Integrated power generation, carbon dioxide separation and downstream processing system and method

Patent metadata

Field	Value
Publication number	US-11456474-B2
Application number	US-202016931841-A
Country	US
Kind code	B2
Filing date	Jul 17, 2020
Priority date	Jul 19, 2019
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

An integrated power generation and exhaust processing system includes a fuel cell system configured to generate power and to separate CO2 included in exhaust output from the fuel cell system, and an exhaust processing system configured to at least one of sequester or densify CO2 separated from the exhaust output from the fuel cell system.

First claim

The invention claimed is:

1. An integrated power generation and exhaust processing system comprising:
a fuel cell system configured to generate power and to separate CO 2 included in exhaust output from the fuel cell system; and
an exhaust processing system configured to at least one of sequester or densify CO 2 separated from the exhaust output from the fuel cell system,
wherein the fuel cell system comprises a solid oxide fuel cell stack configured to generate the power, and a carbon dioxide separation device configured to separate the CO 2 included in the exhaust output from the fuel cell system.

2. The system of claim 1 , wherein the exhaust processing system comprises:
a reservoir configured to receive exhaust output from the fuel cell system; and
a compressor configured to compress exhaust output from the reservoir,
wherein the reservoir is configured to reduce an amount of exhaust backpressure applied to the fuel cell system.

3. The system of claim 2 , wherein the reservoir comprises a relief valve configured to prevent the exhaust backpressure in the reservoir from exceeding a preset level.

4. The system of claim 3 , wherein the preset level is less than an amount of pressure that would damage the fuel cell system.

5. The system of claim 2 , wherein the reservoir comprises internal baffles configured to reduce the amount of exhaust backpressure applied to the fuel cell system.

6. The system of claim 2 , wherein the exhaust processing system further comprises a cooling system configured to reduce the temperature of the exhaust in the reservoir.

7. The system of claim 1 , wherein the exhaust processing system comprises:
a sensor configured to measure a characteristic of a fuel that is provided to the fuel cell system; and
a central processing unit configured to determine an amount of CO 2 in the exhaust output from the fuel cell system based on a measurement by the sensor.

8. The system of claim 1 , wherein the exhaust processing system comprises a CO 2 processor configured to chemically convert the CO 2 into solid calcium carbonate.

9. The system of claim 1 , wherein the exhaust processing system comprises:
a condenser configured to condense water from the exhaust output from the fuel cell system;
a compressor disposed downstream of the condenser with respect to a flow direction of the exhaust and configured to compress the CO 2 in the exhaust; and
at least one heat exchanger configured to heat fuel provided to the fuel cell system using heat from at least one of the condenser or the compressor.

10. The system of claim 9 , wherein the at least one heat exchanger comprises:
a first heat exchanger disposed upstream of the condenser, and configured to heat the fuel using heat from the exhaust; and
a second heat exchanger configured to heat the fuel using heat from at least one of the condenser or the compressor.

11. The system of claim 10 , wherein the second heat exchanger is configured to convert the exhaust into liquid CO 2 .

12. The system of claim 10 , further comprising a liquid natural gas (LGN) vessel configured to provide the fuel in a form of liquid natural gas (LGN) to the second heat exchanger via a LGN conduit; and
the fuel is in the form of natural gas (NG) when the fuel is output from the first heat exchanger.

13. The system of claim 12 , further comprising a vaporizer configured to vaporize water to humidify the fuel during system startup using an external heat source.

14. The system of claim 9 , further comprising a water treatment device configured to at least one of neutralize or polish water received from the condenser.

15. The system of claim 9 , wherein the fuel cell system is located on a ship and is electrically connected to an electrical load of the ship.

16. A method of operating a fuel cell system, comprising:
providing a fuel to a fuel cell system;
operating the fuel cell system to generate power and a fuel exhaust stream;
separating CO 2 from the fuel exhaust stream using a carbon dioxide separation device to generate a CO 2 containing exhaust and a purified exhaust;
providing the separated CO 2 containing exhaust to an exhaust processing system;
at least one of sequestering or densifying CO 2 in the CO 2 containing exhaust using the exhaust processing system,
condensing water from the CO 2 containing exhaust;
compressing the CO 2 in the CO 2 containing exhaust; and

heating a fuel provided to the fuel cell system using heat generated from at least one of the condensing or the compressing.

17. The method of claim 16 , wherein:
fuel cell system is located on a ship and is electrically connected to an electrical load of the ship;
the fuel comprises liquid natural gas (LNG) stored in a LNG vessel;
the compressed CO 2 is stored in a CO 2 storage vessel; and
when the ship arrives at a port, the LNG is filled into the LNG vessel and the CO 2 is removed from the CO 2 storage vessel.

18. A method of operating a fuel cell system, comprising:
providing a fuel to a fuel cell system;
operating the fuel cell system to generate power and a fuel exhaust stream;
separating CO 2 from the fuel exhaust stream using a carbon dioxide separation device to generate a CO 2 containing exhaust and a purified exhaust;
providing the separated CO 2 containing exhaust and solid CaO to a NaOH containing solution, such that the CO 2 gas reacts with the NaOH (l) to form Na 2 CO 3 (l) and water, such that the CaO (s) reacts with the water to form Ca(OH) 2 (l), and such that the Na 2 CO 3 (l) and the Ca(OH) 2 (l) react to precipitate solid CaCO 3 and generate NaOH (l); and
recycling the generated NaOH (l) to react with additional CO 2 gas.

Assignees

• Bloom Energy Corp

Inventors

• Ballantine Arne
• Krishnadass Jayakumar
• Karuppaiah Chockkalingam

Classifications

• H01M8/04164

  by condensers, gas-liquid separators or filters · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/0612

  from carbon-containing material · CPC title

• H01M8/0668 Primary

  Removal of carbon monoxide or carbon dioxide · CPC title

• H01M2250/20

  Fuel cells in motive systems, e.g. vehicle, ship, plane · CPC title