Method for producing metal powder

Patent metadata

Field	Value
Publication number	US-11458536-B2
Application number	US-201716461749-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Nov 16, 2016
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

A method for producing a metal powder provided on the surface thereof with a glassy thin film, wherein a glassy substance is produced in the vicinity of the surface of the metal powder by spray pyrolysis from a solution that contains a thermally decomposable metal compound and a glass precursor that produces a glassy substance that does not form a solid solution with the metal produced from the metal compound by thermal decomposition, so as to form the metal powder provided on the surface thereof with the glassy thin film. The metal includes a base metal as a major component, and the solution contains 5 to 30 mass %, as the mass % with reference to the overall solution, of a reducing agent that is soluble in the solution and exhibits a reducing activity during the aforementioned step of heating.

First claim

The invention claimed is:

1. A method for producing a metal powder containing iron provided on a surface thereof with a glassy thin film in which iron is present, the method comprising:
converting a solution into droplets, wherein the solution contains a thermally decomposable metal compound comprising an iron compound and a glass precursor that produces a glassy substance that does not form a solid solution with a metal produced from the thermally decomposable metal compound by thermal decomposition; and
heating the droplets in a reducing atmosphere, while they are dispersed in a carrier gas, at a temperature higher than a decomposition temperature of the thermally decomposable metal compound, higher than a decomposition temperature of the glass precursor, and higher than a melting point of the metal produced from the thermally decomposable metal compound, to produce a metal powder comprising the metal and to produce the glassy substance on the surface of the metal powder, wherein
the iron in the glassy thin film originates from the iron compound,
the glassy substance comprises a silicate-based glass and contains at least 40 mass % of SiO 2 in terms of oxide,
the solution contains 5 to 30 mass %, with reference to an overall solution, of a reducing agent that is soluble in the solution and exhibits a reducing activity during the aforementioned step of heating, and
a total content in the solution of the thermally decomposable metal compound comprising an iron compound and the glass precursor is 20 to 100 g/L as a total concentration of the two components as an amount of metal components produced from the thermally decomposable metal compound by thermal decomposition and an amount of glass components in terms of oxide produced from the glass precursor by thermal decomposition.

2. The method according to claim 1 , wherein
the reducing agent comprises at least one selected from a group consisting of methanol, ethanol, propanol, ethylene glycol, propylene glycol, diethylene glycol, and tetraethylene glycol.

3. The method according to claim 1 , wherein
1 to 20 volume % of a reducing gas is present in the carrier gas.

4. The method according to claim 3 , wherein
the reducing gas is at least one selected from hydrogen, carbon monoxide, methane, and ammonia gas.

5. The method according to claim 1 , wherein
the metal comprises nickel and iron.

6. The method according to claim 5 , wherein the mass ratio between the nickel and iron is nickel:iron=40:60 to 85:15.

7. The method according to claim 1 , wherein
the glassy substance contains at least one selected from the MgO, CaO, SrO, and BaO in terms of oxide.

8. The method according to claim 2 , wherein 1 to 20 volume % of a reducing gas is present in the carrier gas.

9. The method according to claim 8 , wherein the reducing gas is at least one selected from hydrogen, carbon monoxide, methane, and ammonia gas.

Assignees

• Shoei Chemical Ind Co

Inventors

• Iwasaki Mineto
• Kimura Tetsuya

Classifications

• B22F1/16 Primary

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/065

  Spherical particles · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title

• B22F2302/25

  Oxide · CPC title

• B22F2301/35

  Iron · CPC title