Heat-shrinkable multilayer film

Patent metadata

Field	Value
Publication number	US-11453207-B2
Application number	US-201716346173-A
Country	US
Kind code	B2
Filing date	Oct 18, 2017
Priority date	Nov 9, 2016
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

Provided is a heat-shrinkable multilayer film including: an outer surface layer including a thermoplastic resin; an intermediate layer including a polyamide resin; and an inner surface layer including a sealable resin; the total thickness of the heat-shrinkable multilayer film being from 95 to 160 μm; the thickness of the intermediate layer including the polyamide resin being from 17 to 47 μm; the thickness of the inner surface layer being 55 μm or greater; and the ratio of the thickness of the intermediate layer including the polyamide resin to the total thickness of the heat-shrinkable multilayer film being from 18 to 29%. The heat-shrinkable multilayer film of the present invention has high strength and excellent flexibility. Therefore, the heat-shrinkable multilayer film of the present invention is easily stretched and formed, and can be suitably used as a variety of packaging materials including a food packaging material.

First claim

The invention claimed is:

1. A heat-shrinkable multilayer film consisting of:
an outer surface layer including an aromatic polyester resin;
a first adhesive resin;
an intermediate layer including a polyamide resin;
a barrier layer comprising EVOH;
a second adhesive resin; and
an inner surface layer including a sealable resin comprising a polyethylene resin;
wherein
the polyamide resin constituting the intermediate layer is a mixture of 88 to 86 wt. % of nylon 6-66 and 12 to 14 wt. % of nylon 6I-6T;
a total thickness of the heat-shrinkable multilayer film is from 95 to 160 μm;
a thickness of the intermediate layer including the polyamide resin is from 17 to 47 μm;
a thickness of the inner surface layer is 55 μm to 87 μm;
a ratio of the thickness of the intermediate layer including the polyamide resin to the total thickness of the heat-shrinkable multilayer film is from 18 to 29%, and
the heat-shrinkable multilayer film being laminated in the order of the outer surface layer comprising the aromatic polyester resin, the first adhesive resin, the intermediate layer comprising the polyamide resin, the barrier layer comprising the EVOH, the second adhesive resin, and the inner surface layer comprising the polyethylene resin.

2. The heat-shrinkable multilayer film according to claim 1 , wherein a puncture strength from an inner surface layer side at 23° C. and 50% RH is 21 N or greater; and
a 2.5% secant modulus in both the machine direction (MD) and the transverse direction (TD) is from 100 to 520 MPa.

3. The heat-shrinkable multilayer film according to claim 1 , wherein the heat-shrinkable multilayer film is used for packaging.

4. A heat-shrinkable multilayer film consisting of:
an outer surface layer including an aromatic polyester resin;
a first adhesive resin;
an intermediate layer including a polyamide resin;
a barrier layer comprising EVOH;
a second adhesive resin; and
an inner surface layer including a sealable resin comprising a polyethylene resin;
wherein
the polyamide resin constituting the intermediate layer is a mixture of 85 wt. % of nylon 6-66 and 15 wt. % of nylon 6I-6T;

a thickness of the intermediate layer including the polyamide resin is from 19 to 41 μm;
a total thickness of the heat-shrinkable multilayer film is from 95 to 140 μm;
a ratio of the thickness of the intermediate layer including the polyamide resin to the total thickness of the heat-shrinkable multilayer film is 26%, and
the heat-shrinkable multilayer film being laminated in the order of the outer surface layer comprising the aromatic polyester resin, the first adhesive resin, the intermediate layer comprising the polyamide resin, the barrier layer comprising the EVOH, the second adhesive resin, and the inner surface layer comprising the polyethylene resin.

5. The heat-shrinkable multilayer film according to claim 1 or 4 ,
the heat-shrinkable multilayer film being obtained by co-extruding at least three types of molten thermoplastic resins into a tubular body, rapidly cooling the tubular body in a water bath, passing the film-shaped tubular body through a warm water bath and reheating the film-shaped tubular body, simultaneously biaxially stretching the bubble-shaped tubular film at a draw ratio of 3.4 times in the longitudinal direction (MD) and 3.1 times in the transverse direction (TD), and relaxing the tubular film at 68° C. by 7.5% to 10.0% in the longitudinal direction (MD) and 7.5% to 10.0% in the transverse direction (TD).

6. The heat-shrinkable multilayer film according to claim 1 , wherein the first adhesive resin comprises a maleic anhydride-modified polyolefin.

7. The heat-shrinkable multilayer film according to claim 4 , wherein the first adhesive resin comprises a maleic anhydride-modified polyolefin.

8. The heat-shrinkable multilayer film according to claim 1 , wherein in the inner surface layer, the polyethylene resin comprises a very low density polyethylene (VLDPE).

9. The heat-shrinkable multilayer film according to claim 4 , wherein in the inner surface layer, the polyethylene resin comprises a very low density polyethylene (VLDPE).

10. The heat-shrinkable multilayer film according to claim 8 , wherein the very low density polyethylene (VLDPE) comprises a grade corresponding to (i) a density (g/cm 3 ) of 0.912 and a melt index (g/10 min) of 1, or (ii) a density (g/cm 3 ) of 0.911 and a melt index (g/10 min) of 3.3.

11. The heat-shrinkable multilayer film according to claim 9 , wherein the very low density polyethylene (VLDPE) comprises a grade corresponding to (i) a density (g/cm 3 ) of 0.912 and a melt index (g/10 min) of 1, or (ii) a density (g/cm 3 ) of 0.911 and a melt index (g/10 min) of 3.3.

12. The heat-shrinkable multilayer film according to claim 1 , wherein a thickness of the inner surface layer is 61 μm to 66 μm.

Assignees

• Kureha Corp

Inventors

• NAMBU Shota
• Kitada Ichiro
• Itoh Tadayoshi

Classifications

• B32B2307/31

  Heat sealable · CPC title

• B32B2307/736

  Shrinkable · CPC title

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• Y10T428/1379

  Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit · CPC title

• B32B27/08 Primary

  of synthetic resin · CPC title