Photoelectrochemical cells

Patent metadata

Field	Value
Publication number	US-11453952-B2
Application number	US-202016793815-A
Country	US
Kind code	B2
Filing date	Feb 18, 2020
Priority date	Jul 11, 2017
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

Photoelectrochemical cells including a cathode including alpha-hematite and a metal dichalcogenide, an anode including a conducting polymer, and an electrolyte.

First claim

What is claimed is:

1. A method of generating hydrogen from water, the method comprising providing a photoelectrochemical cell comprising:
(a) an n-type electrode comprising a nanocomposite film comprising a nanomaterial including α-hematite and a metal dichalcogenide, wherein the nanomaterial has an average particle size of from 459 nanometers to 825 nanometers;
(b) a p-type electrode comprising a conducting polymer; and
(c) an electrolyte.

2. The method of claim 1 , wherein the photoelectrochemical cell comprises nanodiamond-regioregular polyhexylthiophene (ND-RRPHTh) blend film as the p-type electrode, MoS 2 -α-hematite as the n-type electrode, and an acidic or a basic solution.

3. The method of claim 1 further comprising:
(b) splitting water into hydrogen and oxygen by means of photocurrent from a p-n junction of the electrochemical cell.

4. The method of claim 3 , wherein the photocurrent is obtained at a potential from about 0 V to about 2,000 V.

5. The method of claim 1 , wherein the nanocomposite film comprises a dopant selected from the group consisting of platinum, tin, cobalt, zinc, palladium, titanium, chromium, rhodium, iridium, and combinations thereof.

6. The method of claim 1 , wherein the electrolyte is an aqueous electrolyte comprising sodium hydroxide, potassium hydroxide, magnesium hydroxide, lithium hydroxide, sodium chloride, potassium chloride, magnesium chloride, hydrochloric acid, sulfuric acid, nitric acid, acetic acid, butyric acid, lactic acid, oxalic acid, myristic acid, and/or perchloric acid.

7. The method of claim 1 , wherein the electrolyte is a gel comprising a polymer and an acid.

8. The method of claim 1 , wherein the conducting polymer is selected from the group consisting of polythiophenes, polyhexylthiophene, regioregular polyhexylthiophene, polyethylenedioxythiophene, polymethylthiophene, polydodcylthiophene, polycarbazole, poly (n-vinylcarbazole), substituted polyethylenedioxythiophenes, polydiooxythiophene, polyaniline, n-poly(N-methyl aniline), poly(o-ethoxyaniline), poly(o-toluidine), polyphenylene vinylene), and combinations thereof.

9. The method of claim 1 , wherein the nanocomposite film is deposited on a conducting fluorine tin oxide (FTO) coated glass plate.

10. The method of claim 1 , wherein the n-type electrode comprises MoS 2 -α-Fe 2 O 3 .

11. The method of claim 1 , wherein the nanocomposite film has from 0.1 wt. % to 5 wt. % MoS 2 .

12. The method of claim 1 , wherein the metal dichalcogenide is selected from the group consisting of molybdenum disulfide, tungsten disulfide, molybdenum diselenide, molybdenum telluride, tungsten selenide, and combinations thereof.

13. The method of claim 1 , wherein:
the electrolyte is a gel comprising a polymer and an acid, and
the polymer of the gel is selected from the group consisting of polyvinyl alcohol, poly(vinyl acetate), poly(vinyl alcohol co-vinyl acetate), poly(methyl methacrylate), poly(vinyl alcohol-co-ethylene ethylene), poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate), polyvinyl butyral, polyvinyl chloride, polystyrene, and combinations thereof, and
the acid of the gel is selected from the group consisting of acetic acid, propionic acid, hydrochloric acid, hydrofluoric acid, phosphoric acid, sulfuric acid, formic acid, benzoic acid, hydrofluoric acid, nitric acid, phosphoric acid, sulfuric acid, tungstosilicic acid hydrate, hydriodic acid, carboxylic acid, and combinations thereof.

14. The method of claim 1 , wherein the conducting polymer is polyhexylthiophene.

Assignees

• Univ South Florida

Inventors

• Alrobei Hussein
• Ram Manoj Kumar

Classifications

• C25B11/095 Primary

  at least one of the compounds being organic · CPC title

• C25B1/55

  Photoelectrolysis · CPC title

• C25B11/091

  consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds · CPC title

• C25B11/051

  Electrodes formed of electrocatalysts on a substrate or carrier · CPC title

• C25B11/057

  consisting of a single element or compound · CPC title