Ferritic stainless steel with excellent ridging resistance

Patent metadata

Field	Value
Publication number	US-11453936-B2
Application number	US-201916979465-A
Country	US
Kind code	B2
Filing date	Mar 29, 2019
Priority date	Mar 30, 2018
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

Ferritic stainless steel securing corrosion resistance while being excellent in ridging resistance able to be stably provided, that is, ferritic stainless steel with excellent ridging resistance having a composition comprising, by mass %, C: 0.001 to 0.01%, Si: 0.3% or less, Mn: 0.3% or less, P: 0.04% or less, S: 0.01% or less, Cr: 10 to 21%, Al: 0.01 to 0.2%, Ti: 0.015 to 0.3%, O: 0.0005 to 0.0050%, N: 0.001 to 0.02%, Ca: 0.0015% or less, and Mg: 0.0003% to 0.0030% and having a balance of Fe and impurities, in which steel, when defining complex inclusions including oxides and having a long axis of 1 μm or more as complex inclusions (A) anddefining complex inclusions satisfying (Formula 1) to (Formula 3) in the complex inclusions (A) as complex inclusions (B),a number ratio of the number of complex inclusions (B) to the number of complex inclusions (A) satisfies (Formula 4), andamong the complex inclusions (B), a number density of complex inclusions having a long axis of 2 μm or more and 15 μm or less is 2/mm2 or more and 20/mm2 or less:Al2O3/MgO≤4  (Formula 1)CaO≤20%  (Formula 2)Al2O3+MgO≥75%  (Formula 3)Number of complex inclusions (B)/Number of complex inclusions (A)≥0.70  (Formula 4)where, in (Formula 1) to (Formula 3), Al2O3, MgO, and CaO indicate the respective mass % in the oxides.

First claim

The invention claimed is:

1. Ferritic stainless steel with excellent ridging resistance having a composition comprising, by mass %,
C: 0.001 to 0.010%,
Si: 0.30% or less,
Mn: 0.30% or less,
P: 0.040% or less,
S: 0.0100% or less,
Cr: 10.0 to 21.0%,
Al: 0.010 to 0.200%,
Ti: 0.015 to 0.300%,
O: 0.0005 to 0.0050%,
N: 0.001 to 0.020%,
Ca: 0.0015% or less, and
Mg: 0.0003% to 0.0030% and
having a balance of Fe and impurities,
wherein a number ratio of a number of complex inclusions (B) to a number of complex inclusions (A) satisfies Formula 4, wherein:
complex inclusions (A) are defined as complex inclusions including oxides, and having a long axis of 1 μm or more, and
complex inclusions (B) are defined as complex inclusions (A) which further satisfy Formula 1, Formula 2, and Formula 3,

wherein a number density of complex inclusions (B) having a long axis of 2 μm or more and 15 μm or less is 2/mm 2 or more and 20/mm 2 or less; and
wherein:
Al 2 O 3 /MgO≤4;  Formula 1:

CaO≤20%;  Formula 2:

Al 2 O 3 +MgO≥75%; and  Formula 3:

Number of complex inclusions ( B )/Number of complex inclusions ( A )≥0.70;  Formula 4:

where, in Formula 1, Formula 2, and Formula 3, Al 2 O 3 , MgO, and CaO indicate the respective mass % of each component in the oxides.

2. Ferritic stainless steel with excellent ridging resistance according to claim 1 , further containing, by mass %, one or more of
B: 0.0020% or less,
Nb: 0.60% or less,
Mo: 2.0% or less,
Ni: 2.0% or less,
Cu: 2.0% or less,
Sn: 0.50% or less
V: 0.200% or less,
Sb: 0.30% or less,
W: 1.00% or less,
Co: 1.00% or less,
Zr: 0.0050% or less,
REM: 0.0100% or less,
Ta: 0.10% or less, and
Ga: 0.0100% or less.

3. Ferritic stainless steel with excellent ridging resistance according to claim 2 , wherein said complex inclusions (A) contain TiN and said chemical composition satisfies Formula 5; and
wherein:
2.44×[% Ti]×[% N]×{[% Si]+0.05×([% Al]−[% Mo])−0.01×[% Cr]+0.35}≥0.0008  Formula 5:

where, [% Ti], [% N], [% Si], [% Al], [% Mo], and [% Cr] show the mass % of the respective elements in the steel.

4. Ferritic stainless steel with excellent ridging resistance according to claim 3 , wherein said chemical composition satisfies Formula 6; and
wherein:
250×[% C]+2×[% Si]+[% Mn]+50×[% P]+50×[% S]+0.06×[% Cr]+60×[% Ti]+54×[% Nb]+100×[% N]+13×[% Cu]≥36  Formula 6:

where, [% C], [% Si], [% Mn], [% P], [% S], [% Cr], [% Ti], [% Nb], [% N], and [% Cu] show the mass % of the respective elements in the steel; when not contained, 0 is entered.

5. Ferritic stainless steel with excellent ridging resistance according to claim 2 , wherein said chemical composition satisfies Formula 6; and
wherein:
250×[% C]+2×[% Si]+[% Mn]+50×[% P]+50×[% S]+0.06×[% Cr]+60×[% Ti]+54×[% Nb]+100×[% N]+13×[% Cu]≥36  Formula 6:

where, [% C], [% Si], [% Mn], [% P], [% S], [% Cr], [% Ti], [% Nb], [% N], and [% Cu] show the mass % of the respective elements in the steel; when not contained, 0 is entered.

6. Ferritic stainless steel with excellent ridging resistance according to claim 1 , wherein said complex inclusions (A) contain TiN and said chemical composition satisfies Formula 5; and
wherein:
2.44×[% Ti]×[% N]×{[% Si]+0.05×([% Al]−[% Mo])−0.01×[% Cr]+0.35}≥0.0008  Formula 5:

where, [% Ti], [% N], [% Si], [% Al], [% Mo], and [% Cr] show the mass % of the respective elements in the steel.

7. Ferritic stainless steel with excellent ridging resistance according to claim 6 , wherein said chemical composition satisfies Formula 6; and
wherein:
250×[% C]+2×[% Si]+[% Mn]+50×[% P]+50×[% S]+0.06×[% Cr]+60×[% Ti]+54×[% Nb]+100×[% N]+13×[% Cu]≥36  Formula 6:

where, [% C], [% Si], [% Mn], [% P], [% S], [% Cr], [% Ti], [% Nb], [% N], and [% Cu] show the mass % of the respective elements in the steel; when not contained, 0 is entered.

8. Ferritic stainless steel with excellent ridging resistance according to claim 1 , wherein said chemical composition satisfies Formula 6; and
wherein:
250×[% C]+2×[% Si]+[% Mn]+50×[% P]+50×[% S]+0.06×[% Cr]+60×[% Ti]+54×[% Nb]+100×[% N]+13×[% Cu]≥36  Formula 6:

where, [% C], [% Si], [% Mn], [% P], [% S], [% Cr], [% Ti], [% Nb], [% N], and [% Cu] show the mass % of the respective elements in the steel; when not contained, 0 is entered.

Assignees

• Nippon Steel Stainless Steel Corp

Inventors

• Kaneko Shigeru
• Fuchigami Katsuhiro
• Inoue Yoshiharu

Classifications

• C22C38/02

  containing silicon · CPC title

• C22C38/06

  containing aluminium · CPC title

• C22C38/48

  with niobium or tantalum · CPC title

• C22C38/04

  containing manganese · CPC title

• C22C38/002

  containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60 · CPC title