Catalyst and process for preparing dimethyl ether

Patent metadata

Field	Value
Publication number	US-11452995-B2
Application number	US-201816956677-A
Country	US
Kind code	B2
Filing date	Dec 20, 2018
Priority date	Dec 20, 2017
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

The invention relates to a catalyst and catalyst layer and process for preparing dimethyl ether from synthesis gas or methanol as well as the use of the catalyst or catalyst layer in this process.

First claim

The invention claimed is:

1. A catalyst admixture of catalyst 2 particles comprising an acidic aluminosilicate zeolite with an SiO 2 :Al 2 O 3 molar ratio of from 10 to 1500:1, 10 to 90 weight % of at least one binder material and 0.01 to 20 weight % of copper, based on the total weight of catalyst 2 particles, which is 100 weight %, and catalyst 1 particles comprising 5 to 80 weight % CuO, ZnO, Al 2 O 3 and optionally ZrO 2 .

2. The catalyst admixture according to claim 1 , formed of a packed bed of an admixture of the catalyst 1 particles and the catalyst 2 particles in a weight ratio of from 1:9 to 9:1.

3. The catalyst admixture according to claim 1 , wherein in the catalyst 2 particles the amount of copper is 0.3 to 5 weight %, based on the total weight of the catalyst 2 particles.

4. The catalyst admixture according to claim 1 , wherein, in the catalyst 2 particles, the binder material is an inorganic oxide binder material different from the aluminosilicate zeolite and copper.

5. The catalyst admixture according to claim 4 , wherein the inorganic oxide binder material is selected from the group consisting of Al 2 O 3 , SiO 2 , TiO 2 , ZrO 2 , or mixtures thereof.

6. The catalyst according to claim 4 , wherein the amount of the inorganic oxide binder material is 20 to 70 weight %, based on the total weight of the catalyst 2 particles.

7. The catalyst admixture according to claim 1 , wherein the catalyst 2 particles are formed of 30 to 80 weight % of at least one acidic aluminosilicate of framework type MFI, 20 to 70 weight % of at least one binder material selected from Al 2 O 3 , SiO 2 , TiO 2 and ZrO 2 , and 0.1 to 5 weight % of copper, based on the total weight of the catalyst 2 particles, which is 100 weight %.

8. The catalyst admixture according to claim 1 , wherein the catalyst 2 particles comprise ZSM-5 aluminosilicate, Al 2 O 3 as binder material, and copper.

9. The catalyst admixture according to claim 1 , wherein the catalyst 1 and catalyst 2 particles have an average maximum particle diameter of from 0.5 to 5 mm.

10. A process for preparing dimethyl ether from methanol, comprising contacting methanol with the catalyst admixture according to claim 1 under dehydrating conditions.

11. The process according to claim 10 , wherein the temperature is in the range of from 200 to 400° C.

12. The process according to claim 10 , wherein the temperature is in the range of from 270 to 280° C.

13. A synthesis gas-to-dimethyl ether process comprising contacting synthesis gas with the catalyst admixture according to claim 1 .

14. The catalyst admixture according to claim 9 , wherein the catalyst 1 and catalyst 2 particles are present as a packed bed of extrudates with an average maximum diameter of from 1 to 3.5 mm and a ratio of average length to average maximum diameter of from 0.5:1 to 10:1.

Assignees

• Basf Se

Inventors

• Schuster Sabine
• Schwab Ekkehard
• Altwasser Stefan
• Kaiser Harry
• Schunk Stephan A
• Gaab Manuela

Classifications

• B01J35/55

  Cylinders or rings · CPC title

• B01J23/72

  Copper · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title

• C07C43/043

  Dimethyl ether · CPC title

• C07C41/09

  by dehydration of compounds containing hydroxy groups · CPC title