Thermosetting composite resin composition having superior surface smoothness and mechanical properties and method of manufacturing automobile shell plate using same

Patent metadata

Field	Value
Publication number	US-11459441-B2
Application number	US-201916567832-A
Country	US
Kind code	B2
Filing date	Sep 11, 2019
Priority date	Jun 3, 2019
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

Disclosed is a thermosetting composite resin composition including a thermosetting resin, particularly an unsaturated polyester resin, a low-profile additive and an inorganic filler, and to a method of manufacturing an automobile shell plate using the same. The thermosetting composite resin composition can be used to manufacture not only automobile shell plates having low specific gravity and superior surface smoothness and mechanical properties but also structural parts such as interior parts for airplanes or railways.

First claim

What is claimed is:

1. A thermosetting composite resin composition, comprising:
about 22 to 28 wt % of a thermosetting resin, wherein the thermosetting resin comprises an unsaturated polyester comprising a polymer of a glycol and an acid, and having a degree of unsaturation of about 47 to 50%;
about 10 to 15 wt % of a low-profile additive (LPA) comprising epoxy and one or more selected form the group consisting of saturated polyester, polyvinyl acetate (PVAc) and polyurethane (PU); and
about 30 to 35 wt % of an inorganic filler comprising one or more selected from the group consisting of glass bubbles, calcium carbonate (CaCO 3 ) and aluminum hydroxide (Al(OH) 3 ),
wherein the inorganic filler has a compressive strength of about 6000 to 6300 psi, wherein the inorganic filler is surface-treated with a silane compound selected from the group consisting of ester-silane, amino-silane, and methacryl-silane, all the wt % based on the total weight of the thermosetting composite resin composition.

2. The thermosetting composite resin composition of claim 1 , further comprising:
a thickening agent; and
a fibrous reinforcement.

3. The thermosetting resin composite resin of claim 2 ,
wherein the thickening agent is present in an amount of 0.7 to 1.5 wt % and the fibrous reinforcement is present in an amount of about 28 to 37 wt %, all the wt % based on the total weight of the thermosetting resin composite resin composition.

4. The thermosetting composite resin composition of claim 1 , wherein the glycol comprises propylene glycol, neopentyl glycol or combinations thereof.

5. The thermosetting composite resin composition of claim 4 , wherein the thermosetting resin comprises a polymer of propylene glycol, neopentyl glycol and an acid, and
a weight ratio of the propylene glycol, the neopentyl glycol and the acid is about 2.5 to 4.5: 1: 4.5 to 6.5.

6. The thermosetting composite resin composition of claim 1 , further comprising an additive comprising a dispersant, a separation inhibitor or combinations thereof.

7. The thermosetting composite resin composition of claim 2 , wherein the thickening agent comprises a magnesium oxide (MgO), wherein the magnesium oxide is in a form of powder or paste.

8. The thermosetting composite resin composition of claim 2 , wherein the fibrous reinforcement comprises a glass fiber.

9. A method of manufacturing an automobile shell plate, comprising:
forming a sheet using the thermosetting composite resin composition of claim 1 ; and
pressing the sheet through molding.

10. The method of claim 9 , wherein the automobile shell plate has a specific gravity of about 1.27 to 1.37.

11. The method of claim 9 , wherein the automobile shell plate has a tensile strength of 65 to 90 MPa, a tensile modulus of 8.0 to 9.0 GPa, an elongation of 1.35 to 1.5%, a flexural strength of 180 to 200 MPa, or a flexural modulus of 8.5 to 10 GPa.

12. The method of claim 9 , wherein the automobile shell plate has a long-term waviness (LTW) of 8 to 15.

13. An automobile shell plate manufactured by the method of claim 9 .

14. A vehicle comprising the automobile shell plate of claim claim 13 .

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Hanwha Q Cells & Advanced Mat Corp

Inventors

• Park Sang Sun
• Lee Seong Muk
• Kim Se Yong
• Kim Ki Young
• Lee Hyeon Kyu

Classifications

• C08K7/14

  Glass · CPC title

• B29C70/18

  in the form of a mat, e.g. sheet moulding compound [SMC] · CPC title

• C08J5/10

  characterised by the additives used in the polymer mixture · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L67/06 Primary

  Unsaturated polyesters · CPC title