Method for modifying fluorine distribution in a hydrocarbon compound

Patent metadata

Field	Value
Publication number	US-11459286-B2
Application number	US-201816618866-A
Country	US
Kind code	B2
Filing date	Jun 5, 2018
Priority date	Jun 6, 2017
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound, comprising a step of making contact between said hydrocarbon compound and a catalytic composition comprising a chromium-based catalyst, said process being performed in a reactor made of a material comprising a base layer made of a material M1 and an inner layer made of a material M2, said base layer and said inner layer being laid against each other by bonding.

First claim

The invention claimed is:

1. A process for modifying the fluorine distribution in a hydrocarbon compound, comprising a step of making contact between said hydrocarbon compound and a catalytic composition comprising a chromium-based catalyst in a reactor, said reactor made of a material comprising a base layer made of a material M1, wherein M1 comprises at least 70% by weight of iron on the basis of the total weight of the material M1, and an inner layer made of a material M2, wherein M2 comprises at least 40% by weight of nickel on the basis of the total weight of the material M2, said base layer and said inner layer being laid against each other by bonding, wherein the material M2 is in contact with the hydrocarbon compound and has a tensile strength less than that of the material M1, wherein the rate of corrosion of the material M2, measured according to ASTM D 2328-65 T, is less than 1 mm/year.

2. A process for modifying the fluorine distribution in a hydrocarbon compound, comprising a step of making contact between said hydrocarbon compound and a catalytic composition comprising a chromium-based catalyst in a reactor, said reactor made of a material comprising a base layer made of a material M1, wherein M1 comprises at least 70% by weight of iron on the basis of the total weight of the material M1, and an inner layer made of a material M2, wherein M2 comprises at least 40% by weight of nickel on the basis of the total weight of the material M2, said base layer and said inner layer being laid against each other by bonding wherein the material M2 is in contact with the hydrocarbon compound and has an elongation greater than that of the material M1, wherein the rate of corrosion of the material M2, measured according to ASTM D 2328-65 T, is less than 1 mm/year.

3. A process for modifying the fluorine distribution in a hydrocarbon compound, comprising a step of making contact between said hydrocarbon compound and a catalytic composition comprising a chromium-based catalyst in a reactor, said reactor made of a material comprising a base layer made of a material M1, wherein M1 comprises at least 70% by weight of iron on the basis of the total weight of the material M1, and an inner layer made of a material M2, wherein M2 comprises at least 40% by weight of nickel on the basis of the total weight of the material M2, said base layer and said inner layer being laid against each other by bonding wherein said inner layer has a thickness of between 0.05 and 10 mm, said thickness of said inner layer being less than that of said base layer, wherein the rate of corrosion of the material M2, measured according to ASTM D 2328-65 T, is less than 1 mm/year.

4. The process as claimed in claim 1 , wherein the bonding is performed by weld bonding, explosive bonding, hot-roll bonding or cold-roll bonding.

5. The process as claimed in claim 1 , wherein said hydrocarbon compound is of formula (I) CX(Y) 2 —CX(Y) m —CH m XY, in which X and Y independently represent H, F or Cl and m=0 or 1 with at least one from among X or Y which is Cl or F.

6. The process as claimed in claim 5 , wherein the hydrocarbon compound is selected from the group consisting of tetrachloropropene, chlorotrifluoropropene, pentachloropropane, dichlorotrifluoropropane, trichlorodifluoropropane, tetrafluorochloropropane, tetrachlorofluoropropane, dichlorodifluoropropene, trichlorofluoropropene, pentafluoropropane and mixtures thereof.

7. The process as claimed in claim 1 , wherein the fluorine content of the hydrocarbon compound is increased by reacting said hydrocarbon compound with hydrogen fluoride in the gas phase in the presence of said catalytic composition, the hydrocarbon compound being a saturated halogenated hydrocarbon or an unsaturated halogenated hydrocarbon or an unsaturated hydrocarbon.

8. The process as claimed in claim 1 , wherein the fluorine content of the hydrocarbon compound is reduced by dehydrofluorination of said hydrocarbon compound in the presence of said catalytic composition, said hydrocarbon compound being a fluorinated hydrocarbon compound.

9. The process as claimed in claim 1 , wherein the fluorine distribution of the hydrocarbon compound is modified by isomerizing said hydrocarbon compound in the presence of said catalytic composition, said hydrocarbon compound being a fluorinated hydrocarbon compound.

10. The process as claimed in claim 1 , wherein the fluorine distribution of the hydrocarbon compound is modified by dismutating said hydrocarbon compound in the gas phase in the presence of said catalytic composition, said hydrocarbon compound being a chlorofluorinated hydrocarbon compound.

11. The process as claimed in claim 1 , wherein the fluorine content of the hydrocarbon compound is reduced by reacting said hydrocarbon compound with hydrogen chloride in the gas phase in the presence of said catalytic composition, said hydrocarbon compound being a halogenated hydrocarbon compound containing at least one fluorine atom.

12. The process as claimed in claim 1 , wherein the fluorine content of a first hydrocarbon compound is increased by reacting said first hydrocarbon compound with hydrogen fluoride in the gas phase in the presence of a catalytic composition comprising a chromium-based catalyst, the first hydrocarbon compound being a saturated halogenated hydrocarbon or an unsaturated halogenated hydrocarbon or an unsaturated hydrocarbon, and in that the fluorine content of a second hydrocarbon compound is reduced by dehydrofluorinating said second hydrocarbon compound in the presence of said catalytic composition, said second hydrocarbon compound being a fluorinated hydrocarbon compound.

13. The process of claim 1 , wherein said base layer comprises less than 0.2% of carbon and/or less than 1% of molybdenum and/or less than 2% of chromium on the basis of the total weight of the material M1.

14. The process of claim 6 , wherein the hydrocarbon compound is selected from the group consisting of 2-chloro-3,3,3-trifluoro-1-propene (HFCO-1233xf), 2,3-dichloro-1,1,1-trifluoropropane (HCFC-243db), 1,1,1,2,3-pentachloropropane (HCC-240db), 1,1,2,2,3-pentachloropropane (HCC-240aa), 1,1,1,3,3-pentachloropropane (HCC-240fa), 1,1,2,3-tetrachloro-1-propene (HCO-1230xa), 2,3,3,3-tetrachloro-1-propene (HCO-1230xf), 1,1,3,3-tetrachloro-1-propene (HCO-1230za), 1,3,3,3-tetrachloro-1-propene (HCO-1230zd), 1,1,1,2,2-pentafluoropropane (HFC-245cb) and 1-chloro-3,3,3-trifluoro-1-propene (HCF0-1233zd).

Assignees

• Arkema France

Inventors

• Deur-Bert Dominique
• Wendlinger Laurent

Classifications

• C07C17/093

  by replacement by halogens · CPC title

• C07C17/367

  by depolymerisation · CPC title

• C07C17/206

  the other compound being HX · CPC title

• C07C17/12

  in the ring of aromatic compounds · CPC title

• C07C21/18

  containing fluorine · CPC title