Water soluble film, packets employing the film, and methods of making and using same

Patent metadata

Field	Value
Publication number	US-11459433-B2
Application number	US-202017018310-A
Country	US
Kind code	B2
Filing date	Sep 11, 2020
Priority date	Mar 27, 2015
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

A water-soluble film including a polyvinyl alcohol copolymer resin, a plasticizer, an anti-block filler, and a release modifier is disclosed herein. Also disclosed are related packets incorporating the film, and related methods of making and using the film and packets.

First claim

What is claimed is:

1. A water-soluble film comprising a mixture of a water-soluble polyvinyl alcohol, a plasticizer, an anti-block filler, and a fatty acid release modifier, wherein the anti-block filler is an untreated synthetic amorphous silica and the fatty acid release modifier is stearic acid wherein the water-soluble film has a static coefficient of friction (COF) of 0.43 or less.

2. The water-soluble film of claim 1 , wherein the water-soluble polyvinyl alcohol comprises an anionic group modified polyvinyl alcohol.

3. The water-soluble film of claim 2 , wherein the anionic group modified polyvinyl alcohol comprises a monomethyl maleate copolymer.

4. The water-soluble film of claim 2 , wherein the rate of anionic group modification is in a range of about 1 mol % to about 10 mol %.

5. The water-soluble film of claim 1 , wherein the ratio of the anti-block filler to the fatty acid release modifier is in a range of about 3:1 to about 1:3.

6. The water-soluble film of claim 1 , wherein the anti-block filler is present in an amount of at least about 0.1 PHR.

7. The water-soluble film of claim 1 , wherein the fatty acid release modifier is present in an amount of at least about 0.1 PHR.

8. The water-soluble film of claim 1 , wherein the total amount of the anti-block filler and the fatty acid release modifier is less than about 4 PHR.

9. The water-soluble film of claim 1 , wherein the anti-block filler has a median particle size in a range of about 3 microns to about 11 microns.

10. The water-soluble film of claim 1 , wherein the film has a tensile strength in a range of about 40 MPa to about 60 MPa.

11. The water-soluble film of claim 1 , wherein the film has a tear strength in a range of about 1000 g/mil to about 2100 g/mil.

12. The water-soluble film of claim 1 , wherein the plasticizer is one or more selected from the group of glycerol, sorbitol, 2-methyl-1,3-propanediol, trimethylolpropane, and propylene glycol.

13. The water-soluble film of claim 1 , wherein the water-soluble polyvinyl alcohol is a maleate polyvinyl copolymer having a carboxyl pendant group modification degree in a range of about 6 mol % to about 10 mol %, and a viscosity in a range of about 10.5 cP to about 22.5 cP, and a degree of hydrolysis in a range of about 80% to about 99%.

14. The water-soluble film of claim 1 , further comprising a second release modifier, wherein the second release modifier is one or more selected from the group of fatty acids other than stearic acid, fatty acid esters, fatty acid amides, linear or branched versions of any of the foregoing, saturated or unsaturated versions of any of the foregoing, and substituted or unsubstituted versions of any of the foregoing.

15. The water-soluble film of claim 1 , further comprising one or more additional ingredients selected from a modified starch filler, an antioxidant, a surfactant, a defoamer, and a bitterant.

16. The water-soluble film of claim 1 , wherein:
the water-soluble polyvinyl alcohol comprises a monomethyl maleate copolymer; and
the plasticizer comprises glycerol, sorbitol, 2-methyl-1,3-propanediol, trimethylolpropane, propylene glycol, or a combination thereof.

17. The water-soluble film of claim 1 , wherein the film, when formed into a container holding a liquid detergent, does not release the liquid detergent into bulk water at 20° C. for at least 30 seconds.

18. The water-soluble film 1, wherein the plasticizer comprises glycerol, sorbitol, and trimethylolpropane, wherein the plasticizer blend is present in a total amount of about 40 PHR to about 50 PHR and the individual components are:
22.5 PHR<glycerol<23.3 PHR;
10.3 PHR<sorbitol<15.0 PHR; and
7.5 PHR<trimethylolpropane<10.2 PHR.

19. A container comprising the film of claim 1 .

20. A water-soluble film comprising a mixture of a water-soluble polyvinyl alcohol and a plasticizer blend comprising glycerol, sorbitol, and trimethylolpropane, wherein the plasticizer blend is present in a total amount of about 40 PHR to about 50 PHR and the individual components are:
22.5 PHR<glycerol<23.3 PHR;
10.3 PHR<sorbitol<15.0 PHR; and
7.5 PHR<trimethylolpropane<10.2 PHR,
and wherein the water-soluble film has a modulus at 10% of <30 N/mm 2 , a residue value of about 48 wt % or less as measured by the Dissolution Chamber Test and a Corrected Dissolution Time of <100 seconds.

Assignees

• Monosol Llc

Inventors

• Nii Shinsuke
• Lee David M
• Childers Jennifer L

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08K5/0016 Primary

  Plasticisers · CPC title

• C08J2329/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C08F16/06

  Polyvinyl alcohol {; Vinyl alcohol} · CPC title

• C08F216/06

  Polyvinyl alcohol {; Vinyl alcohol} · CPC title