Method for preparing membrane and associated membrane and filter element

Patent metadata

Field	Value
Publication number	US-11458439-B2
Application number	US-201616065991-A
Country	US
Kind code	B2
Filing date	Dec 19, 2016
Priority date	Dec 24, 2015
Publication date	Oct 4, 2022
Grant date	Oct 4, 2022

Abstract

The disclosure of the present invention relates to a method for preparing membrane and associated membrane and filter element. The method comprises providing a porous substrate having a plurality of pores; and applying a pre-filler solution to at least partially occupy the pores in the porous substrate. The membrane comprises a porous substrate and a filter layer formed on the porous substrate. The filter element comprises a core tube; and a membrane as prepared and rolled around the core tube.

First claim

What we claim is:

1. A method for preparing a membrane, comprising:
providing a porous substrate having an asymmetric structure including an exposed knitted first side and a second side, wherein the exposed knitted first side comprises flow channels in a direction parallel to a surface of the porous substrate and the second side comprises a porous structure having a mean pore size of 50-1000 microns;
applying a pre-filler solution to at least partially occupy the flow channels in the exposed knitted first side, and to at least partially occupy pores in the second side of the porous substrate;
applying a membrane solution to the second side of the porous substrate applied with the pre-filler solution, and;
solidifying the membrane solution to form a filter layer on the porous substrate while leaving the flow channels at least partially free of the filter layer.

2. The method according to claim 1 , wherein the pre-filler solution comprises water, organic liquids or combination thereof.

3. The method according to claim 2 , wherein the organic liquids comprise alcohols, glycerol, ethylene glycol, N,N-dimethyl formamide (DMF), N-methyl pyrrolidone (NMP), dimethyl sulfoxide (DMSO), dimethylacetamide (DMAc) or any combination thereof.

4. The method according to claim 1 , wherein the pre-filler solution is applied onto the exposed knitted first side of the porous substrate comprising the flow channels; and the membrane solution is applied onto the second side of the porous substrate comprising the porous structure.

5. The method according to claim 1 , wherein applying the pre-filler solution and/or applying the membrane solution comprises spraying coating.

6. The method according to claim 1 , wherein the pre-filler solution comprises a component for solidifying the membrane solution.

7. The method according to claim 1 , wherein the porous substrate has a mean pore size of 100-1000 microns.

8. The method according to claim 1 , wherein the membrane comprises a thickness in range of 300-1000 microns.

9. A membrane prepared by the method of claim 1 .

10. The membrane according to claim 9 , wherein the porous substrate comprises a plurality of pores having a pore size in range of 100-1000 microns.

11. The membrane according to claim 9 , having a thickness in range of 300-800 microns.

12. The membrane according to claim 9 , having a thickness in range of 300-500 microns.

13. The membrane according to claim 9 , the membrane comprises a thickness in range of 100-1000 microns.

14. A filter element, comprising:
(1) a core tube; and
(2) a membrane prepared according to the method of claim 1 and rolled around the core tube.

15. The filter element according to claim 14 , comprising a feed spacer.

16. The filter element according to claim 14 , comprising a lead porous substrate.

17. The method according to claim 1 , further comprising:
either:
applying an additional pre-filler solution to at least partially occupy the flow channels in the exposed knitted first side and applying an additional membrane solution to the exposed knitted first side applied with the additional pre-filler solution, or
applying the membrane solution to the exposed knitted first side applied with the pre-filler solution; and

solidifying the membrane solution or the additional membrane solution to form a filter layer on the exposed knitted first side.

18. The method according to claim 1 ,
wherein applying the membrane solution to the porous substrate applied with a pre-filler solution comprises applying the membrane solution to both the exposed knitted first side and the second side of the porous substrate, and
wherein solidifying the membrane solution comprises forming a filter layer on both the exposed knitted first side and the second side of the porous substrate while leaving the flow channels at least partially free of the filter layer.

19. The method according to claim 1 , wherein the pre-filler solution is an aqueous solution comprising a first interfacial-polymerization reagent, and where the method further comprises:
removing excess aqueous solution to provide an aqueous-coated filter layer, and
applying an organic solution comprising a second interfacial-polymerization reagent to the aqueous-coated filter layer; and
reacting the first and second interfacial-polymerization reagents to form an interfacial-polymerization layer.

Assignees

• Gen Electric
• Bl Technologies Inc

Inventors

• Yang Linglu
• Wang Peng
• Lu Su
• Liu Zhen
• Peng Yun
• Costa Lawrence C

Classifications

• B01D2323/21

  Fillers · CPC title

• B01D2325/04

  Characteristic thickness · CPC title

• B01D2323/26

  Spraying processes · CPC title

• B01D69/105 Primary

  Support pretreatment · CPC title

• B01D2323/46

  Impregnation · CPC title