductor; and a conductive layer laminated on a surface of the insulating layer opposite to the thermal conductor, the insulating layer containing first inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.90 or less, second inorganic particles having an average aspect ratio of 2 or less and an average circularity of 0.95 or more, third inorganic particles having an average aspect ratio of more than 2, and a binder resin, the content of the first inorganic particles in 100% by volume of the insulating layer being 0.5% by volume or more and 55% by volume or less, the content of the second inorganic particles in 100% by volume of the insulating layer being 0.5% by volume or more and 55% by volume or less, and the content of the third inorganic particles in 100% by volume of the insulating layer being 25% by volume or more and 65% by volume or less.
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