Barrier film

Patent metadata

Field	Value
Publication number	US-11458703-B2
Application number	US-201816767541-A
Country	US
Kind code	B2
Filing date	Nov 28, 2018
Priority date	Nov 28, 2017
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

Provided is a barrier film that includes a base layer (A), and a barrier layer (B) located on one side of the base layer and including one or more cured layers of polysilazane layers having a surface (S) of a concavo-convex structure formed by protruding particles, the barrier film having excellent barrier properties against the external environment, and excellent optical properties. The barrier film can be used for an electronic product sensitive to moisture.

First claim

The invention claimed is:

1. A barrier film, comprising:
a base layer (A); and
a barrier layer (B) located on one side of the base layer and including a cured polysilazane layer formed by curing a polysilazane layer having a surface (S) of a concavo-convex structure formed by particles protruding from the surface,
wherein the polysilazane layer has an amount of polysilazane of 90% or more based on the weight of the polysilazane layer,
wherein the particles having a diameter smaller than a thickness of the polysilazane layer exist in a floating state on the surface of the polysilazane layer,
wherein the cured polysilazane layer having the surface of a concavo-convex structure is an outermost layer of the barrier layer,
wherein an amount of the particles is 0.05 parts by weight to 1 part by weight relative to 100 parts by weight of the polysilazane of the polysilazane layer, and
wherein the cured polysilazane layer has a static friction coefficient of 0.4 or less.

2. The barrier film according to claim 1 , wherein the surface (S) is the opposite surface of the polysilazane layer surface facing the base layer (A).

3. The barrier film according to claim 1 , wherein a polysilazane of the polysilazane layer has a unit of Formula 1 below:

wherein, R 1 , R 2 and R 3 are each independently a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkylsilyl group, an alkylamide group or an alkoxy group.

4. The barrier film according to claim 1 , wherein the polysilazane layer or the cured layer thereof has a kinetic friction coefficient of 0.4 or less.

5. The barrier film according to claim 1 , wherein the particles protruding from the surface (S) have a height of 5 nm or more when measured by an atomic force microscope (AFM).

6. The barrier film according to claim 1 , wherein the polysilazane layer comprises particles having a diameter larger than the height of the polysilazane layer.

7. The barrier film according to claim 1 , wherein the particles are inorganic particles selected from clay, talc, alumina, calcium carbonate, zirconia and silica particles.

8. The barrier film according to claim 1 , wherein the particles are included in an amount of 5 parts by weight or less relative to 100 parts by weight of the polysilazane of the polysilazane layer.

9. The barrier film according to claim 1 , wherein the particles have a diameter in a range of 5 to 200 nm.

10. The barrier film according to claim 1 , further comprising an intermediate layer (C) between the base layer (A) and the barrier layer (B),
wherein the intermediate layer (C) comprises an acrylic resin, a urethane resin, a melamine resin, an alkyd resin, an epoxy resin, a siloxane polymer or a condensation product of an organosilane compound of Formula 2 below:

wherein:
X is hydrogen, halogen, an alkoxy group, an acyloxy group, an alkyl carbonyl group, an alkoxycarbonyl group, or —N(R2) 2 , where R2 is hydrogen or an alkyl group;
R 1 is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an arylalkyl group, an alkylaryl group, an arylalkenyl group, an alkenylaryl group, an arylalkynyl group, an alkynylaryl group, halogen, an amino group, an amide group, an aldehyde group, an alkylcarbonyl group, a carboxy group, a mercapto group, a cyano group, a hydroxy group, an alkoxy group, an alkoxycarbonyl group, a sulfonyl group, a phosphoryl group, an acryloyloxy group, a methacryloyloxy group or an epoxy group;
Q is a single bond, an oxygen element or —N(R2)-, where R2 is hydrogen or an alkyl group; and
m is a number in a range of 1 to 3.

11. The barrier film according to claim 1 , wherein the barrier film has a water vapor transmission rate of 10 mg/m 2 day or less, as measured at a temperature of 38° C. and 100% relative humidity.

12. An electric or electronic element comprising the barrier film according to claim 1 .

13. The barrier film according to claim 1 , wherein the polysilazane layer has an amount of polysilazane of 95% or more based on the weight of the polysilazane layer.

14. The barrier film according to claim 1 , wherein the particles include a hydrophobic or a hydrophilic functional group on a surface of the particles.

15. The barrier film according to claim 1 , wherein the particles are hydrophobic silica particles surface-treated with an acrylic compound.

Assignees

• Lg Chemical Ltd

Inventors

• Jeong Hee Joon
• Hwang Jang Yeon
• Park Bo Ra
• Shin Sung Jin
• Yang Hee Wang

Classifications

• C08G77/62

  Nitrogen atoms · CPC title

• B32B3/30 Primary

  characterised by a layer formed with recesses or projections, e.g. {hollows, grooves, protuberances, ribs (apertured layer B32B3/266; layer with cavities or internal voids B32B3/26)} · CPC title

• B32B2262/10

  Inorganic fibres · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title